Method of preparing ceramic powders using chelate precursors

Abstract

Wet-chemical methods involving the use of water-soluble hydrolytically stable metal-ion chelate precursors and the use of a nonmetal-ion-containing strong base can be used in a coprecipitation procedure for the preparation of ceramic powders. Examples of the precipitants used include tetraalkylammonium hydroxides. A composition-modified barium titanate is one of the ceramic powders that can be produced. Certain metal-ion chelates can be prepared from 2-hydroxypropanoic acid and ammonium hydroxide.

Description

CROSS-REFERENCE TO RELATED APPLICATION(S)[0001]The present application is a continuation of U.S. patent application Ser. No. 11 / 369,255, filed Mar. 7, 2006, entitled “METHOD FOR PREPARING CERAMIC POWDERS USING CHELATE PRECURSORS,” naming inventors Richard D. Weir and Carl W. Nelson, which application is incorporated by reference herein in its entirety.FIELD OF THE DISCLOSURE[0002]The present invention relates to methods for preparing ceramic powders, and particularly to wet-chemical processes using chelate precursors.BACKGROUND[0003]Ceramic powders are used in the fabrication of numerous different types of devices including specialized mechanical components, coating for mechanical components, semiconductor devices, superconducting devices, device packaging, passive electronic components such as capacitors, and more sophisticated energy storage devices. Numerous different techniques exist for the synthesis and fabrication of ceramic powders including solid phase synthesis such as sol...

AI Technical Summary

Benefits of technology

This approach results in high-purity ceramic powders with improved electrical properties and reduced contamination, enabling higher relative permittivities and dielectric breakdown strengths, while minimizing processing steps and avoiding the incorporation of unwanted contaminants.

Problems solved by technology

Despite the advantages of wet chemical processes, the ceramics industry largely remains reluctant to employ these techniques.

Because of the often wide disparity in particle size among the various commercially available starting powders (and even significant variation in particle size of the same powder from lot to lot), an optimum result from ball milling rarely occurs, and a contamination-free product is never obtained.

Moreover, additional processing steps are still required.

Of course, this increases the amount of ball-milling wear debris added to the powder, thereby increasing the amount of contamination in the end ceramic product.

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