Non-woven fabric laminate and method for production thereof
A non-woven fabric layer and non-woven fabric technology, applied in the field of non-woven fabric laminates and their manufacturing, can solve the problems of insufficient stretchability, softness, and processability, and achieve less sticking and excellent curl resistance Effect
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[0120] Hereinafter, the present invention will be described more specifically in conjunction with examples, but the present invention is not limited to these examples.
[0121] The physical property values and the like in Examples and Comparative Examples were measured by the following methods.
[0122] (1) Weight per unit area [g / m 2 ]
[0123] Take 6 test pieces of 200 mm (MD) x 50 mm (CD) from the nonwoven fabric and / or the nonwoven fabric laminate. Among them, the positions for taking the test piece are MD and CD at any 3 positions (a total of 6 positions). Next, the mass (g) of each obtained test piece was measured using the upper-pan electronic balance (manufactured by Kenseiko Kogyo Co., Ltd.). Calculate the mass average value of each test piece. Converted from the obtained average value to the equivalent of 1m 2 The mass (g) of each non-woven fabric sample is rounded off to the second place after the decimal point, and it is used as the weight per unit area of ...
manufacture example 1
[0178] In a nitrogen atmosphere, diphenylmethane diisocyanate (hereinafter referred to as MDI) was put into tank A, and the temperature was adjusted to 45° C. while stirring without mixing air bubbles.
[0179] In a nitrogen atmosphere, 628.6 parts by weight of polyester polyol with a number average molecular weight of 2000 (manufactured by Mitsui Takeda Chemical Co., Ltd., trade name: Takeraku U2024), 2.21 parts by weight of IRGANOX 1010 and 77.5 parts by weight of 1,4-butanediol were packed. Put it into tank B and adjust to 95°C while stirring. This mixture is referred to as polyol solution 1.
[0180] The hard segment amount calculated from these reaction raw materials was 37.1% by weight.
[0181] Then, through the infusion pipeline provided with a gear pump and a flow meter in the middle, the MDI is quantitatively delivered to a high-speed mixer (SM40) adjusted to 120° C. ), after stirring and mixing at 2000rpm for 2 minutes, it was delivered to a static mixer. The sta...
Embodiment 1
[0185]
[0186] The MFR of 96 parts by weight (according to ASTM D1238, measured at a temperature of 230°C and a load of 2.16 kg) is 60 g / 10 minutes, and the density is 0.91 g / cm 3 , a propylene homopolymer with a melting point of 160°C (hereinafter referred to as "PP-1") and 4 parts by weight of MFR (according to ASTM D1238, measured at a temperature of 190°C and a load of 2.16kg) is 5g / 10min, and the density is 0.97g / cm 3 and high-density polyethylene (hereinafter referred to as "HDPE") having a melting point of 134° C. were mixed to prepare a thermoplastic resin composition (B-1).
[0187]
[0188] The TPU-1 prepared in the above-mentioned Production Example 1 and the above-mentioned B-1 were independently melted with an extruder (ф30 mm), and then a spunbonded non-woven fabric forming machine with a spinning nozzle (with The length of the direction perpendicular to the direction of travel of the machine is 100mm), the temperature of the resin and the die are both 220...
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