Acrylic resin, resin boards, transparent electrode boards for touch panels, touch panels, and processes for production of them

A technology of transparent electrodes and manufacturing methods, applied in chemical instruments and methods, synthetic resin layered products, electrical digital data processing, etc., can solve problems such as plate cracking, plate cracking, etc., to prevent damage, improve heat resistance, excellent The effect of optical properties

Inactive Publication Date: 2007-05-30
MITSUBISHI RAYON CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, this method has a problem in that if the peeling process is not carried out at a high temperature in the manufacturing process, cracks will occur.
However, this transparent substrate has a problem that the plate is easily cracked in the step of peeling from the cell after polymerization and curing.

Method used

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  • Acrylic resin, resin boards, transparent electrode boards for touch panels, touch panels, and processes for production of them
  • Acrylic resin, resin boards, transparent electrode boards for touch panels, touch panels, and processes for production of them
  • Acrylic resin, resin boards, transparent electrode boards for touch panels, touch panels, and processes for production of them

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0144] In 10 parts of isostearyl methacrylate ("NK ester S-1800M" manufactured by Shin Nakamura Chemical Industry Co., Ltd.), 10 parts of methyl methacrylate and bis (oxymethyl) tricyclo [5, 2, 1 ,0 2,6 ] In 100 parts of a mixture of 80 parts of decane dimethacrylate, 0.05 parts of 2,2'-azobis(2,4-dimethyl-4-methoxyvaleronitrile) as a polymerization initiator were mixed, 0.05 part of tert-butyl peroxy pivalate, 0.05 part of tert-hexyl peroxy isopropyl carbonate and 0.03 part of terpinolene as a polymerization regulator, and the resulting mixture is put into a suction filter bottle, stirred, and vacuum removed gas to obtain a polymerization mixture.

[0145] The polymerization mixture was poured into a mold formed by inserting a gasket between a pair of tempered glass sheets at a distance of 1.7mm, and air bubbles were removed, and then placed in a heating furnace, and polymerized at 55°C for 1 hour, then at 50°C for 1 hour, and then heated at 135°C Polymerized for 3 hours. ...

Embodiment 2~24

[0147] [Examples 2-24, Comparative Examples 1-9]

[0148] Except having used the raw material composition shown in Tables 1-6, it carried out similarly to Example 1, and produced the acrylic resin board. The evaluation results are shown in Tables 1-6.

Embodiment 25

[0150] In Example 1, 0.05 part of n-dodecyl mercaptan was further added as a chain transfer agent to the polymerization mixture, and the rest was carried out in the same manner as in Example 1 to produce an acrylic resin plate. The evaluation results are shown in Table 7. Moreover, bis(oxymethyl)tricyclo[5,2,1,0 2,6 ] The residual monomer amount of decane dimethacrylate was 2.09%.

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Abstract

A process for the production of acrylic resin boards by polymerizing and curing a polymerizable mixture which comprises 100 parts by mass of a mixture comprising an alkyl methacrylate wherein the alkyl has 1 to 4 carbon atoms and a polyfunctional (meth)acrylate, 0.001 to 1 part by mass of a polymerization initiator having a ten-hour half-life temperature of 80 DEG C or above, and 0.015 to 0.2 part by mass of cyclohexadiene or a terpenoid; an acrylic resin comprising 3 to 30 % by mass of alkyl methacrylate units wherein the alkyl has 8 to 20 carbon atoms, 2 to 35 % by mass of monoethylenically unsaturated monomer units comprising alkyl methacrylate units wherein the alkyl has 1 to 4 carbon atoms, and 35 to 95 % by mass of polyfunctional (meth)acrylate units; resin boards made from this resin and a process for the production thereof; and transparent electrode boards for touch panels and touch panels, made by using the above resin boards.

Description

technical field [0001] The present invention relates to an acrylic resin excellent in heat resistance, appearance, and shape stability, a resin plate made of the acrylic resin, and a transparent electrode for a touch panel having a transparent substrate excellent in heat resistance, transparency, and conductive film adhesion Plates, touch panels with the transparent electrode plates and their manufacturing methods. Background technique [0002] <Acrylic resin board> [0003] Acrylic resin sheets are used in lenses, automotive parts, lighting components, various electronic displays, etc. due to their excellent optical properties. However, when the acrylic resin plate is heat-treated at high temperature, it has a disadvantage of insufficient heat resistance. [0004] As a technique for improving the heat resistance of an acrylic resin sheet, there is a method of introducing a crosslinked structure by adding a polyfunctional monomer during polymerization of methyl metha...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08F220/10C08F2/38C08F4/00G06F3/033H01B5/14B32B27/30C08J5/00C08F220/20
Inventor 菅本秀征川合治畠山宏毅
Owner MITSUBISHI RAYON CO LTD
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