The invention relates to an oxidation reaction catalyst of telluriferous
alkane ammonia, which comprises a
silicon dioxide carrier and a combination which is calculated according to the
atomic ratio and comprises the following general formula: MovaNbbTecDdOx, wherein D is at least one selected form Sn, Ti, Fe, Bi, Sb or W. The oxidation reaction catalyst mainly solves the problems that Te is easy to volatilize, the preparation technology is complex, the preparation environment is unstable, and the
active component of the catalyst is easy to volatilize, thereby resulting in bad stability of the catalyst in the prior art; and the oxidation reaction catalyst better solves the problems through adopting the technical proposal that Mo-V-Nb-Te base is used as the main component, the
hydrothermal synthesis method is adopted, the preparation environment is changed through adding
reducing agent and acid during the preparation process, that is, firstly the solution of the corresponding salt or the corresponding
oxide compound of Mo and Te is mixed with the solution of the corresponding salt or the corresponding
oxide compound of V and Nb, then a specified volume of
reducing agent and acid are added to adjust the pH value, and
hydrothermal treatment is performed to the uniformly
mixed solution. The catalyst has the advantages that the catalyst has good
oxidation reduction stability, the
reaction temperature is low, the
reaction product is clean, and high yield coefficient can be kept for a long time, and the catalyst can be applied to the industrial production for the preparation of the unsaturated acid
nitrile in the
alkane ammonia oxidation reaction.