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Water steam correcting absorptive pool based on saturated steam pressure

An absorption cell and water vapor technology, which is applied in the direction of color/spectral characteristic measurement, etc., can solve the problems of low detection sensitivity and water vapor difficulty, and achieve the effect of simple and feasible method, low cost, and reduced etalon effect

Inactive Publication Date: 2009-10-28
ANHUI INST OF OPTICS & FINE MECHANICS - CHINESE ACAD OF SCI
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Problems solved by technology

Direct absorption spectroscopy is a gas measurement method that does not require calibration, but it is easily affected by background noise and the detection sensitivity is very low. In order to improve the detection sensitivity, the method of wavelength modulation is generally used. This method must be performed at a known temperature. Calibrate the gas with known concentration, but it is very difficult to obtain water vapor with known concentration and temperature in reality, so the method based on saturated vapor pressure is used to measure H 2 O Calibration is a feasible and effective method

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  • Water steam correcting absorptive pool based on saturated steam pressure

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Embodiment Construction

[0011] The meanings of the labels in Fig. 1 are as follows: 1, air pump, 2, vacuum pump, 3, three-way piston, 4, two-way piston, 5, flushing pipe, 6, constant temperature water bath, 7, glass window, 8, butterfly valve 1 , 9. Glass pipe, 10. Butterfly valve 2, 11. Butterfly valve 3, 12. Condenser tube, 13. Precision digital pressure gauge, 14. Stainless steel cylinder, 15. High-precision thermometer, 16. U-shaped equipotential gauge , 17, round bottle 18, magnetic stirrer

[0012] The heatable calibrated absorption cell uses the principle of saturated vapor pressure: at a certain temperature, the pure liquid reaches equilibrium with its vapor, and the vapor pressure at this time is called the saturated vapor pressure at that temperature, and this temperature is the boiling point at that pressure. For a liquid, a boiling point corresponds to a unique saturated vapor pressure, that is, a temperature corresponds to a unique saturated vapor pressure. Measure the saturated vapor p...

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Abstract

The invention discloses a water vapor calibration absorption pool based on saturated vapor pressure, which is characterized in that it includes a constant temperature water bath, a thermometer, a U-shaped equipotential meter, and a round bottle are placed in the constant temperature water bath, and the round bottle 1. One end of the U-shaped equipotential meter is connected to the stainless steel cylinder. There is a conduit on the stainless steel cylinder connected to the vacuum pump through the two-way piston. The other end of the U-shaped equipotential meter is connected to a conduit. It is divided into two circuits, one of which is connected to the pressure gauge, and the other is connected to the air pump through the three-way piston; there are symmetrical transparent windows at both ends of the stainless steel cylinder, and the outlets of nitrogen pipes are installed on the outside of the transparent windows. The measurement range is between -101.30kPa-101.30kPa, and the temperature control accuracy is ±0.05°C. It is a simple, convenient and cheap laboratory instrument.

Description

technical field [0001] The invention belongs to a gas calibration instrument, in particular to a heatable water vapor calibration absorption pool based on saturated vapor pressure. Background technique [0002] As one of the main products of hydrocarbon combustion, H 2 The emission of O is an important indicator of combustion efficiency, and the emission of H in the combustion process 2 Continuous online monitoring of O concentration is an effective means to achieve effective control of the combustion process and timely adjustment of fuel input, thereby improving combustion efficiency and saving energy. At the same time, in order to achieve effective control of the combustion process, many related industrial productions need to control the H in the combustion process. 2 O.CO 2 Real-time measurement of emissions, which limits the application of traditional sampling-based gas detection methods such as gas chromatography, wet chemical methods, etc., because the extraction me...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): G01N21/39G01N21/27
Inventor 夏慧刘文清张玉钧阚瑞锋陈东王铁栋王敏崔益本
Owner ANHUI INST OF OPTICS & FINE MECHANICS - CHINESE ACAD OF SCI
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