Catalyst for water vapor reformation of ethanol to prepare hydrogen and its prepn and use

A steam reforming and catalyst technology, applied in chemical instruments and methods, metal/metal oxide/metal hydroxide catalysts, physical/chemical process catalysts, etc., can solve the problem of easy carbon deposition, unfavorable hydrogen production process, hydrogen Low selectivity and other problems, to achieve the effect of high conversion rate, cheap source of raw materials, and simple preparation method

Active Publication Date: 2007-08-22
YUNNAN ZHENGBANG SCI & TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Among copper-based catalysts, ZnO and SiO are mainly studied 2 、Cr 2 o 3 , Nb 2 o 5 Carrier supported copper catalyst, the catalyst has better activity at low temperature, but the hy

Method used

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Examples

Experimental program
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Embodiment 1

[0021] A catalyst for hydrogen production by steam reforming of ethanol is loaded with Ni-Fe on a composite carrier of aluminum oxide and silicon dioxide. In this embodiment, nickel oxide-iron oxide can also be loaded on the composite carrier of aluminum oxide and silicon dioxide.

Embodiment 2

[0023] A catalyst for hydrogen production by steam reforming of ethanol is loaded with Ni-Co on a composite carrier of aluminum oxide and silicon dioxide. In this embodiment, nickel oxide-cobalt oxide can also be loaded on the composite carrier of aluminum oxide and silicon dioxide.

Embodiment 3

[0025] The invention discloses a catalyst for hydrogen production by steam reforming of ethanol, in which Ni-Cu is loaded on a composite carrier of aluminum oxide and silicon dioxide. In this embodiment, nickel oxide-copper oxide can also be loaded on the composite carrier of aluminum oxide and silicon dioxide.

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PUM

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Abstract

The present invention is catalyst for water vapor reformation of ethanol to prepare hydrogen and its preparation process and use. The catalyst is composite alumina and silica carrier supported Ni-Fe, Ni-Co, Ni-Cu, Ni-Zn, Cu-Zn, Cu-Co, Ni-Zr, NiO-LaOx, NiO-CeOx, NiO-YOx, NiO-MgOx or NiO-SrOx. It is prepared through the following steps: preparing catalyst carrier; compounding mixed solution of two kinds of nitrate; prepared turbid liquid of catalyst carrier; adding the mixed solution into the turbid liquid through stirring, evaporating water, stoving, grinding and baking. The catalyst has simple preparation process, low use temperature, high ethanol converting rate, and other advantages.

Description

technical field [0001] The invention relates to a catalyst, a preparation method and application, in particular to a catalyst for hydrogen production, a preparation method and the use of the catalyst for hydrogen production by steam reforming of ethanol, which belongs to the fuel cell hydrogen source technology. Background technique [0002] With the increasing global warming effect and the depletion of non-renewable resources such as petroleum, the disadvantages of fossil fuels have been paid attention to by various countries, and it is urgent to find a non-polluting green fuel that can replace petroleum. As a clean energy, hydrogen is attracting more and more attention. [0003] Hydrogen is an efficient, clean and renewable energy, which will play a significant role in the sustainable development of the global energy system and will have a huge impact on the global ecological environment. Hydrogen itself is renewable and when burned produces only water and no pollutants, ...

Claims

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Application Information

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IPC IPC(8): B01J23/94B01J23/89B01J23/74B01J23/70C01B3/32
CPCY02P20/584
Inventor 张金利张利峰李王一平
Owner YUNNAN ZHENGBANG SCI & TECH
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