Compound, charge transporting material and organic electroluminescent element
A technology of electroluminescent components and electron transport materials, which is applied in the field of charge transport materials and new compounds, can solve the problems of oxidation degradation of electron transport layer materials, expensive peripheral device drive circuits, insufficient luminous efficiency of components, etc., and achieve excellent amorphousness , excellent oxidation-reduction stability, and the effect of increasing technical value
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[0465] Hereinafter, the present invention will be described in more detail with reference to Examples. However, the present invention is not limited to the following examples as long as the gist of the present invention is not exceeded.
Synthetic example
[0467] Synthesis examples of the compounds of the present invention and compounds useful as the charge transport material of the present invention are given in Synthesis Examples 1 to 26 below. The glass transition temperature is determined by DSC measurement, the vaporization temperature is determined by Tg-DTA measurement, and the melting point is determined by DSC measurement or Tg-DTA measurement.
Synthetic example 1
[0468] (Synthesis Example 1) Final Product 1 to Final Product 2
[0469]
[0470] Final product 1
[0471] Sulfuric acid (8.0 ml) was added to a mixture of isophthalaldehyde (2.7 g), acetophenone (9.6 g) and acetic acid (57 ml) at room temperature under an atmospheric atmosphere, followed by stirring at room temperature for 6 hours. After methanol (50 ml) was added to the resulting solution and stirred, the precipitate was collected by filtration and washed with methanol, whereby the final product 1 (2.6 g) was obtained.
[0472]
[0473] Final product 2
[0474]The final product 1 (2.6g), 1-phenylacetylpyridinium bromide (6.3g), ammonium acetate (29g), acetic acid (130ml) and N,N-dimethylformamide (130ml) were dissolved in a stream of nitrogen It was stirred for 8.5 hours while heating under reflux, and water (80 ml) and methanol (80 ml) were added to the resulting solution, followed by stirring. The obtained precipitate was collected by filtration, washed with metha...
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