Manufacturing method of phosphogypsum ball

A production method and technology of phosphogypsum, which is applied in the field of production of phosphogypsum balls, can solve problems such as increasing costs, and achieve the effects of reducing cement costs, improving ball wear resistance, and high sulfur trioxide content

Inactive Publication Date: 2007-01-31
朱成书
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The method for making phosphogypsum balls in the prior art is the disc pelletizing method, and its water content is above 15%, which will increase the cost in cement production

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment Construction

[0018] A method for making phosphogypsum balls, characterized in that the method comprises the following steps:

[0019] 1) Selection of raw materials; waste from phosphate fertilizer plants; the best storage period is more than half a year, volatilization, homogenization, and natural drying; natural volatilization of phosphoric acid and sulfuric acid; screening to remove impurities; less than 10mm;

[0020] 2) Add modifier alkaline substance calcium carbide slag or lime (calcium hydroxide content is 1-5‰;), mix well and put into drying kiln for drying; the moisture content of the dried export material is 2-7%; During the drying process, impurities such as water, water-soluble phosphorus pentoxide, sulfate and phosphate are volatilized;

[0021] 3) Ball molding; volume density is 1.5-3 tons / m 3 .

[0022] 4) The shape is oval; circular; or other shapes.

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Abstract

The present invention relates to a preparation method of phosphogypsum sphere which can be substituted for natural gypsum in cement industrial. Said method includes the following steps: (1), raw material selection: selecting naturally dried rejected material of phosphate fertilizer plant, screening, removing impurity, its grain size is less than 10mm; (2), adding modifying agent alkaline substance, uniformly mixing them, drying in drying kiln, in the drying process making the impurities of water, water-soluble phosphorus pentoxide, sulfate radical and phosphate radical be volatilized; and (3), pressing sphere and forming.

Description

technical field [0001] The invention relates to a method for making phosphogypsum balls used in the cement industry to replace natural gypsum. Background technique [0002] As an additive in cement, gypsum can regulate the setting time and stimulate the activity of cement in cement. Natural gypsum needs to be crushed during the application process, which takes a lot of labor and electricity, which increases the production cost, and the content of sulfur trioxide is low. [0003] Phosphogypsum is a by-product of wet-process phosphoric acid production. It has been recognized by many manufacturers to replace natural gypsum to produce cement. The manufacturing method of the phosphogypsum balls in the prior art is the disk pelletizing method, and its water content is above 15%, which will increase the cost in cement production. Contents of the invention [0004] The purpose of the present invention is to provide a m...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C04B11/26
Inventor 朱成书
Owner 朱成书
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