Laundry system having unitized dosing

a dosing system and unitized technology, applied in textiles and papermaking, softening compositions, packaging, etc., can solve the problems of wasting unusable perfume, increasing the encapsulation process, and reducing the service life of the produ

Inactive Publication Date: 2003-06-05
THE PROCTER & GAMBLE COMPANY
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Benefits of technology

[0022] Further, the present invention provides an effervescent laundry article for dispensing in a laundry wash and / or rinse bath solution, the article having a fabric care composition comprising an active or mixture of actives that is between about 1% and about 99% of the composition and less than about 5%, preferably less than about 3% and more preferably less than about 1% detergent surfactant, and less than about 5%, preferably less than about 3% and more preferably less than about 1% fabric softener active, the composition having an effervescent system comprising an acid, carbon dioxide source and optionally a binder. Even more preferred is an effervescent laundry article that is free of detergent surfactant and fabric softener actives, the article having a fabric care composition comprising an active or mixture of actives that is between about 1% and about 99% of the composition and an effervescent system comprising an acid, carbon dioxide source and optionally a binder. Optionally, the effervescent system will comprise an effervescent granule to improve the release of the active or actives from the effervescent laundry article.
[0028] In a further process aspect, the invention provides methods for dispensing packaged laundry additive products for use by individuals in customizing a laundry solution to deliver a fabric care benefit desired by the individual. The method comprises the step of providing a supply of at least two different types of packaged articles, each having a unitized dose of a fabric care composition, each fabric care composition having a fabric care active or mixture of actives that is between about 1% and about 99% of the composition. The method also includes the step of providing a dispensing device for housing the supply of packaged articles that is capable of allowing an individual to select one or more types of fabric enhancing articles and removing the packaged article from the dispensing device.
[0033] The present invention concerns the unitized delivery of fabric care actives to a laundry solution, regardless of whether the delivery is to a wash and / or rinse bath solution, the temperature of the solution or the presence of other materials in the solution. The delivery of a fabric care active or mixture of actives to a laundry solution in a unitized dose enables a consumer to impart specific fabric care benefits to the fabrics while maximizing convenience and flexibility.

Problems solved by technology

During the laundry process, a substantial amount of perfume that is added to the wash and / or the rinse cycle is lost with the water and in the subsequent drying cycle (either line drying or machine drying).
This has resulted in both a waste of unusable perfume that are not deposited on the laundered fabrics, and a contribution to the general air pollution from the release of volatile organic compounds to the air.
However, the encapsulation process is more demanding, and perfume leakage due to breakage of the microcapsules during processing, packaging, shipping, and storing of the product tends to occur.
However, the activation to release perfume can be less effective than the encapsulation methods described herein above.
Many types of aminofunctional silicones also cause fabric yellowing and such silicones are not preferred.
Although silicones with a high number, e.g., greater than about 0.5 millimolar equivalent of amine groups can be used, they are not preferred because they can cause fabric yellowing.
However, it is to be noted that excessive scum dispersant may adversely affect softening where the use of fabric softener actives are to be added to the laundry solution.
Therefore, cyclodextrin does not complex effectively with some very low molecular weight organic amines and acids when they are present at low levels.
The addition of the glycols tends to fill up void space in the cyclodextrin cavity that is unable to be filled by some malodor molecules of relatively smaller sizes.
It has been found that this small amount of chlorine in the tap water can cause fading of some fabric dyes.
Although by this process no dye molecules are lost, the result of this chelation is a change of hue or a dimming or loss of intensity to the color of the fabric.
However, this sameness definition does not exclude polyamines that comprise other extraneous units comprising the polymer backbone and that are present due to an artifact of the chosen method of chemical synthesis.
However, not all of the preferred heavy metal ion controlling agents comprise backbones that include a "chain elongation moiety".
However, prior to the present invention, their use in laundry applications has been limited to the delivery of detergent actives.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

example vii

Preparation of HPMC Encapsulate

[0585] Neodol 91-8 and perfume were mixed in a beaker and stirred with a spatula until homogeneous. Two pieces of hydroxypropyl methlycellulose film (available from Chris Craft Ind., Inc.) were cut into sections approximately 1.5 inches square. The pieces were heat sealed on three sides using a conventional heat sealer, to form a pouch or envelope. Approximately 2 g of the perfume-Neodol mixture was added to the pouch and the fourth side was heat sealed to enclose the mixture. The weight percentages of these components in the final product are presented in Table B.

6TABLE B Component Order of Addition Weight % Neodol 91-8 1 43.67 Perfume 2 43.67 Hydroxypropylmethylcellulose 3 12.66

[0586] Highly water-soluble capsules containing fabric care actives can be prepared by a variety of methods. Water-soluble materials in film form are particularly useful in such methods. Preferred films will include those films that are highly water-soluble having fast dissolu...

examples viii

-IX

Preparation of PVA and HPMC Capsules

[0589] In Examples VIII and IX presented in Table C, the fill material consisted of a mixture of perfume and Neodol 91-8 and the polyvinyl alcohol spherical capsules were made by the aforementioned encapsulation process described in WO97 / 35537.

[0590] In yet another example, a mixture of perfume and Neodol 91-8 (1:1 wt. Ratio) was sealed in a hemispherical capsule made of a water soluble polyvinyl alcohol film (Mono-sol 8630 made by Chris Craft Industries, Inc.). The film was deformed by vacuum, filled without about 10 cc of perfume / Neodol mixture and a second segment of polyvinyl alcohol film was placed over the mold and the two film sections were heat sealed with a pressure plate at about 300.degree. F. for about 2 seconds at a pressure of about 70 psig. The final product was a generally hemispherical capsule containing the fabric care active. Excess film about the seal was trimmed away to improve the aesthetics of the capsulate.

[0591] Althoug...

example xi

Zeolite / Perfume Complex

[0602] The zeolite is first activated by drying it overnight in an oven at 130.degree. C. under reduced pressure of less than 30 mm Hg. The weight loss due to drying was approximately 5 g / kg of zeolite material. One hundred grams of zeolite was then placed in a beaker with 15 g of perfume active. These materials were stirred in the beaker with a glass rod until there was uniformity in the mixture at which point the mixture was giving off a small amount of heat. The mixture was then transferred to a glass blender and mixed for 1 minute at which point the heat coming from the mixture was very noticeable. Alternative mixers and grinders may be used at this stage, but devices having plastic elements should be avoided as the perfume may react or be absorbed into or degrade the plastic.

[0603] The amount of perfume in the perfume loaded zeolite was 13%.

[0604] 2. Effervescent Articles

[0605] The articles of the present invention may also have an effervescence system or...

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Abstract

Compositions, articles and methods are provided for supplying fabric care benefits to clothing or fabrics in an automated washing machine and by manual washing. The fabric care compositions preferably have less than about 5% detergent surfactants, more preferably less than 3%, even more preferably less than 1% and are most preferably free of detergent surfactants. Similarly, the fabric care compositions preferably have less than about 5% fabric softener actives, more preferably less than 3%, even more preferably less than 1% and are most preferably free of detergent surfactants. The laundry articles can take a variety of forms in a variety of physical states all of which will rapidly dispense a unitized amount of one or more selected fabric care agents to a wash and / or rinse bath solution during the laundering process under a variety of conditions. The invention also pertains to laundry kits that contain a variety of such articles and instructions concerning their use. Likewise, methods for preparing a customized laundry solution to obtain a specific; fabric care benefit selected based on the user's personal preferences and / or the fabric care needs of the fabrics being laundered are also provided. Further, the present invention also concerns methods for assisting a consumer in identifying the unitized articles to be used in preparing a laundry solution that will impart desired fabric care benefits as well as merchandising displays for dispensing the articles, assembling customized laundry kits and instructing the consumer on the selection and use of laundry articles.

Description

CROSS REFERENCE RELATED TO CASE[0001] This patent application claims the benefit of U.S. Provisional Application Serial No. 60 / 203,472 filed May 11, 2000 by Welch, et al.[0002] The present invention relates to compositions, articles and methods for supplying fabric care benefits to clothing or fabrics in an automated washing machine and by manual washing. The articles take a variety of forms and will rapidly dispense a unitized amount of one or more selected fabric care agents to a wash and / or rinse bath solution during the laundering process under a variety of conditions. The invention also pertains to laundry kits that contain a variety of such articles and instructions concerning their use. Likewise, methods for preparing a customized laundry solution to obtain fabric care benefits selected based on the user's personal preferences and / or the fabric care needs of the fabrics being laundered are also provided. Further, the present invention also concerns methods for assisting a con...

Claims

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Application Information

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Patent Type & Authority Applications(United States)
IPC IPC(8): A47F1/08B65D65/46C11D1/62C11D1/72C11D3/00C11D3/37C11D3/42C11D3/48C11D3/50C11D11/00C11D17/04C11D17/06D06M15/03D06M15/11D06M15/15D06M15/333
CPCA47F1/08C11D17/046C11D3/0015C11D3/0021C11D3/0026C11D3/0036C11D3/0052C11D3/0068C11D3/373C11D3/42C11D3/48C11D3/50C11D3/505C11D11/0017C11D17/0039C11D17/041C11D17/042C11D17/043C11D3/001
Inventor CASWELL, DEBRA SUEWELCH, ROBERT GARYRIDYARD, MARK WILLIAMSAYERS, EDWARDYORK, DAVID WILLIAMDUFTON, DANIEL JAMESHOWE, SIMONESHUIS, JOHANPENA-ROMERO, ANGELINALAUDAMIEL-PELLET, CHRISTOPHEHOFFMAN, WUNDRIARIDECKNER, GEORGE ENDELWAHL, ERROL HOFFMANMURPHY, RUTH ANNEHENSLEY, CHARLES ALBERTTRINH, TOANDIHORA, JITEN ODHAVJIBAKER, ELLEN SCHMIDTLITTIG, JANET SUESCHROEDER, TIMOTHY JAMESDIERSING, STEVEN LOUISDODD, MALCOLM MCCLARENGALLON, LOIS SARA
Owner THE PROCTER & GAMBLE COMPANY
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