Alkali-containing catalyst formulations for low and medium temperature hydrogen generation
A catalyst, hydrogen-rich technology, applied in the field of and unsupported catalyst, hydrogen-rich syngas, aqueous syngas mixture
- Summary
- Abstract
- Description
- Claims
- Application Information
AI Technical Summary
Problems solved by technology
Method used
Image
Examples
Embodiment 1
[0159] 4" wafers were pre-coated with 15 different carriers by slurry dispensing into masterbatches. Carrier deposition was performed with the following carriers: SiO 2 (PQ-MA 1620), WSi 2 99.5%, SiO 2 (80:20 SiO 2 Mixture Kieselgur: BASF), SiO 2 (Aerosil 200), SiO 2 (KA160), SiO 2 (SS5131), SiO 2 (Condea Siralox 5 / 150), SiO 2 (Norton XS16080), SiO 2 (Engelhard Siliperl AF125), SiO 2 LSA, γ-Al 2 o 3Catalox SBa-150, V-doped sol-gel zirconia (Norton XZ16052) PtCe masterbatches 1 and 2. Each slurry was prepared from 1 g in 4 mL of 50:50 ethylene glycol ("EG"):H 2 The carrier composition of the O mixture, except that by adding 1 g carrier to 8 mL EG / H 2 SiO prepared in O, 50:50 2 PQ-MA 1620 and by adding 1.5g to 4mLEG / H 2 ZrO prepared in O / methyl ether ("MEO"), 32.5:30:37.5 2 XZ16052.
[0160] Each carrier slurry was dispensed by liquid from a microtiter plate onto a vertical column of 15 spots on the wafer. After completing the dispensing steps for columns 1-...
Embodiment 2
[0167] γ-Al 2 o 3 (Catalox SBa-150) carrier dispensed 3 μL (1 g γ-Al 2 o 3 in 4 mL of 50:50EG / H 2 O) to 15 x 15 squares of cells on the wafer to pre-coat a 4" wafer. The wafer was then oven dried at 70°C for 12 minutes.
[0168] By adding Pt(NH 3 ) 2 (NO 2 ) 2 (2.5% Pt) stock solutions were spotted into the corresponding first row / last column positions to synthesize internal standards. By placing Na on the wafer 2 Pt(OH) 6 The stock solution (from powder, 1% Pt) was dispensed into rows C1-C5 (2.5 μL per well) to implant a uniform layer of Pt into the wafer.
[0169] The following metal gradients were then injected from top to bottom into rows C6-C15 by dispensing the microtiter plate from the corresponding reservoir Cavro and diluting with distilled water: ZrO(NO 3 ) 2 , La(NO 3 ) 3 , Y(NO 3 ) 3 , Ce(NO 3 ) 3 、H 2 MoO 4 , Fe(NO 3 ) 3 , Co(NO 3 ) 2 , ZrO(OAc) 2 , Mn(NO 3 ) 2 and KRuO 4 . The transfer microtiter plate pattern was then replicated to t...
Embodiment 3
[0176] Slurry distribution through catalyst powder with 5 commercial catalysts (supplied by Alfa Aesar and Aldrich (commercial catalysts used: Ir 1% / γ-Al 2 o 3 (reduced), Ir 5% / CaCO 3 (reduced), Pd 0.5% / γ-Al 2 o 3 (reduced), Pd 5% / BaCO 3 (reduced), Ru 5% / γ-Al 2 o 3 (reduced), each from 4mL EG / H 2 1.5 g catalyst in O / MEO 32.5:30:37.5 for slurry preparation). Each carrier solution was dispensed into 3 different rows at 5 row intervals. The wafer was then oven dried at 70°C for 12 minutes. By adding Pt(NH 3 ) 2 (NO 2 ) 2 Stock solutions (2.5% Pt) were spotted into the corresponding first row / last column positions to synthesize internal standards. 2 rows of NaOH (1M) and 1 row of Pt(NH 3 ) 2 (NO 2 ) 2 A 15-point doping gradient of (2%) was implanted into the wafer, and the microtiter plate pattern was replicated to the wafer (2.5 μL dispensing volume per well, 5 replicates per row, resulting in 3 5×15 rectangles on the wafer).
[0177] The wafer was dried at room...
PUM
Login to View More Abstract
Description
Claims
Application Information
Login to View More