Solvent in use for purifying products in anthracene series in crystal level

A product and crystallization technology, applied to the separation of heterocycles, can solve the problems of poor washing separation ability, infeasibility, and low yield, and achieve the effect of improving washing separation ability, improving purification effect, and improving separation effect

Inactive Publication Date: 2007-02-21
BAOSHAN IRON & STEEL CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0007] In the existing literature and practical application, the solvent is benzene, acetone, etc., but the disadvantages of these solvents are: 1. When the impurities are separated, the useful components will be taken away too much; 2. In industrialization not feasible in production
[00

Method used

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  • Solvent in use for purifying products in anthracene series in crystal level

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Experimental program
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Embodiment Construction

[0018] The solvent used for crystallization and purification of anthracene series products provided by the invention is prepared by reacting crude benzene with hydrogen and then distilling.

[0019] Compare with prior art by using a specific embodiment of the present invention below, illustrate the beneficial effect of the present invention:

[0020] In the prior art, the solvent FO (anthracene-carba solvent oil) is used to wash and crystallize the anthracene segment AATO of the tar to obtain the intermediate product FACO (anthracene-carba crystallization product), which is then distilled under reduced pressure to produce a carbazole content of about 90%. carbazole products, but the quality of the carbazole products can not be further improved, and the yield is only about 50%, so that the purity of the carbazole products cannot meet the product quality requirements.

[0021] Judging from the product composition of the carbazole product obtained, it contains 2 kinds of impuriti...

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Abstract

This invention relates to a solvent for crystallizing and purifying anthracene series products, which is composed of toluene, xylene, trimethylbenzene, styrene, benzofuran, indane and indene, wherein the sum of toluene, xylene and trimethylbenzene is 70-95 wt.%; the sum of xylene and styrene is 70-90 wt.%; the sum of benzofuran, indane and indene is 1-5 wt.%. The solvent can increase the washing and separation abilities to the impurities in the anthracene range in tar, improve the purification effect of anthracene and carbazole, and increase the yield.

Description

technical field [0001] The invention relates to a solvent used for crystallization and purification of anthracene series products, and is especially suitable for separating condensed rings and heterocycles in coal chemical tar components and purifying anthracene series products. Background technique [0002] At present, for the refining of anthracene and carbazole, anthracene products of coal chemical industry, there are mainly methods of distillation, or crystallization, or solvent crystallization combined with distillation, to remove the impurity components in the anthracene segment of tar through separation. To achieve the purpose of purifying anthracene and carbazole. [0003] The current composition of the tar anthracene segment is shown in Table 1: [0004] [0005] Table 1. The components of the current tar anthracene segment [0006] As can be understood from Table 1, if the distillation method is used, it cannot be refined, and if the crystallization method is ...

Claims

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Application Information

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IPC IPC(8): C07C7/14
Inventor 阮栋陶军顾镇钧
Owner BAOSHAN IRON & STEEL CO LTD
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