Recording ink and manufacturing method thereof, ink cartridge, ink recorded matter, inkjet recording apparatus, and inkjet recording method
An ink and recording technology, which is applied in the fields of inkjet recording and ink cartridges, can solve the problems that it is not easy to have both the anti-foaming effect and the aforementioned foam-breaking effect, the reliability is reduced, and the storage stability is good.
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Embodiment 1
[0181] -Preparation of black ink-
[0182] 50% by mass of black pigment (manufactured by Toyo Ink Co., Ltd., "KM-9036", average particle diameter: 102nm), 10% by mass of glycerin, 15% by mass of 1,3-butanediol, 2-ethanediol as the aforementioned self-dispersing pigment, Base-1,3-hexanediol 2 mass%, 2-pyrrolidone 2 mass%, surfactant (C 13 h 27 O(C 2 h 4 O) 7 H) Mix 1% by mass, self-emulsifying silicone defoamer (manufactured by Shin-Etsu Chemical Co., Ltd.), 0.1% by mass of "KS508", and ion-exchanged water (the balance), stir well at room temperature, and use the average pore size 1.2 μm membrane filter for filtration. The black ink of Example 1 was prepared from the above.
Embodiment 2
[0184] -Preparation of yellow ink-
[0185] After mixing 30% by mass of C.I. Pigment Yellow 97, 15% by mass of polyoxyethylene oleyl ether ammonium sulfate, 30% by mass of ethylene glycol, and pure water (the balance) as the aforementioned pigment, it was dispersed using a wet sand mixer, Coarse particles were removed by centrifugation (800 rpm, 15 minutes) to prepare a yellow pigment dispersion (1) with an average particle diameter of 120 nm.
[0186] Then, 20% by mass of the aforementioned yellow pigment dispersion (1), 5% by mass of glycerin, 15% by mass of diethylene glycol, 2% by mass of 2,2,4-trimethyl-1,3-pentanediol, and a surface active agent (C 13 h 27 O(C 2 h 4 O) 5 CH 2 COOH) sodium salt 1% by mass, silicone antifoaming agent (manufactured by Shin-Etsu Chemical Co., Ltd., "KS 531" 0.1% by mass), and ion-exchanged water (the rest) were mixed, stirred well at room temperature, and the average pore diameter was used. The membrane filter of 1.2 μm is filtered.Th...
Embodiment 3
[0188] -Preparation of magenta ink-
[0189] Mix 30% by mass of C.I. Pigment Red 122 as the aforementioned pigment, 15% by mass of polyoxyethylene oleyl ammonium sulfate, 30% by mass of glycerin, and pure water (the balance), and disperse using a triple roll mill. Coarse particles were removed by separation treatment (800 rpm, 15 minutes) to prepare a magenta pigment dispersion (2) having an average particle diameter of the pigment of 150 nm.
[0190] Then, 25% by mass of the aforementioned magenta pigment dispersion (2), 5% by mass of glycerin, 15% by mass of diethylene glycol, 2% by mass of 2,2,4-trimethyl-1,3-pentanediol, and a surface active agent (C 13 h 27 O(C 2 h 4 O) 5 CH 2 COOH) sodium salt 1% by mass, silicone defoamer (manufactured by Shin-Etsu Chemical Co., Ltd., "KS 531" 0.1% by mass), and ion-exchanged water (the rest) were mixed, stirred well at room temperature, and used with an average pore diameter of 1.2 The membrane filter of μm is filtered.The magen...
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