Catalyst of manganese cobalt hexacyanide complex, its preparation and usage

A catalyst and cyanide technology, applied in the direction of organic compound/hydride/coordination complex catalysts, physical/chemical process catalysts, chemical instruments and methods, etc., can solve the problem of less development of new skeleton structures

Inactive Publication Date: 2005-06-29
LIMING RES INST OF CHEM IND
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

So far, the research on cyanide complex catalysts is mainly based on the hexacyanocobalt zinc framework, with more research on ligands

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0031] Solution A: 29g of manganese chloride tetrahydrate, 30ml of tert-butanol, and 30ml of water were mixed and stirred until completely dissolved.

[0032] Solution B: 8g K 3 Co(CN) 6 , 150ml of water and stir until completely dissolved.

[0033] In a 1000ml three-necked flask, add solution A, and add solution B dropwise at 40°C. After the dropwise addition, add 250ml of 50% tert-butanol aqueous solution, then add 2g of diethylene glycol dibenzoate, 2g of polypropylene oxide polyether with two functional molecular weights of 4000, disperse evenly, and filter. The filter cake was redispersed in 250ml of 70% tert-butanol aqueous solution, 2g of diethylene glycol dibenzoate and 2g of polypropylene oxide polyether with a molecular weight of 4000 were added, dispersed evenly, and filtered. The filter cake was redispersed in 250ml of tert-butanol, and 1g of diethylene glycol dibenzoate and 1g of polypropylene oxide polyether with a molecular weight of 4000 were added, disperse...

Embodiment 2

[0039] Solution A: 29g of manganese chloride tetrahydrate, 30ml of tert-butanol, and 30ml of water were mixed and stirred until completely dissolved.

[0040] Solution B: 8g K 3 Co(CN) 6 , 150ml of water and stir until completely dissolved.

[0041] In a 1000ml three-necked flask, add solution A, and add solution B dropwise at 40°C. After the dropwise addition, add 250ml of 50% tert-butanol aqueous solution, then add 2g of dipropylene glycol dibenzoate, 2g of polypropylene oxide polyether with a molecular weight of 4000 and two functionalities, disperse evenly, and filter. The filter cake was redispersed in 250ml of 70% tert-butanol aqueous solution, 2g of dipropylene glycol dibenzoate and 2g of polypropylene oxide polyether with a molecular weight of 4000 were added, dispersed evenly, and filtered. The filter cake was redispersed in 250ml of tert-butanol, 1g of dipropylene glycol dibenzoate and 1g of polypropylene oxide polyether with a molecular weight of 4000 were added,...

Embodiment 3

[0047] Solution A: 35g of manganese acetate tetrahydrate, 30ml of tert-butanol, and 30ml of water were mixed and stirred until completely dissolved.

[0048] Solution B: 8g K 3 Co(CN) 6 , 150ml of water and stir until completely dissolved.

[0049] In a 1000ml three-necked flask, add solution A, and add solution B dropwise at 40°C. After the dropwise addition, add 250ml of 50% tert-butanol aqueous solution, then add 2g of dipropylene glycol dibenzoate, 2g of bifunctional polytetrahydrofuran-ethylene oxide copolyether with a molecular weight of 4000, disperse evenly, and filter. The filter cake was redispersed in 250 ml of 70% tert-butanol aqueous solution, 2 g of dipropylene glycol dibenzoate and 2 g of bifunctional polytetrahydrofuran-ethylene oxide copolyether with a molecular weight of 4000 were added, dispersed evenly, and filtered. Disperse the filter cake in 250ml of tert-butanol, add 1g of dipropylene glycol dibenzoate, 1g of polytetrahydrofuran-ethylene oxide copolyet...

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PUM

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Abstract

The invention concerns the catalyst using 6-H-Gu-Mn as the framework, and its producing way and application in gathering ether. The catalyst is synthesized by water dissolved Mn salt, 6H-Gu acid (salt), organic match thing, organic functions compound and polymer. The gathering ether made by this way , has the features of fewer high numerator tail, low glue degree, the gathering ether compounded at high temperature has low degree of not saturation, narrow distributing of numerator.

Description

technical field [0001] The invention relates to a cyanide complex catalyst (hereinafter referred to as DMC) and its preparation method and its application in the preparation of polyether polyol. Background technique [0002] The DMC catalyst is usually a cyanide-coordinated double metal complex precipitate. Commonly used double metal cyanide complexes include hexacyanocobalt zinc, hexacyanoferric (2 or 3 valent) zinc, tetracyanide nickel zinc, hexacyanoiridium zinc and cyanide complexes in which zinc is replaced by iron, cobalt, nickel, etc. compound precipitation. When this simple cyanide complex is used as a catalyst, the activity is very low. When other ligands such as some metal halides and organic ligands are added to the DMC catalyst, its catalytic activity is greatly improved. Its preparation process is generally to add organic ligands to the suspension of the newly generated double metal cyanide complex for complexation reaction, and then use the aqueous solution o...

Claims

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Application Information

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IPC IPC(8): B01J31/16C08G65/34
Inventor 周集义王文浩王建伟李俊贤李新豪贾利亚王勇平常伟林钱露
Owner LIMING RES INST OF CHEM IND
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