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Particulate water absorbent mainly composed of water absorbing resin, manufacturing method therefor, and absorptive article

A technology of water-absorbing resin and water-absorbing agent, applied in chemical instruments and methods, absorbing pads, other chemical processes, etc., can solve the problems of insufficient deodorization performance, not showing sufficient performance, etc., and achieve the effect of excellent absorption capacity

Inactive Publication Date: 2007-07-04
NIPPON SHOKUBAI CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Therefore, there are present problems that conventional water-absorbent resins do not show sufficient performance for use at high concentrations, and deodorizing performance is also insufficient at high concentrations

Method used

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  • Particulate water absorbent mainly composed of water absorbing resin, manufacturing method therefor, and absorptive article
  • Particulate water absorbent mainly composed of water absorbing resin, manufacturing method therefor, and absorptive article
  • Particulate water absorbent mainly composed of water absorbing resin, manufacturing method therefor, and absorptive article

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0251] Into a 2 L four-neck separable flask equipped with a stirrer, reflux condenser, thermometer, nitrogen inlet tube and dropping funnel, 1.0 L of cyclohexane was charged, and 3.8 g of fatty acid sucrose ester (DAI-ICHI KOGYO SEIYAKU Co. Manufacture, DK-esterF-50, HLB=6) as a dispersant dissolved therein. Dissolved oxygen was degassed by bubbling nitrogen. In another flask, 84.6 g of sodium acrylate, a neutralized product of the acrylic acid of Production Example 1, 21.6 g of the acrylic acid of Production Example 1, and 0.016 g of N, N'-methylenebisacrylamide were dissolved in 197 g of ion Water was exchanged, and 0.4 g of hydroxyethylcellulose (manufactured by Daicel Chemical Industries, HEC-Daicel EP-850) was dissolved therein to prepare an aqueous monomer solution having a monomer concentration of 35 wt%. To this monomer aqueous solution, 0.15 g of potassium persulfate was added and dissolved therein. Then, the dissolved oxygen was degassed by bubbling nitrogen. Then...

Embodiment 2

[0257] To 100 parts by weight of the particulate water-absorbing agent (1) obtained in Example 1, 0.3 parts by weight of fine granular silica (manufactured by NIPPON AEROSIL, AEROSIL® 200 (average particle size of primary particles: 12 nm) was added and mixed (dry blended). )) to obtain granular water-absorbing agent (2). The results of evaluating the thus obtained particulate absorbent (2) in a similar manner to Example 1 are shown in Tables 1 and 2.

Embodiment 3

[0259] By spraying 2 parts by weight of an aqueous solution of a plant leaf extract comprising diethylenetriaminepentaacetic acid and a 15% by weight Theaceae plant (trade name: FS-80MO, supplier: Shiraimatu Shinyaku company, address: 37- 1 Ugawa, Minakuchi-cho, Kouka-Gun, Shiga-ken, Japan) aqueous solution, mixed with 100 parts by weight of the granular water-absorbing agent (1) obtained in Example 1 (the amount of each component is adjusted so that Diethylenetriaminepentaacetic acid and 15wt% of plant leaf extract of Theaceae plants are respectively 50ppm (weight) and 0.1wt% relative to the water-absorbing agent (1). The resulting mixture was cured at 60°C for 1 hour. Then, 0.3 parts by weight of fine granular calcium stearate (manufactured by Kanto Chemical Co., Ltd.) was added and mixed (dry blended) thereto to obtain a granular water absorbing agent (3). Table 1 and Table 2 show the results of evaluating the thus obtained particulate water-absorbing agent (3) in a simila...

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Abstract

A particulate water-absorbing agent including a water-absorbing resin having superior property, and being suited for practical applications at high concentrations in absorbing cores such as diapers and the like without generation of any odor of the organic solvent can be obtained because no organic solvent is included.

Description

technical field [0001] The present invention relates to a particulate water-absorbing agent comprising a water-absorbing resin as a main component. More specifically, it relates to a particulate water-absorbing agent that exhibits a more excellent absorbency in practical use as an absorbent article such as a disposable diaper (hereinafter referred to as a diaper) without generating an odor. Background technique [0002] Currently, water-absorbent resins (absorbents) capable of absorbing body fluids and hydrophilic fibers such as pulp are widely used as constituent materials of sanitary products such as disposable diapers, sanitary napkins, and pads for incontinent patients. As water-absorbent resins, for example, partially neutralized and crosslinked polyacrylic acid, hydrolyzate of starch-acrylic acid graft polymer, saponified vinyl acetate-acrylate copolymer, acrylonitrile copolymer or hydrolysis of acrylamide copolymer Compounds, or their cross-linked polymers, cross-lin...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B01J20/26B01J20/30A61F13/15A61F13/53
CPCB01J20/261B01J20/26A61F2013/530569A61F2013/530751A61F2013/5307A61F13/531B01J2220/68A61L15/60B01J20/2803C08F6/18C08F220/06
Inventor 和田克之植田裕子神头照幸石崎邦彦井村元洋
Owner NIPPON SHOKUBAI CO LTD