A high-impregnation non-alkali glass fiber sizing agent for LFT reinforced polypropylene and its application, the sizing agent includes a pH regulator, a silane coupling agent, a film-forming agent A, a film-forming agent B, a lubricant, a surface Active agent, antioxidant and deionized water, film-forming agent A is polypropylene wax emulsion modified by maleic anhydride grafting, film-forming agent B is polyethylene emulsion modified by maleic anhydride grafting, lubricant is PEG The combination of lubricants and mineral oil lubricants, the surfactant is a combination of microcrystalline wax emulsion and cationic polyacrylamide emulsion, and the antioxidant is hypophosphite. The present invention also provides the application of the sizing agent in the production of alkali-free glass fibers for LFT-reinforced polypropylene. The glass fibers produced by the sizing agent have good interfacial bonding properties and can be rapidly compatible with polypropylene resin at high temperatures. The impregnation speed is fast, and it also has good manufacturability, good wear resistance, less hairiness, and high impregnation properties, which can improve production efficiency and reduce production costs.