Hot melt pressure sensitive adhesive for paper labels

a technology of adhesives and labels, applied in the direction of adhesives, thin material handling, transportation and packaging, etc., can solve the problems of label tear on any attempt to remove, change of color, change of paper surface of facestock opposite the coated surface, etc., to reduce the tendency to discolor or stain paper, reduce the tendency to discolor or stain, and high tack and adhesive performance

Inactive Publication Date: 2008-06-26
BOSTIK SA
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Benefits of technology

[0012]The HMPSAs according to the present invention exhibit one or more of the following properties: a reduced tendency to discolor or stain paper after being coated thereon, a reduced tend

Problems solved by technology

Once removed from the release liner and adhered to a substrate, these labels tear on any attempt to remove them.
When such HMPSAs are coated onto a support layer (or facestock) made of paper in order to manufacture a label, there is the frequent problem that the color of the paper surface of the facestock opposite the coated surface changes over time, especially during storage at temperatures above room temperature.
This change of color may take the form of s

Method used

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Examples

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Embodiment Construction

[0013]In accordance with one aspect of the present invention, there is provided a hot melt pressure sensitive adhesive (HMPSA) composition comprising:

[0014]a) from 30 to 50% of a mixture of styrenic block copolymers consisting of:[0015]10 to 70% of at least one SX1S triblock copolymer, and[0016]30 to 90% of at least one SX2 diblock copolymer;[0017]wherein:[0018]S represents a polymerized segment of a styrene monomer,[0019]X1 and X2, identical or different, represent each an elastomeric polymerized segment of one or two monomers selected from the group consisting of isoprene, butadiene, and their respective hydrogenated derivatives;[0020]and wherein the overall styrene monomer content in said mixture is comprised between 14 and 40%;

[0021]b) from 40 to 55% of one or more tackifying resin(s) with a softening temperature comprised between 70 and 150° C. comprising a tackifying resin (i) obtainable by hydrogenating, polymerizing or copolymerizing mixtures of aliphatic unsaturated hydroca...

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Abstract

A HMPSA is provided that preferably includes at least a) from 30 to 50% of a mixture of triblock and diblock styrenic copolymers having an overall styrene content comprised between 14 and 40%, b) from 40 to 55% of a tackifying resin with a softening temperature comprised between 70 and 150° C. obtainable by hydrogenating, polymerizing or copolymerizing mixtures of aliphatic unsaturated hydrocarbons having about 5, 9 or 10 carbon atoms; c) from 4 to 20% of a hydrocarbon oil with an aromatic content less than 15%; d) from 1 to 6% of a filler selected among calcium carbonate or a low molecular weight homopolymer or copolymer of polyethylene. A laminated system is also provided that includes at least an adhesive layer utilizing the HMPSA and paper facestock. Also included are PSA labels obtainable from the laminated system with a reduced tendency to discolor after storage.

Description

[0001]The present invention is concerned with a Hot Melt Pressure Sensitive Adhesive (HMPSA) compositions and systems. The HMPSA systems include a laminate comprising an adhesive layer consisting of said HMPSA and a paper facestock. The HMPSA systems also include a permanent Pressure Sensitive Adhesive label obtainable from the laminated system.BACKGROUND OF THE INVENTION[0002]A Pressure Sensitive Adhesive (PSA) is an adhesive whose coating on the surface of paper or film makes it permanently tacky at room temperature and enables the surface to adhere readily on a substrate under light and brief pressure. PSAs are largely used for the manufacturing of labels, in particular paper based labels, which are fixed on articles for information presentation purposes (such as bar code, name, price) and / or for mere ornamental purposes.[0003]PSAs are generally applied by continuous coating processes on a large surface of a support layer, made of a base material (also called facestock) which con...

Claims

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Application Information

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IPC IPC(8): C08L53/00
CPCC08L53/02C08L2205/02C09J153/02C08L53/00C08L2666/24Y10T428/31902
Inventor GOUBARD, DAVIDHAEGER, ROBERT JOHN
Owner BOSTIK SA
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