Process for continuous oxidation
Patent Information
- Authority / Receiving Office
- US ยท United States
- Current Assignee / Owner
- DEGUSSA AG
- Publication Date
- 2002-05-30
- Estimated Expiration
- Not applicable ยท inactive patent
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Abstract
Description
INTRODUCTION AND BACKGROUND
[0001] The present invention concerns a continuous process for oxidation. This process is particularly suitable for the oxidation step in the anthraquinone process for production of hydrogen peroxide, in which substituted anthrahydroquinones are oxidized by oxidation with an oxygen-containing gas to form substituted anthraquinones and hydrogen peroxide.
[0002] In the anthraquinone process this oxidation was initially performed cocurrently in gas distribution towers connected in series using fresh air in each tower, which was both technically complicated and uneconomic. Although the oxidation rate could be increased in a cocurrent flow of air and working solution according to U.S. Pat. No. 3,073,680 whilst retaining specific bubble sizes, obtainable by means of fine-pore gas distributor organs and specific cross-sectional loads, problems arose with the removal of the resulting foam and with the gas-liquid phase separation.
[0003] U.S. Pat. No. 2,902,347 descr...