Liquid organopolysiloxane composition for matting and cured article having a matted surface

a technology of organopolysiloxane and composition, which is applied in the direction of transportation and packaging, coating, special tyres, etc., can solve the problems of loss of image contrast, poor visibility, poor reliability of the detection system receiving the light beam, etc., and achieve the loss of reliability of the detection system, reduce contrast, and cure the effect of high speed

Inactive Publication Date: 2007-12-13
SHIN ETSU CHEM IND CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Benefits of technology

[0021]The liquid organopolysiloxane composition for matting of the present invention is readily capable of providing a cured article having a matted surface without additionally conducing a separate step such as mechanical surface roughening by using a file.
[0022]Accordingly, use of such organopolysiloxane composition as a potting or coating material in an image display such as LED will obviate the problems of reduced contrast due to reflection of the incident light beam on the surface of the cured article as well as loss of reliability of the detection system.
[0023]The liquid organopolysiloxane composition for matting of the present invention comprises (A) a thermosetting liquid organopolysiloxane composition, and (B) a hollow filler having a melting point of at least 150° C., a specific weight of 0.01 to 0.8, a particle size of up to 200 μm.
[0024]The thermosetting liquid organopolysiloxane used in the present invention as component (A) is not particularly limited for its type or mode of curing as long as it is liquid at room temperature (25° C.), and cures by heating to form a cured article having r

Problems solved by technology

Such reflection resulted in the loss of image contrast which in turn resulted in the poor visibility, and also, in the poor reliability of the detection system receiving the light beam from the LED.
However, mechanical surface roughening of the cured article resulted in the increase in the number of steps, which invited increase in the production cost.
Use of the optical device with higher luminance also resulted in the increased cost.
However, incorporation of the inorganic filler at a high content was requried in order to provide a sufficiently matted surface by this method, and such incorporation of the inorganic filler at a high content resulted in an increased viscosity of the composition, and hence, in a marked decrease in the flowability.
Accordingly, use of such composition as a potting material or coating material was difficult.
In the case of these silicone rubber compositions, the filler had a specific weight higher

Method used

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Examples

Experimental program
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Effect test

example 1

[0063]50 parts of KE1280(A) (product name; manufactured by Shin-Etsu Chemical Co., Ltd.; viscosity, 1,500 mPa·s) and 50 parts of KE1280(B) (product name; manufactured by Shin-Etsu Chemical Co., Ltd.; viscosity, 1,000 mPa·s) respectively having the formulation as shown below were mixed to produce a liquid organopolysiloxane composition. This composition had a viscosity of 1,300 mPa·s.

[0064][KE1280(A)][0065]Base polymer (vinyl group-containing dimethylpolysiloxane): 90%,[0066]Platinum catalyst: 0.01%,[0067]Fumed silica: 5.0%,[0068]Other additives: 4.99%

[0069][KE1280(B)][0070]Base polymer (vinyl group-containing dimethylpolysiloxane): 75%[0071]Methyl hydrogen polysiloxane: 10.0%,[0072]Fumed silica: 5.0%,[0073]Other additives: 10.0%

[0074]Next, to this liquid organopolysiloxane composition was added 6 parts of CEL-STAR Z-36 (product name of a hollow filler manufactured by Tokai Kogyo Co., Ltd. having an outer shell of borosilicate glass, a particle size of 25 to 70 μm, and a specific wei...

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Abstract

A liquid organopolysiloxane composition is provided. This composition can readily form a cured article having a matted surface without requiring separate step such as mechanical surface roughening, and this composition is well adapted for use as a potting material or a coating material in electric and electronic components such as LED. An article having a matted surface produced by curing such composition is also provided. The liquid organopolysiloxane composition for matting comprises (A) 100 parts by weight of a thermosetting liquid organopolysiloxane composition, and (B) 0.1 to 100 parts by weight of a hollow filler having a melting point of at least 150° C., a specific weight of 0.01 to 0.8, and a particle size of up to 200 μm. The composition has a viscosity at room temperature of 100 to 100,000 mPa·s. The resulting cured article has a surface glossiness of up to 40.

Description

CROSS-REFERENCE TO RELATED APPLICATION[0001]This non-provisional application claims priority under 35 U.S.C. §119(a) on Patent Application No. 2006-158090 filed in Japan on Jun. 7, 2006, the entire contents of which are hereby incorporated by reference.TECHNICAL FIELD[0002]This invention relates to a flowable liquid organopolysiloxane composition for producing a cured article having a matted surface. This invention also relates to a cured article having a matted surface.BACKGROUND ART[0003]A liquid organopolysiloxane (silicone rubber) composition which is flowabile at room temperature and which cures by heating or the like has been widely used as a potting material or coating material in various fields such as construction and industry.[0004]An article produced by curing such liquid silicone rubber composition had a smooth and glossy surface, and when such composition is used for sealing, adhesion, or electric insulation of a liquid crystal display (LED), the surface of the cured co...

Claims

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Application Information

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IPC IPC(8): B32B9/04C08K3/40
CPCC08G77/12C08G77/20C08K7/22Y10T428/24372C08L83/04Y10T428/24421C08L83/00Y10T428/31663C08K3/40C08J9/224C08K3/34
Inventor OZAI, TOSHIYUKIIWATA, MITSUHIRO
Owner SHIN ETSU CHEM IND CO LTD
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