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Anti-veining additive for the production of casting molds and cores

a technology of additives and casting molds, applied in the field of additives, can solve the problems of reducing the mechanical strength of the core, affecting the mold quality,

Inactive Publication Date: 2013-10-10
ASK CHEM ESPANA
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Benefits of technology

The invention provides cores and molds that have the same mechanical performance as traditional sand-based cores and molds, but without the issue of veining. Additionally, the gas produced by the invention is significantly reduced and stabilizes after 20 minutes, similar to other commercial anti-veining additives.

Problems solved by technology

The castings obtained using cores and molds manufactured with molding sands generally have a series of shape defects that must be later machined to obtaining a dimensionally suitable part.
These defects occur because the core or mold experiences heating due to the effect of the molten metal which is poured therein, which causes its expansion and, as a consequence, the occurrence of cracks on its surface.
Nevertheless, in addition to not eliminating the veining in many cases, this technique has the drawbacks of the iron oxide reducing the mechanical strength of the core and, furthermore, the formation of fayalite increases the tendency of penetration causing the outer surface of the part obtained to have irregularities which must be later treated.
The problem again is the reduction of the mechanical strength of the core.
The main drawback of this technique is that since the flour burns, a large amount of gas is produced which, when diffuse, can lead to dimensional problems in the obtained parts.
The drawback of this technique is that the cores obtained have a certain tendency to penetration, the application of paints or other treatments on the surface of the cores obtained being necessary before casting the part.
The problem of these hollow microspheres is that when they are used in amounts less than 10% by weight in the sand mixture they do not give optimal results, i.e., they do not always prevent veining to the extent that is required.

Method used

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  • Anti-veining additive for the production of casting molds and cores
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  • Anti-veining additive for the production of casting molds and cores

Examples

Experimental program
Comparison scheme
Effect test

example 1

Thermal Analysis of Different Types of Microspheres

[0048]The thermal performance of different types of hollow microspheres the composition of which is detailed in the following Table 1, was analyzed:

TABLE 1Composition of the microspheres in % by weightSample 1Sample 2Sample 3Sample 4Sample 5SiO255.767.159.158.055.6Al2O328.816.727.830.238.3Fe2O36.44.094.663.761.91CaO0.752.021.852.410.96MgO1.551.510.971.290.4Na2O0.430.90.580.210.35K2O4.363.922.252.140.57TiO21.390.791.041.991.07PPC0.622.971.7500.84

[0049]The melting test was carried out in a MISURA hot-stage microscope. The hot-stage microscope is an equipment which allows observing a sample when it is subjected to a heating cycle. At the same time it allows recording the outline of the sample throughout the melting test in a data carrier. The evolution of the shrinkage of the sample depending on the temperature was determined from the recorded images by means of image analysis equipment.

[0050]A cylindrical button 3 mm in diameter and 3...

example 2

Effect of Lithium Carbonate and Strontium Carbonate on the Thermal Properties of the Microspheres

[0059]The thermal performance of the same samples from the Example 1 with the addition of 6% lithium carbonate and 6% strontium carbonate, respectively, was analyzed. The same methodology of analysis as that in claim 1 was used.

[0060]The results for the samples to which 6% lithium carbonate was added are represented in the following Table 3:

TABLE 3thermal analysis of the microspheres with lithium carbonate94% Sample94% Sample94% Sample100%1 +5 +2 +MixtureSample 56% Co3Li6% Co3Li6% Co3LiT Start1,1551,0851,215  890Shrinkage (TSS)T End Shrinkage1,5501,2101,3201,035(TES)T Softening (TS)1,2401,3501,155-1,170SPHERE (TSp)HEMISPHERE1,2701,340-51,210(TSp)T Melting (TM)1,2951,3501,230

[0061]The data relating to sample 5 together with 6% of lithium carbonate and 6% of strontium carbonate are represented both in Table 4 and in FIG. 3.

TABLE 4(94% Sample 5 +(94% Sample 5 +Sample 56% Co3Li)6% Co3Sr)T St...

example 3

Preparation of Casting Cores with Different Additives and Evaluation of the Veining and the Skin of the Resulting Parts

[0062]Cores were prepared from 94% Echave C-70 sand, 1% ISOCURE FOCUS® 418 / 618 phenolic-urethane resin, and 5% of the additive (94% of the microsphere sample+6% Co3Li). The 3 components were mixed in a grinder and the mixture was introduced in the in the hopper of a core shooting machine. The mixture was shot into the core box to obtain the shape of the core and it was gassed with amine. The cured cores were extracted with their final shape.

[0063]A veining test was performed and the skin of the metal parts obtained from the use of different additives according to the invention was also observed. The following Table shows the results:

TABLE 5Mixture94%94%94%94%100%SampleSampleSampleSampleSample1 + 6%5 + 6%5 + 6%2 + 6%100%5Co3LiCo3LiCo3LiCo3LiSandAddition to10%5%5%3%5%0%the sandVEINING7001010SKIN10000 0

[0064]As can be observed, the use of 6% lithium carbonate as a comp...

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Abstract

The present invention belongs to the field of the additives for molding sands used in the manufacture of casting molds and cores. More specifically, the present invention relates to an additive to prevent veining in the manufacture of metal parts, to a molding sand comprising said additive, to a core or mold prepared from said molding sand and to a metal part prepared by means of using one of said cores or molds.

Description

FIELD OF THE INVENTION[0001]The present invention belongs to the field of additives for molding sands used in the manufacture of casting molds and cores. More specifically, the present invention relates to an additive to prevent veining in the manufacture of metal parts, to a molding sand comprising said additive, to a core or mold prepared from said molding sand and to a metal part prepared by means of using one of said cores or molds.BACKGROUND OF THE INVENTION[0002]The castings obtained using cores and molds manufactured with molding sands generally have a series of shape defects that must be later machined to obtaining a dimensionally suitable part. These defects occur because the core or mold experiences heating due to the effect of the molten metal which is poured therein, which causes its expansion and, as a consequence, the occurrence of cracks on its surface. The molten metal penetrates into these cracks, thus forming a type of partitions or lamellas on the surface of the p...

Claims

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Application Information

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Patent Type & Authority Applications(United States)
IPC IPC(8): B22C1/02B22C1/22
CPCC04B26/00B22C1/188C04B35/653C04B2111/00939C04B2235/3201C04B2235/3203C04B2235/3206C04B2235/3208C04B2235/3213C04B2235/3232C04B2235/3272C04B2235/442C04B2235/528C04B2235/72C04B35/18B22C1/22B22C1/02C04B14/041C04B22/10C04B20/002C04B14/02C04B14/06
Inventor PRAT URREIZTIETA, SANTIAGOMENDIZABAL CASTELLANOS, MARCO ANTONIOPUERTOLLANO ABASCAL, MARIA JOSEREINA RIVERO, JES S
Owner ASK CHEM ESPANA