Unlock instant, AI-driven research and patent intelligence for your innovation.

Improved method for converting residues incorporating deep hydroconversion steps and a deasphalting step

Active Publication Date: 2021-04-08
INST FR DU PETROLE
View PDF0 Cites 9 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Benefits of technology

This patent describes a way to improve the process for making fuel oil using a catalyst that includes a specific type of clay, called a zeolite. The process involves modifying the process steps to increase the conversion of certain parts of the oil-making process while reducing the overall complexity of the oil. By using specific zeolites, the process can also produce more propylene and isobutene, which are important components of fuel oil.

Problems solved by technology

The large amount of asphalt produced limits the maximum level of overall conversion of the process.
This simple and economical process makes possible thermal integration within one and the same reaction section and makes it possible to obtain a DAO of good quality; nevertheless, the asphalt yields are high, which limits the maximum overall conversion achievable by this process.
The overall conversion of this process is limited by the unconverted heavy effluent.

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • Improved method for converting residues incorporating deep hydroconversion steps and a deasphalting step

Examples

Experimental program
Comparison scheme
Effect test

example 1

not in Accordance with the Invention

[0142]Scheme having a high hourly space velocity and high temperature (overall HSV=0.3 h−1+431 / 431° C.)+deasphalting stage (SDA)

[0143]In this example, two ebullating-bed reactors (first and second deep hydroconversion section) are positioned in series, operated at high hourly space velocity (HSV) and high temperature with an inter-step separation section and a downstream deasphalting process.

Hydroconversion Section A

[0144]The fresh feedstock of table 1 is sent in its entirety into the first ebullating-bed hydroconversion section A, in the presence of hydrogen, which section comprises a three-phase reactor a NiMo / alumina hydroconversion catalyst exhibiting a NiO content of 4% by weight and a MoO3 content of 9% by weight, the percentages being expressed with respect to the total weight of the catalyst. The section operates as an ebullating bed having upflow of liquid and of gas.

[0145]The conditions applied in the hydroconversion section A are presen...

example 2

According to the Invention

[0154]Scheme according to the invention having a low hourly space velocity (overall HSV=0.089 h−1+411 / 411° C.) and having a low temperature+SDA

[0155]In this example, the present invention is illustrated in a process scheme with two ebullating-bed reactors positioned in series, operated at low hourly space velocity (HSV=0.089 h−1) and at low temperature (411 / 411° C.) and with an inter-step separation section and a downstream deasphalting process, as described in connection with FIG. 1.

Hydroconversion Section A

[0156]The fresh feedstock of table 1 is sent in its entirety into the first ebullating-bed hydroconversion section A, in the presence of hydrogen, which section comprises a three-phase reactor containing a NiMo / alumina hydroconversion catalyst exhibiting a NiO content of 4% by weight and a MoO3 content of 9% by weight, the percentages being expressed with respect to the total weight of the catalyst. The section operates as an ebullating bed having upflo...

example 3

not in Accordance with the Invention

[0167]Scheme having a high hourly space velocity and having a moderate temperature (overall HSV=0.3 h−1+420 / 420° C.)+SDA deasphalting stage

[0168]In this example, the operation is carried out with two ebullating-bed reactors positioned in series (first and second deep hydroconversions), which are operated at high hourly space velocity (HSV) and at moderate temperature (420° C.) with an inter-step separation section and a downstream deasphalting process.

Hydroconversion Section A

[0169]The fresh feedstock of table 1 is sent, in its entirety, into an ebullating-bed hydroconversion section A, in the presence of hydrogen. The three-phase reactor contains a NiMo / alumina hydroconversion catalyst exhibiting a NiO content of 4% by weight and a MoO3 content of 9% by weight, the percentages being expressed with respect to the total weight of the catalyst. The section operates as an ebullating bed having upflow of liquid and of gas.

[0170]The conditions applied ...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

PUM

No PUM Login to View More

Abstract

The invention concerns a method for converting heavy hydrocarbon feedstocks of which at least 50% by weight boils at a temperature of at least 300° C., and in particular vacuum residues. The feedstocks are subjected to a first step a) of deep hydroconversion, optionally followed by a step b) of separating a light fraction, and a heavy residual fraction is obtained from step b) of which at least 80% by weight has a boiling temperature of at least 250° C. Said fraction from step b) or the effluent from step a) is then subjected to a second step c) of deep hydroconversion. The overall hourly space velocity for steps a) to c) is less than 0.1 h−1. The effluent from step c) is fractionated to separate a light fraction. The heavy fraction obtained, of which 80% by weight boils at a temperature of at least 300° C., is sent to a deasphalting step e). The deasphalted fraction DAO is then preferably converted in a step f) chosen from ebullated bed hydroconversion, fluidised bed catalytic cracking and fixed bed hydrocracking.

Description

[0001]The present invention relates to the conversion of heavy hydrocarbon feedstocks including at least 50% by weight of a fraction having a boiling point of at least 300° C. These are crude oil or feedstocks resulting, directly or after treatment, from the atmospheric and / or vacuum distillation of a crude oil, such as atmospheric or vacuum residues.[0002]It is relatively difficult to enhance these oil residues in value, both from a technical viewpoint and from an economic viewpoint. This is because new regulatory constraints are drastically lowering the maximum admissible content of sulfur in bunker fuel oils (from 3% by weight to 0.5% by weight of sulfur). In addition, the market is in particular demanding fuels which can be distilled at atmospheric pressure at a temperature of less than 380° C., indeed even less than 320° C.PRIOR ART[0003]Patent FR 2 906 814 of the Applicant Company describes a process comprising successively linking together a deasphalting stage, producing a de...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

Application Information

Patent Timeline
no application Login to View More
IPC IPC(8): C10G67/04C10G69/04C10G47/30C10G47/02
CPCC10G67/049C10G67/0463C10G69/04C10G47/30C10G2300/4006C10G2300/4018C10G2300/206C10G2300/4012C10G47/02C10G55/06C10G65/18
Inventor MARQUES, JOAODREILLARD, MATTHIEUFEUGNET, FREDERICLE COZ, JEAN-FRANCOIS
Owner INST FR DU PETROLE
Features
  • R&D
  • Intellectual Property
  • Life Sciences
  • Materials
  • Tech Scout
Why Patsnap Eureka
  • Unparalleled Data Quality
  • Higher Quality Content
  • 60% Fewer Hallucinations
Social media
Patsnap Eureka Blog
Learn More