Composition for forming protection film and protection film
A technology of protective film and composition, applied in optics, instruments, nonlinear optics, etc., can solve problems such as cell gap disorder
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[0164] Method for preparing the composition
[0165] The composition of the present invention is preferably prepared by uniformly dissolving or dispersing the above-mentioned components in an appropriate solvent.
[0166] Examples of such solvents include alcohols, ethers, glycol ethers, ethylene glycol alkyl ether acetates, diethylene glycol monoalkyl ethers, diethylene glycol dialkyl ethers, propylene glycol monoalkyl ethers, propylene glycol Alkyl ether acetate, propylene glycol alkyl ether propionate, aromatic hydrocarbons, ketones, esters, etc.
[0167] As specific examples of these solvents, the following can be enumerated respectively:
[0168] As alcohol, for example, methanol, ethanol, etc. can be cited;
[0169] Examples of ethers include tetrahydrofuran and the like;
[0170] As glycol ethers, for example, diethanol monomethyl ether, ethylene glycol monoethyl ether, etc.;
[0171] Examples of glycol alkyl ether acetate include methyl cellosolve acetate, ethyl c...
Embodiment
[0207] Hereinafter, the present invention will be described more specifically by giving examples of synthesis and examples, but the present invention is not limited to the following examples.
[0208] (A) Synthesis of polyorganosiloxane
Synthetic example 1
[0210]Add 27.24g of methyltrimethoxysilane (MTMS), 49.28g of 2-(3,4-epoxycyclohexyl)ethyltrimethoxysilane in a reaction vessel equipped with a stirrer, thermometer, dropping funnel, and reflux cooling pipe (ECETS), 12.02 g dimethyldimethoxysilane (DMDS), 749.2 g methyl isobutyl ketone (MIBK), 12.65 g triethylamine, mixed at room temperature. Then, 90 g of deionized water was dropped from the dropping funnel over 30 minutes, and then reacted at 80° C. for 4 hours while mixing under reflux. After the reaction, the organic layer was taken out and washed in a 0.2% by weight aqueous solution of ammonium nitrate until the washed water became neutral, and then the solvent and water were distilled off under reduced pressure to obtain polyorganosilicon which was a viscous transparent liquid. oxane.
[0211] (Polymer A-1)
[0212] The polyorganosiloxane 1 In H-NMR analysis, near the chemical shift (δ)=3.2ppm, the peak based on the epoxy group was basically the theoretical intensity, ...
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