Improved method for converting residues incorporating deep hydroconversion steps and a deasphalting step
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example 1
not in Accordance with the Invention
[0142]Scheme having a high hourly space velocity and high temperature (overall HSV=0.3 h−1+431 / 431° C.)+deasphalting stage (SDA)
[0143]In this example, two ebullating-bed reactors (first and second deep hydroconversion section) are positioned in series, operated at high hourly space velocity (HSV) and high temperature with an inter-step separation section and a downstream deasphalting process.
Hydroconversion Section A
[0144]The fresh feedstock of table 1 is sent in its entirety into the first ebullating-bed hydroconversion section A, in the presence of hydrogen, which section comprises a three-phase reactor a NiMo / alumina hydroconversion catalyst exhibiting a NiO content of 4% by weight and a MoO3 content of 9% by weight, the percentages being expressed with respect to the total weight of the catalyst. The section operates as an ebullating bed having upflow of liquid and of gas.
[0145]The conditions applied in the hydroconversion section A are presen...
example 2
According to the Invention
[0154]Scheme according to the invention having a low hourly space velocity (overall HSV=0.089 h−1+411 / 411° C.) and having a low temperature+SDA
[0155]In this example, the present invention is illustrated in a process scheme with two ebullating-bed reactors positioned in series, operated at low hourly space velocity (HSV=0.089 h−1) and at low temperature (411 / 411° C.) and with an inter-step separation section and a downstream deasphalting process, as described in connection with FIG. 1.
Hydroconversion Section A
[0156]The fresh feedstock of table 1 is sent in its entirety into the first ebullating-bed hydroconversion section A, in the presence of hydrogen, which section comprises a three-phase reactor containing a NiMo / alumina hydroconversion catalyst exhibiting a NiO content of 4% by weight and a MoO3 content of 9% by weight, the percentages being expressed with respect to the total weight of the catalyst. The section operates as an ebullating bed having upflo...
example 3
not in Accordance with the Invention
[0167]Scheme having a high hourly space velocity and having a moderate temperature (overall HSV=0.3 h−1+420 / 420° C.)+SDA deasphalting stage
[0168]In this example, the operation is carried out with two ebullating-bed reactors positioned in series (first and second deep hydroconversions), which are operated at high hourly space velocity (HSV) and at moderate temperature (420° C.) with an inter-step separation section and a downstream deasphalting process.
Hydroconversion Section A
[0169]The fresh feedstock of table 1 is sent, in its entirety, into an ebullating-bed hydroconversion section A, in the presence of hydrogen. The three-phase reactor contains a NiMo / alumina hydroconversion catalyst exhibiting a NiO content of 4% by weight and a MoO3 content of 9% by weight, the percentages being expressed with respect to the total weight of the catalyst. The section operates as an ebullating bed having upflow of liquid and of gas.
[0170]The conditions applied ...
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