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Polarized sheet protective film and polarized sheet using said film and liquid crystal display device

A technology for polarizers and protective films, applied in optics, instruments, nonlinear optics, etc., which can solve problems such as degradation of LCD visibility, and achieve the effect of improving visibility, improving characteristics and appearance

Active Publication Date: 2006-06-07
KONICA MINOLTA OPTO
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] When the liquid crystal display device is used continuously for a long time, or when it is used continuously at high temperature, or under high temperature and high humidity, the deterioration of LCD visibility is inevitable

Method used

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  • Polarized sheet protective film and polarized sheet using said film and liquid crystal display device
  • Polarized sheet protective film and polarized sheet using said film and liquid crystal display device
  • Polarized sheet protective film and polarized sheet using said film and liquid crystal display device

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1~11

[0183] (Manufacturing polarizer protective film by solution casting method)

[0184] When the cellulose triacetate film of the present invention having a desired dry film thickness of 40 μm is produced by the solution casting method, the dope is firstly prepared. That is, the following compounded composition in which triacetyl cellulose was dissolved in a solvent was put into an airtight container, and the prepared dope was dissolved while stirring, and the prepared dope was filtered with filter paper.

[0185] (mastic composition)

[0186] 100 parts by weight of cellulose triacetate with an acetyl substitution degree of 2.88

[0187] (number average molecular weight 150,000)

[0188] 10 parts by weight of triphenyl phosphate

[0189] Ethyl phthalate ethyl glycolate 2 parts by weight

[0190] UV-23L (ultraviolet absorber) 0.75 parts by weight

[0191] UV-28L (ultraviolet absorber) 0.75 parts by weight

[0192] AEROSIL 200V 0.1 parts by weight

[0193] Dichloromethane 47...

Embodiment 12~14

[0233] (Manufacture of polarizer protective film by melt casting method)

[0234] The cellulose triacetate film of the polarizer protective film of the present invention having a target dry film thickness of 80 μm was produced by the melt casting film forming method.

[0235] 100 parts by weight of cellulose triacetate with an acetyl substitution degree of 2.88

[0236] (number average molecular weight 150,000)

[0237] 10 parts by weight of triphenyl phosphate

[0238] Ethyl phthalate ethyl glycolate 2 parts by weight

[0239] UV-23L (ultraviolet absorber) 0.75 parts by weight

[0240] UV-28L (ultraviolet absorber) 0.75 parts by weight

[0241] Antioxidant 0.01 parts by weight

[0242] Infrared absorber IR-2 (embodiment 12) 0.4 parts by weight

[0243] In Example 13, 0.3 parts by weight of IR-7 as an infrared absorber was used, and in Example 14, 0.2 parts by weight of IR-32 as an infrared absorber was used.

[0244] The mixture of the above-mentioned materials was mel...

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Abstract

The present invention provides a polarizing plate protective film, which has a transmittance of 10% or less at a wavelength of 380 nm and a transmittance of 91% or more at a wavelength of 450 nm. The characteristic is that at least one of the following conditions A, B and C is satisfied: Condition A: The transmittance of the above-mentioned polarizing plate protective film after 200 hours in an environment with a temperature of 80°C and a humidity of 90% RH. The transmittance relative to the above-mentioned wavelengths varies between 80% and 120% respectively; Condition B: After the above-mentioned polarizer protective film has been exposed to a dry environment at a temperature of 105°C for 200 hours, the transmittance relative to the above-mentioned wavelengths The transmittance ranges from 90% to 110% respectively; Condition C: The transmittance of the above-mentioned polarizing plate protective film after 200 hours in an environment with a temperature of -50°C relative to the transmittance of the above-mentioned wavelength , their variation ranges are between 90% and 110% respectively.

Description

technical field [0001] The present invention relates to a polarizing plate protective film used as a protective film for a polarizing plate of a liquid crystal display device (LCD), and a polarizing plate using the film. Background technique [0002] In recent years, liquid crystal display devices (LCDs) have been increasingly used in liquid crystal displays such as TVs, personal computers, and mobile phones because of space saving and energy saving. In particular, with the progress of larger screen size and higher image quality of TV, higher quality of liquid crystal display devices is required due to the expansion, generalization and diversification of use places, and further improvement of display function and visibility function is required. [0003] It has been found that the quality of liquid crystal displays is influenced by the characteristics of polarizers, one of the components of liquid crystal displays. The stabilization of the polarization characteristics of th...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): G02F1/1335
CPCB29C55/04B32B7/12B32B2307/42G02B5/22G02B5/3033G02F1/133528
Inventor 涩谷昌洋
Owner KONICA MINOLTA OPTO