Process for fabricating circuit assemblies using electrodepositable dielectric coating compositions

A composition and electrodeposition technology, applied in electrophoretic coatings, printed circuit parts, circuits, etc., can solve problems such as insufficient electrical insulation performance

Inactive Publication Date: 2005-09-21
PPG IND OHIO INC
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0011] US4,601,916 proposes that the direct deposition of an insulating coating onto the metal wall portion of the hole can form a uniform film of resin on the hole wall without thinning of the coating at the top and bottom edges of the hole, and subsequent metal deposition will not interfere with Hole wall adhesion, further electrical insulation performance is not enough

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment A

[0096] This example describes the preparation of the electrodepositable coating composition used in Example 1 below. These resin binders were prepared from the following ingredients as described below. The listed values ​​represent parts by weight (unit: gram).

[0097] components

Example A

crosslinking agent 1

1882

Diethylene glycol monobutyl ether formal

108.78

EPON®828 2

755.30

Tetrabromobisphenol A

694.90

TETRONIC 150R1 3

0.33

Diethanolamine

51.55

Aminopropyldiethanolamine

113.2

remove distillate

(67.66)

Sulfamic acid

45.17

deionization

2714

lactic acid 4

1.70

Resin intermediate 5

244.7

rosin 5

27.49

Deionized water

2875

[0098] components

parts by weight (g)

ethanol

92.0

Propylene Glycol

456.0

Polyol a

739.5

methyl isobu...

Embodiment 1

[0112] 1 Catalyst slurry, purchased from PPG Industries, Inc.

[0113] The ingredients listed above are combined and mixed with gentle agitation. The composition was ultrafiltered 50% and reconstituted with deionized water.

[0114] Preparation of circuitized substrates

[0115] An INVAR metal perforated monolayer (50 microns thick, supplied by Buckbee-Mears, a division of BMC Industries, Inc.) containing 200 micron diameter holes spaced 500 microns apart (center to center) in a square grid arrangement was cleaned and microetched etch to remove unwanted dirt, oil and oxides. The pre-cleaned perforated substrate was then electroplated to provide a copper metal layer with a thickness of 9 microns.

[0116] The electrodepositable coating composition of Example 1 above was electrophoretically applied to the plated substrate in an electrodeposition bath at a temperature of 105°F (41°C) at 90 volts for 2 minutes. The electrocoated substrate was rinsed with deionized wate...

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PUM

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Abstract

Provided is a process for forming metallized vias in a substrate including the steps of (I) applying to an electroconductive substrate an electrodepositable coating composition onto all exposed surfaces of the substrate to form a conformal dielectric coating; (II) ablating a surface of the dielectric coating to expose a section of the substrate; (III) applying a layer of metal to all surfaces to form metallized vias in the substrate. Also disclosed are processes for fabricating a circuit assembly which include the application of an electrodoepositable coating composition onto exposed surfaces of the substrate / core to form a conformal dielectric coating thereon. The electrodepositable coating composition includes a resinous phase dispersed in an aqueous phase, where the resinous phase has a covalently bonded halogen content of at least 1 percent by weight. The dielectric coating derived therefrom has a low dielectric constant and low dielectric loss factor.

Description

technical field [0001] The present invention relates to methods of forming metallized vias and preparing multilayer circuit assemblies including dielectric coatings, particularly dielectric coatings applied by electrodeposition. Background technique [0002] Electrical components such as resistors, transistors and capacitors are commonly mounted on circuit panel structures such as printed circuit boards. Circuit panels generally comprise a generally planar sheet of dielectric material with electrical conductors disposed on one or both of the planar major surfaces of the sheet. The conductor is generally made of metallic material such as copper, etc., and is used to connect electrical components mounted on a circuit board. When the conductors are on both major surfaces of the panel, the panel may have hole conductors extending through holes (or vias) in the dielectric layer to connect conductors on opposite surfaces. Multilayer circuit panel assemblies have heretofore been ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): H01K3/10H05K1/05H05K3/00H05K3/02H05K3/44
CPCY10T29/49156Y10T29/49165H05K3/445H01L2924/0002H05K2201/09554Y10T29/49155H05K1/056H05K3/44H05K2203/0582H05K2203/135H05K3/0032H05K3/0035H01L2924/00C09D5/44H05K1/05
Inventor G·J·麦克克鲁姆T·C·莫利雅利缇K·C·奥尔森M·G·桑德拉A·E·王S·R·扎瓦克
Owner PPG IND OHIO INC
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