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Ethylene furnace tube surface coating preparation method

A furnace tube and coating technology, which is applied in the field of coating preparation on the surface of ethylene furnace tubes, can solve the problems of strict requirements, high cost and energy consumption, and easy oxidation of penetrating agents.

Inactive Publication Date: 2007-04-25
CHINA PETROLEUM & CHEM CORP +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0011] The above-mentioned prior art is applied to the steam cracking process. Although the ethylene production cycle is extended to a certain extent and the yield of the target product is improved, the osmotic agent cannot be reused in the preparation process, and the waste is large, and the osmotic agent is easily oxidized.
Moreover, the heat treatment equipment used in the process is strictly required, and the cost and energy consumption are relatively large;

Method used

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  • Ethylene furnace tube surface coating preparation method
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Examples

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preparation example Construction

[0022] The chromium coating on the surface of the ethylene furnace tube prepared by the present invention is a thermal diffusion coating, which is formed by infiltrating metal and a series of elements into the matrix material such as nickel-based stainless steel in one step by adopting a variable temperature powder infiltration method.

[0023] In view of the considerable solubility of chromium in iron, during the powder embedding process, the surface is converted into a chromium alloy layer through the thermal diffusion of chromium to the steel substrate, and the thickness of the infiltrated layer and the content of chromium in the layer can be determined by Thermal diffusion temperature, processing time to control.

[0024] The chromizing is carried out in the co-drilling equipment, and the chromizing of the present invention is carried out in the co-drilling box. The accompanying drawing is a structural schematic diagram of the co-infiltration box provided by the present in...

Embodiment 1

[0049] The material and raw materials of the furnace tube used in this embodiment are all the same as those of Comparative Examples 1 and 2. The furnace tube is prepared with a coating according to the method provided by the present invention, and the co-penetration agent used is composed of: 50% by weight of chromium powder (200 mesh) , 2% by weight of cerium dioxide, 1% by weight of sodium chloride, 2% by weight of ammonium chloride, 0.2% by weight of chromium dichloride, 10% by weight of graphite powder, and the rest being alumina powder. The heating temperature is 1060°C, the heating rate is 160°C / hour, and the constant temperature is 8 hours. The coking suppression experiment was carried out on a medium-sized ethylene cracking device. The coking experiment conditions and results are shown in Table 1. The coating was prepared according to the present invention. The coking rate of the furnace tube is only 0.3712×10 -7 kg / cm 2 h, far lower than Comparative Examples 1 and 2....

Embodiment 2

[0057] The furnace tube material and raw material that present embodiment adopts are all identical with comparative example 3,4, and this furnace tube prepares coating according to the method provided by the present invention, and used co-penetration agent consists of: 45% by weight chromium powder (200 orders), 2% by weight of cerium oxide, 1% by weight of sodium chloride, 2% by weight of ammonium chloride, 0.1% by weight of chromium dichloride, 12% by weight of graphite powder, and the rest being alumina powder. The heating temperature is 1060°C, the heating rate is 160°C / hour, and the constant temperature is 8 hours. The coking inhibition experiment was carried out on the medium-sized ethylene cracking device. The coking experiment conditions and results are shown in Table 2. The coating was prepared according to the present invention. The coking rate of the furnace tube is only 0.6212×10 -7 kg / cm 2 h, far lower than Comparative Examples 3 and 4.

[0058] Table 2

[0059...

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Abstract

A way of making the coat of ethene stove's pipe. Put the dry co-infiltration menstruum into the co-infiltration equipment, embed the processed workpiece into co-infiltration menstruum, then seal up the exit of the equipment and heat up the workpiece in the equipment to the temperature around 500-1400 degree. The speed of heating is 10-200 degree per hour. Keep the temperature about 5-40 hours, and then refrigerate it. The whole process is protected by the environment of argon. This approach improves the stove pipe's capability of controlling scorching. The coat and the pipe's wall could combine well, hard to shed and do not damnify the intrinsic mechanical performance. The cost is low, the process is easy to operate and it could reduce the more than 50% scorching due to the high temperature.

Description

technical field [0001] The invention relates to the surface coating of metal materials, more specifically, a method for preparing the coating on the surface of ethylene furnace tubes. Background technique [0002] With the rapid development of my country's economy, the demand for ethylene and other low-grade olefins has increased significantly. During the "Tenth Five-Year Plan" period, it is planned to increase the production capacity of about 4.05 million tons of ethylene, and the total capacity will reach about 9 million tons per year. In terms of demand, it is predicted that the demand for ethylene will reach 15 million tons by 2005, an increase of 40%. The annual growth rate of demand for ethylene will reach 8.5% higher than the growth of GDP. At that time, the production capacity of ethylene can only meet 60% of the demand. In 2005, the production capacity of propylene will reach nearly 7 million tons, which is expected to only meet 65% of the demand for propylene. Ste...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C23C10/56
Inventor 崔德春李锐樊黑钦肖荣军陈昱
Owner CHINA PETROLEUM & CHEM CORP
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