In-mold label with separable part
An in-mold label and label technology, which can be applied to stamps, instruments, identification devices, etc., and can solve problems such as loosening and reduced adhesion
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Embodiment 1
[0088]
[0089]
[0090] The catalyst was prepared according to the method disclosed in JP-A 61-130314. Specifically, to 2.0 mmol of ethylene-bis(4,5,6,7-tetrahydroindenyl) zirconium dichloride complex was added methylaluminoxane (purchased from Toyo Stofer). This was diluted to 10 liters with toluene, and thus a catalyst solution was prepared. Using this solution, polymerization was carried out as follows: A mixture of ethylene and 1-hexene in which the 1-hexene content was 80% by weight was fed into a 1.5 liter capacity stirred autoclave type continuous reactor. The pressure inside the reactor is maintained at 1,600kg / cm 2 , the reaction temperature is 160°C.
[0091] After the reaction, an ethylene / α-olefin copolymer (with a 1-hexene content of 22% by weight) was obtained with an MFR of 18 g / 10 min and a density of 0.898 g / cm 3 And the Q value is 1.9. There is a peak in the TREF elution curve of this polymer with a peak temperature of 50°C. H / W of this peak temper...
Embodiment 2
[0119] An in-mold label having a separable portion and a labeled resin container were prepared in the same manner as in Example 1 except that a lubricant was applied to 60% of the area of the separable portion. In this blown container, the label print did not fade, and the label neither shrunk nor bubbled. Additionally, the detachable portion of the label does not come loose from the container.
Embodiment 3
[0121] In the method of Example 1, after the aqueous solution is applied to the surface layer of the film, the aqueous solution containing only 1.0% by weight of the quaternary nitrogen-containing acrylic terpolymer (a) is applied to the back of the film, thereby forming An antistatic layer is formed on both sides. The wettability index of the surface of the heat-sealing resin layer on the back side of the film was 50 mN / m. Others are as shown in Example 1, and an in-mold label having a separable portion and a labeled resin container can be manufactured in the same manner as in Example 1. In the blown containers thus obtained, the label print did not fade and the label neither shrunk nor bubbled. Additionally, the detachable portion of the label does not come loose from the container.
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