Process for producing single crystal and process for producing annealed wafer
Through multiple pulling methods and pulling condition correction technology, the problem of uneven quality of silicon single crystals has been solved, low-cost and efficient production of high-quality silicon single crystals has been achieved, and the defect density of the wafer has been optimized through nitrogen doping and heat treatment technology. Improved device performance and yield.
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Embodiment 1
[0062] A crucible with a diameter of 55 cm is set in the single crystal manufacturing device shown in Figure 1, and in order to use the CZ method to grow a silicon single crystal with a diameter of 20 cm, firstly, 120 kg of polycrystalline silicon raw material is placed in the crucible, and doped with nitrogen, so that the growth The nitrogen concentration of the silicon single crystal becomes 3 x 10 13 atoms / cm 3 . Then, the polycrystalline silicon raw material was melted by heating with a heater, and a silicon single crystal having a body length of 100 cm and a diameter of 20 cm was grown. Next, the polysilicon raw material with the same weight as the single crystal pulled up from the first one was added into the crucible, and the same type of crystal was repeatedly pulled by the multiple pulling method.
[0063] At this time, as shown in FIG. 2 , three kinds of single crystal pulling conditions were prepared according to the time counted from the start of heating by the h...
Embodiment 2
[0066] Next, when the silicon single crystal is grown, the flow rate of the inert gas, that is, argon (as a cleaning gas), is prepared to change the pattern 2' according to the passage of time (this inert gas is introduced from the gas inlet 10, and the After being drawn between the single crystal 3 and the gas rectifying cylinder 11, pass between the heat insulating member 12 and the melt surface of the raw material melt 4, and then flow out from the gas outlet 9), and start heating from the heater From 35 hours to 70 hours (the second one), use this pattern 2' (increase the gas flow rate by 15% compared with the first one), use the same pattern 1 as the first one for the pulling speed, and set other conditions to be the same as In the same manner as in Example 1, evaluation was performed in this manner. As a result, as shown in Figure 5, the density of defects near the surface can be uniformly distributed in the length direction of the single crystal, and the average value o...
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Abstract
Description
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