Process of combining ceramic layer onto surface of iron base material

A technology of iron-based material and surface compounding, applied in metal material coating process, superimposed layer plating, coating and other directions, can solve the problem of easy peeling of coating, difficulty in controlling film thickness, limited protective effect of iron-based materials, etc. problems, to achieve the effect of preventing diffusion, high hardness and high temperature resistance, and strong technical adaptability

Inactive Publication Date: 2009-07-15
JIANGSU UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The main protection method currently used is to apply paint to the surface of iron-based materials, which can reduce the direct contact between aluminum and iron-based materials to a certain extent. limited protection
Xie Shiyue et al. ("Research on Carbon Steel Hot Dip Aluminum Plating and Micro-arc Oxidation", Light Alloy Processing Technology, No. 9, 2003: 35-38) proposed a combination of hot-dip aluminum plating technology and micro-arc oxidation technology. method to obtain an oxide ceramic film on the surface of steel, but it is still difficult to control the film thickness

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0011] Dry the iron-based material at 350°C for half an hour to remove oil (grease), then use 20% hydrochloric acid solution for rust removal, and wash it with cold water after rust removal. Boil the workpiece treated above for 10 minutes to eliminate the cleaning solution that may remain inside the workpiece during the degreasing and rust removal process. The boiled workpiece is painted with 8% potassium fluozirconate aqueous solution, and the workpiece is dried at 350° C. for 30 minutes after painting. After the workpiece is dried, it can be immersed in the pure aluminum liquid, and the workpiece is dip-coated in the pure aluminum liquid for 2 minutes to obtain a hot-dip aluminum layer with a thickness of about 100 microns. For the above-mentioned iron-based material dipped and plated with aluminum, adopt aluminum anodic oxidation technology (oxidation electrolyte: 5% oxalic acid, 10% phosphoric acid, 1% stabilizer, the rest is water, the temperature of the electrolyte is 30...

Embodiment 2

[0013] Use 10% NaOH aqueous solution to degrease (grease) the iron-based material, then use 20% hydrochloric acid solution for derusting treatment, and wash with cold water after derusting. Boil the workpiece treated above for 10 minutes to eliminate the cleaning solution that may remain inside the workpiece during the degreasing and rust removal process. The boiled workpiece is soaked in 6% potassium fluozirconate aqueous solution, and after soaking for 5 minutes, the workpiece is taken out and dried at 450° C. for 20 minutes. After the workpiece is dried, it can be immersed in the pure aluminum liquid, and the workpiece is dip-coated in the pure aluminum liquid for 30 seconds to obtain a hot-dip aluminum layer with a thickness of about 30 microns. For the above-mentioned iron-based material dipped and plated with aluminum, the commonly used aluminum anodic oxidation technology (oxidation electrolyte: 5% oxalic acid, 10% phosphoric acid, 1% stabilizer, the rest is water, the ...

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Abstract

The present invention proposes a combination of hot-dip aluminum plating technology and aluminum anodic oxidation technology to composite the ceramic layer on the surface of iron-based materials, that is, to carry out conventional degreasing (grease) treatment on iron-based materials, and then use hydrochloric acid solution to degrease Rust treatment, wash with cold water after rust removal. After the above-mentioned iron-based material is boiled, it is soaked in 6-8% potassium fluozirconate aqueous solution for 2-10 minutes or directly painted. After soaking or brushing, take it out and dry it at 350-450°C for 20-30 minutes. After drying, immerse in pure aluminum liquid for 10 seconds to 2 minutes, and then use aluminum anodic oxidation technology to oxidize all or part of the aluminum on the surface of the iron-based material into Al2O3 to obtain a ceramic layer composite iron-based material with a surface layer of Al2O3. The technology of the present invention has strong adaptability, can be applied to various types of workpieces such as wires, nets, plates, rods, tubes, etc., and can obtain high-temperature oxidized ceramic layers with different thicknesses; the alumina obtained by anodic oxidation has high hardness and High temperature resistance, can effectively prevent the diffusion of iron into aluminum.

Description

technical field [0001] The invention relates to a method for compounding a ceramic layer on the surface of an iron-based material. Specifically, the present invention relates to a technical method for compounding a ceramic layer on the surface of an iron-based material by combining the hot-dip aluminum plating technology with the aluminum anodic oxidation technology. Background technique [0002] Iron-based materials have strong and tough characteristics, so they are widely used in the production of tools and filter screens for aluminum alloy smelting. However, when iron-based materials are in contact with aluminum alloy solutions at high temperatures, they are easily dissolved into aluminum to form brittle iron-aluminum phases, which deteriorate the performance of aluminum alloy materials and increase production costs. For example, in the production process of aluminum alloy wheels, barbed wire is used as a filter in the pouring process. Since the filter used every time i...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C23C28/00C23C2/12C25D11/04C23G1/00
Inventor 陈刚赵玉涛程晓农
Owner JIANGSU UNIV
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