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Formula of environment protection type flame-retardant rubber pipe

A flame retardant adhesive and environmentally friendly technology, applied in the direction of hoses, pipes, pipes/pipe joints/pipe fittings, etc., it can solve the problems of corrosive damage to the whole car, hinder the evacuation of personnel, etc., to improve physical and mechanical properties and reduce costs. Effect

Inactive Publication Date: 2010-11-03
TIANJIN PENGYI GRP CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, once a fire breaks out, the polymer will produce a large amount of smoke and toxic corrosive hydrogen halide gas, causing secondary disasters, which are often more serious than the consequences of burning, causing secondary damage and aftereffects More durable, the car as a whole is subject to corrosive damage, and secondly, the smoke will hinder the evacuation of personnel

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0025] EPDM rubber 100 parts,

[0026] Extrude 20 parts of carbon black (N550) quickly,

[0027] 40 parts paraffin oil,

[0028] Calcined pottery clay 60 parts,

[0029] 160 parts of aluminum hydroxide,

[0030] Zinc borate 5 parts,

[0031] 10 parts of antimony trioxide,

[0032] Dithiuram tetrasulfide (DPTT) 0.5 part,

[0033] 2.0 parts of zinc dibutyldithiocarbamate (BZ),

[0034] Tetramethylthiuram disulfide (TMTD) 0.5 parts,

[0035] 3 parts zinc oxide,

[0036] 1 part stearic acid,

[0037] 3 parts of polyethylene glycol,

[0038] 1.5 parts of morphine disulfide (DTDM),

[0039] Sulfur 0.6 parts.

Embodiment 2

[0041] EPDM rubber 100 parts,

[0042] Extrude 30 parts of carbon black (N550) quickly,

[0043] 30 parts paraffin oil,

[0044] Calcined pottery clay 50 parts,

[0045] 140 parts of aluminum hydroxide,

[0046] 7.5 parts of zinc borate,

[0047] 15 parts of antimony trioxide,

[0048] Dithiuram tetrasulfide (DPTT) 0.8 part,

[0049] 1.8 parts of zinc dibutyldithiocarbamate (BZ),

[0050] Tetramethylthiuram disulfide (TMTD) 0.65 parts,

[0051] Zinc oxide 4 parts,

[0052] 2 parts stearic acid,

[0053] 2 parts polyethylene glycol,

[0054] 1.8 parts of morphine disulfide (DTDM),

[0055] Sulfur 0.45 parts.

Embodiment 3

[0057] EPDM rubber 100 parts,

[0058]Extrude 40 parts of carbon black (N550) quickly,

[0059] 20 parts paraffin oil,

[0060] Calcined pottery clay 40 parts,

[0061] 120 parts of aluminum hydroxide,

[0062] Zinc borate 10 parts,

[0063] 20 parts of antimony trioxide,

[0064] Dithiuram tetrasulfide (DPTT) 0.65 parts,

[0065] 1.5 parts of zinc dibutyldithiocarbamate (BZ),

[0066] Tetramethylthiuram disulfide (TMTD) 0.8 parts,

[0067] Zinc oxide 5 parts,

[0068] 3 parts stearic acid,

[0069] 1 part polyethylene glycol,

[0070] Morphine disulfide (DTDM) 2.0 parts,

[0071] Sulfur 0.3 parts.

[0072] Using the formulation of the above-mentioned embodiment, the physical and mechanical properties tensile strength is 14Mpa, which is 1.5 times higher than that of the traditional formulation, and the national standard of flame retardancy can be obtained. burning effect. And meet the environmental protection and safety requirements of today's automotive hoses.

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Abstract

The invention relates to a formula of an environment-friendly flame retardant hose, which comprises the following compositions and weight portions: 100 portions of ethylene propylene diene rubber, 20 portions to 40 portions of fast extruded carbon black, 40 portions to 60 portions of calcined clay, 120 portions to 160 portions of aluminium hydroxide, 5 portions to 10 portions of zinc borate, 10 portions to 20 portions of antimony trioxide, 0.5 portion to 0.8 portion of thiuram tetrasulfide, 1.5 portions to 2.0 portions of zinc dibutyl dithiocarbamate, 0.5 portion to 0.8 portion of tetramethylthiuram disulfide, 3 portions to 5 portions of zinc oxide, 1 portion to 3 portions of stearic acid, 1 portion to 3 portions of polyethylene glycol, 1.5 portions to 2.0 portions of morpholine disulfide, 0.3 portion to 0.6 portion of sulfur and 20 portions to 40 portions of paraffin oil. Compared with the traditional product, the invention has the tensile strength of physical and mechanical property of 14MPa, which is higher than the traditional formula by 1.5 times. The invention can obtain FV-0 grade of vertical burn of national standard of flame resistance, namely the requirements of nonflammable material, can achieve the same flame resistant effect with the traditional method and meet the requirements of environment protection and safety of the hose of the modern automobile.

Description

technical field [0001] The invention relates to the technical field of rubber hoses, in particular to the formula of environment-friendly flame-retardant rubber hoses. Background technique [0002] Flame retardant hose mainly refers to the cold air hose used in automobiles. The hose is a full hose, that is, only one layer of rubber, and the material is ethylene propylene diene monomer (EPDM for short). The cold air hose of the car works in a high temperature and flammable environment, so its flame retardant performance is very important. Since the main chain of most rubbers contains a large amount of carbon, hydrogen, oxygen and other elements, it is easy to generate combustible gas when heated and melted, and it is easy to burn with oxygen at high temperature. In order to achieve the purpose of flame retardancy, the traditional method is to use halogen-containing polymers and add a large amount of halogen-containing flame retardants. However, once a fire breaks out, the p...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08L23/16C08K13/02C08K3/22C08K3/38C08K3/34F16L11/04
Inventor 张洪起孙佩祝李风海王学荣
Owner TIANJIN PENGYI GRP CO LTD
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