Organic electroluminescence device and organic light emitting medium
an electroluminescence device and organic technology, applied in the field of organic electroluminescence, can solve the problems of insufficient life and efficiency of light emission for practical applications, inability to use organic el devices using this material for practical applications, and insufficient life and properties. , to achieve the effect of excellent heat resistance and high purity of color
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example 1
[0132] On a glass plate having a size of 25×75×1.1 mm, a transparent electrode made of indium tin oxide and having a thickness of 120 nm was formed. After the glass substrate was cleaned by irradiation with ultraviolet light and exposure to ozone, the glass substrate was placed in a vacuum vapor deposition apparatus.
[0133] After N,N′-bis[4-(diphenylamino)phenyl]-N,N′-diphenylbiphenyl-4,4′-diamine was vapor deposited so that a hole injecting layer having a thickness of 60 nm was formed, N,N,N′,N′-tetrakis(4-biphenyl)-4,4′-benzidine was vapor deposited on the formed hole injecting layer so that a hole transporting layer having a thickness of 20 nm was formed. Then, compound (EM4) shown above as component (B) and compound (EM83) shown above as component (A) were simultaneously vapor deposited in amounts such that the ratio of the amount by weight of component (B) to the amount by weight of component (A) was 40:3 so that a light emitting layer having a thickness of 40 nm was formed.
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examples 2 to 19
[0136] Organic EL devices were prepared in accordance with the same procedures as those conducted in Example 1 except that compounds shown in Table 1 were used as component (B) and component (A). The results of testing the obtained devices by passing an electric current at a current density of 10 mA / cm2 are shown in Table 1. The half-life times obtained by the test of continuous passage of a direct current at initial luminances shown in Table 1 are also shown in Table 1.
example 20
[0142] An organic EL device was prepared in accordance with the same procedures as those conducted in Example 1 except that compounds shown in Table 2 were used as component (B) and component (A) and Alq:Cs / Al was used as the cathode. Alq:Cs / Al was a mixed layer containing Alq and Cs (cesium) metal as the electron transporting compounds in relative amounts by mole of 1:1. The results of testing the obtained device by passing an electric current at a current density of 10 mA / cm2 are shown in Table 2. The half-life time obtained by the test of continuous passage of a direct current at the initial luminance shown in Table 2 is also shown in Table 2.
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