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51 results about "Zinc dibutyldithiocarbamate" patented technology

Zinc dibutyldithiocarbamate is a Standardized Chemical Allergen. The physiologic effect of zinc dibutyldithiocarbamate is by means of Increased Histamine Release, and Cell-mediated Immunity. The chemical classification of zinc dibutyldithiocarbamate is Allergens.

Formula of environment protection type flame-retardant rubber pipe

The invention relates to a formula of an environment-friendly flame retardant hose, which comprises the following compositions and weight portions: 100 portions of ethylene propylene diene rubber, 20 portions to 40 portions of fast extruded carbon black, 40 portions to 60 portions of calcined clay, 120 portions to 160 portions of aluminium hydroxide, 5 portions to 10 portions of zinc borate, 10 portions to 20 portions of antimony trioxide, 0.5 portion to 0.8 portion of thiuram tetrasulfide, 1.5 portions to 2.0 portions of zinc dibutyl dithiocarbamate, 0.5 portion to 0.8 portion of tetramethyl thiuram disulfide, 3 portions to 5 portions of zinc oxide, 1 portion to 3 portions of stearic acid, 1 portion to 3 portions of polyethylene glycol, 1.5 portions to 2.0 portions of morpholine disulfide, 0.3 portion to 0.6 portion of sulfur and 20 portions to 40 portions of paraffin oil. Compared with the traditional product, the invention has the tensile strength of physical and mechanical property of 14MPa, which is higher than the traditional formula by 1.5 times. The invention can obtain FV-0 grade of vertical burn of national standard of flame resistance, namely the requirements of nonflammable material, can achieve the same flame resistant effect with the traditional method and meet the requirements of environment protection and safety of the hose of the modern automobile.
Owner:TIANJIN PENGYI GRP CO LTD

Electrochemical corrosion resistant inner ply compound formula

The invention relates to an inner hose formula for an electrochemical corrosion resistant hose, which comprises the following compositions in portion by weight: 30 to 70 portions of low-mooney ethylene propylene diene rubber, 70 to 30 portions of high-mooney ethylene propylene diene rubber, 60 to 80 portions of semi-reinforcing carbon black, 60 to 90 portions of silica fume, 1.2 to 1.8 portions of bi-thiuram tetrasulfide, 1.7 to 2.3 portions of zinc dibutyl dithiocarbamate, 0.5 to 0.8 portion of tetramethyl thiuram disulfide, 3 to 5 portions of zinc oxide, 1 to 3 portions of polyethylene glycol, 1.5 to 2.0 portions of morphine disulfide, 0.3 to 0.6 portion of sulfur, 50 to 60 portions of paraffin oil, 1 to 3 portions of stearic acid and 2 to 4 portions of 2, 2, 4-trimethyl-1, 2-biquionlyl dihydride polymers. Compared with the prior product, the inner hose formula for the electrochemical corrosion resistant hose has obvious differences; the tensile strength is 12.0 MPa; the volume resistivity is 1X10<12> omega.cm and 1X10<5> omega.cm higher than that of the prior product; the service life of the electrochemical corrosion resistant hose is greatly improved; and the inner hose formula for the electrochemical corrosion resistant hose can well meet the demands of heat resistance and electrochemical corrosion resistance of a radiator hose of a motor vehicle.
Owner:TIANJIN PENGYI GRP CO LTD

Preparation method of silver sulfide-zinc sulfide semiconductor nanometer heterojunction

The invention provides a preparation method of a silver sulfide-zinc sulfide semiconductor nanometer heterojunction. The preparation method comprises a step (A) of enabling reaction precursor silver dibutyl dithiocarbamate to undergo pyrolysis in a mixed solvent to obtain silver sulfide particles; and a step (B) of enabling the silver sulfide obtained in the step (A) to serve as a catalyst, enabling an intermediate product formed by pyrolysis of zinc dibutyl dithiocarbamate to be dissolved in the mixed solvent containing the silver sulfide particles, separating out zinc sulfide nanorods from the silver sulfide particles under the effect of trioctylphosphine and n-octadecyl mercaptan, and forming the silver sulfide-zinc sulfide semiconductor nanometer heterojunction. The preparation method of the silver sulfide-zinc sulfide semiconductor nanometer heterojunction is simple and convenient, high in rate of production and suitable for industrial production. The shape and the structure of the silver sulfide-zinc sulfide semiconductor nanometer heterojunction can be controlled under normal pressure, and the rate of production can be over 80%.
Owner:WENZHOU UNIVERSITY

Ethylene-propylene-diene monomer mould pressing abnormal shape sponge sheath rubber composition

The invention relates to an ethylene-propylene-diene monomer (EPDM) mould pressing abnormal shape sponge sheath rubber composition. The composition includes the components by weight: 100 parts of EPDM rubber, 60-80 parts of semi-reinforcing carbon black, 30-50 parts of paraffin oil, 3-5 parts of zinc oxide, 2-4 parts of stearic acid, 1-3 parts of polyethylene glycol, 0.3-0.5 parts of dibenzothiazole disulfide, 1.3-1.5 parts of zinc dibutyldithiocarbamate, 0.5-0.8 parts of tetramethylthiuram disulfide, 0.3-0.5 parts of dithiuram tetrasulfide, 6.5-7.5 parts of azodicarbonamide, 2.5-3.5 parts of 4,4'-oxybis(benzenesulfonyl hydrazide), and 0.8-1.2 parts of sulfur. The EPDM rubber is used in the invention. By adjusting the ratio of various components in the recipe and process conditions, the abnormal shape sponge sheath with excellent heat aging resistance, small density, stable dimension and smooth and exquisite surface can be prepared.
Owner:TIANJIN PENGYI GRP CO LTD

Colorized ethylene propylene terpolymer rubber sealing strip and preparation method thereof

The invention relates to a colorized ethylene propylene terpolymer rubber sealing strip which is prepared from the following raw materials in parts by weight: 90-100 parts of ethylene propylene terpolymer rubber, 160-180 parts of complex mineral filler, 60-80 parts of colorless paroline, 0.8-1.2 part of toner, 0.3-0.6 part of sulfur, 1-2 parts of zinc dibutyldithiocarbamate, 0.8-1.5 part of 2-mercaptobenzothiazole, 0.3-0.8 part of tetramethyl thiuram disulfide, 0.2-0.6 part of Zinc dimethyldithiocarbamate, 0.8-2 parts of 4,4'-dithiodimorpholine, 4-6 parts of zinc oxide and 0.8-1.2 part of stearic acid. The colorized ethylene propylene terpolymer rubber sealing strip provided by the invention is easy for extruding production, and has the advantages that the color assortment effect is good, no aromatic hydrocarbon is separated out so that the attractive appearance is ensured, and the ageing resistance and the weather fastness are better.
Owner:JIANGYIN HAIDA RUBBER & PLASTIC GROUP

Preparation method of zinc dibutyldithiocarbamate

The invention relates to the field of rubber vulcanizing promoter and particularly relates to a preparation method of zinc dibutyldithiocarbamate. The preparation method comprises the following stepsof: dropping carbon disulfide into reaction solution containing zinc oxide, dibutylamine, a dispersing agent and a first organic solvent to carry out reaction, and after reaction is ended, obtaining the zinc dibutyldithiocarbamate, wherein the first organic solvent is insoluble in water and the obtained zinc dibutyldithiocarbamate is insoluble or slightly soluble in the first organic solvent. Thepreparation method of the zinc dibutyldithiocarbamate has the beneficial effects that an anhydrous solvent method is adopted to prepare the zinc dibutyldithiocarbamate, so that the generation of salt-containing waste water is avoided; since the first organic solvent is insoluble in water, the first organic solvent and the water can be separated by liquid-separating operation; the first organic solvent after water removal can be repeatedly utilized, so that the solvent cost is reduced and simultaneously the yield of a product is increased; the operation is simple and convenient, the generationof the salt-containing waste water is avoided, and the method is a cleaning environment-friendly new method, and is easily applied in large-scale production practice.
Owner:WILLING NEW MATERIALS TECH CO LTD

Preparation method of one-dimensional heterogeneous nano material of manganese sulfide and zinc sulfide

The invention relates to a one-dimensional heterogeneous nano material of manganese sulfide and zinc sulfide, and belongs to the technical field of nano material preparation. The one-dimensional heterogeneous nano material of manganese sulfide and zinc sulfide is dried to be gray powder, the powder particles are in a cotton swab rod shape, namely, the head of a cotton swab is silver sulfide nano particles, a rod part is composed of segmented zinc sulfide and manganese sulfide, and the material serves as a luminescent material to be applied to photoelectric devices, or serves as a magnetic material to be applied to magnetic devices, serves as an electrode material to be applied to an electrochemical energy storage device. The specific preparation method comprises the following steps: adding a silver sulfide nanoparticle catalyst, zinc dibutyl dithiocarbamate or manganese dibutyl dithiocarbamate into a mixed solvent, and uniformly conducting stirring; conducting heating and heat preserving under inert gas protection or a vacuum condition, adding manganese dibutyl dithiocarbamate or zinc dibutyl dithiocarbamate, uniformly conducting stirring, and under inert gas protection or a vacuum condition, conducting heating, heat preserving and cooling to obtain the material.
Owner:HEFEI UNIV OF TECH

Power cable for ethylene propylene rubber insulating ship

The invention discloses a power cable for an ethylene propylene rubber insulating ship. The power cable comprises a conductor, an insulating layer, an insulation shielding layer, a tape layer, an armoring layer and a sheath layer, and is characterized in that the insulating layer is arranged at the outside of the conductor, so that an insulating wire core is formed; the tape layer, the armoring layer and the sheath layer are sequentially arranged at the outside of the insulating wire core; the insulating layer is prepared from the following raw materials: ethylene propylene rubber, zinc dibutyl dithiocarbamate, polybutadiene, vinyl chloride-vinyl acetate copolymer, butyl chlorocarbonate, dimethylaminoethyl acrylate and the like. The power cable disclosed by the invention has the advantages that good flame resistance, high ageing resistance, high working stability and high reliability are achieved; the insulating layer has excellent flame resistance and excellent insulation property by means of improving the raw materials of the insulating layer, so that the whole service life is long.
Owner:ANHUI GUANGFU CABLE CO LTD

Anti-aging sealing rubber strip for building doors and windows and preparation method thereof

The invention provides an anti-aging sealing rubber strip for building doors and windows and a preparation method thereof, and relates to the field of sealing materials. The anti-aging sealing rubberstrip comprises the following raw materials in parts by weight: 40-60 parts of p-phenylene silicone rubber, 30-40 parts of tin coupling type solution polymerized styrene-butadiene rubber, 30-40 partsof natural rubber, 1-3 parts of zinc methacrylate, 4-8 parts of liquid polyisoprene rubber, 1-1.8 parts of dioctyl sebacate, 10-20 parts of 774 carbon black, 10-20 parts of 550 carbon black, 2- 5 parts of nanometer magnesium hydroxide, 10-15 parts of asphalt-based chopped carbon fibers, 5-10 parts of polyvinylidene chloride, 1-3 parts of microcrystalline wax, 1-3 parts of stearic acid, 0.1-1.2 parts of maleic anhydride grafted ethylene propylene diene monomer, 1-1.5 parts of sulfur, 0.2-0.6 part of dicumyl peroxide, 0.5-1.5 parts of zinc dibutyl dithiocarbamate, 1-2 parts of accelerant, 1-5 parts of reinforcing component and 1.5-2.2 parts of anti-aging agent. The sealing rubber strip has excellent mechanical properties, and the related properties of the sealing rubber strip are slightly changed through a 100 DEG C and 300 h thermo-oxidative aging test and the sealing rubber strip has excellent thermal oxidation resistance and long service life.
Owner:安徽领珂数据科技有限公司

Ethylene propylene diene monomer rubber sealing strip compatible with silicone adhesive

The invention relates to an ethylene propylene diene monomer rubber sealing strip compatible with a silicone adhesive. The sealing strip is prepared by compounding the following raw materials: 100 mass parts of ethylene propylene diene monomer rubber, 45 to 55 mass parts of paroline with the arene content of less than 0.5 percent, 100 to 120 mass parts of carbon black, 0.3 to 0.5 part of sulphur, 1.5 to 2 parts of zinc dibutyldithiocarbamate, 1.2 to 1.5 parts of benzothiazolethiol, 0.3 to 0.5 part of tetramethyl thiuram disulfide, 0.5 to 0.6 part of zinc dimethyldithiocarbamate, and 1.5 to 2 parts of dithiodimorpholine. The ethylene propylene diene monomer rubber sealing strip compatible with the silicone adhesive is compatible with the silicone adhesive, has low cost, high intensity and tearing property, and long service life and can be produced on a large scale.
Owner:JIANGYIN HAIDA RUBBER & PLASTIC GROUP

High-cleanness alcohol-based liquid fuel

The invention provides a high-cleanness alcohol-based liquid fuel, and belongs to the technical field of alcohol-based liquid fuels. The high-cleanness alcohol-based liquid fuel is prepared from methanol, ethanol gasoline and an additive; and the additive is prepared from polyisooctyl methacrylate, 2,4-dimethyl-6-tert-butyl phenol, N,N'-disalicylidene-1,2-propanediamine, dodecyl methacrylate, diethylene glycol monomethyl ether, methyl palmitate, diethylaminoethyl methacrylate, zinc dibutyl dithiocarbamate, 2-n-octyl-4-isothiazolin-3-one, dioctyl phthalate, N-phenyl-N'-sec-butylphenylenediamineand isopropyl benzoate. The alcohol-based liquid fuel has the advantages of small corrosivity to metal parts, good lubricity, high viscosity and high heat value, has reddish brown color, achieves a blue-green combustion fire, does not generate residual liquid, smoke dust, carbon deposition, sulfur dioxide or other harmful gases in the combustion process, and meets environmental protection requirements.
Owner:中油新能源有限公司

Heat-resistant high-strength cable sheath material and preparation method thereof

The invention discloses a heat-resistant high-strength cable sheath material. The material is prepared from, by weight, 50-70 parts of SBR-1712 emulsion polymerized butadiene styrene rubber, 30-50 parts of NBR-3604 butadiene-acrylonitrile rubber, 1-2 parts of N-tertiary butyl-2-benzothiazole sulfenamide, 2-4 parts of N, N'-m-phenylene dimaleimide, 1-2 parts of stearic acid, 0.5-1 part of zinc dibutyl dithiocarbamate, 2-6 parts of paraffin, 0.5-1.5 parts of an anti-aging agent, 3-8 parts of hydroxyapatite powder, 2-5 parts of white oil, 15-25 parts of semi-reinforced carbon black and 10-20 parts of light calcium carbonate. Meanwhile, the invention discloses a preparation method of the heat-resistant high-strength cable sheath material. The heat-resistant high-strength cable sheath material is excellent in processability, heat resistance and mechanical strength, simple in processing technology, great in practicability and easy to popularize.
Owner:SUZHOU KEMAO ELECTRONICS MATERIALS TECH

Preparation method of ternary zinc sulfide manganese nanowire

The invention relates to a preparation method of a ternary zinc sulfide manganese nanowire. The doping amount of manganese is 26 to 84 percent, the nanowire is uniform in size, the diameter is 6.9+ / -1.2 nm and the manganese is doped uniformly; the structural general formula of the ternary zinc sulfide manganese is ZnxMn1-xS, and the numerical range of the subscript x is 0.26 to 0.84; and the ternary zinc sulfide manganese nanowire serves as a magnetic material and is applied to magnetic devices, or serves as a light-emitting material and is applied to photoelectric devices. The preparation method particularly comprises the following steps: adding a silver sulfide (Ag2S) nanoparticle catalyst, zinc dibutyl dithiocarbamate (Zn(ddtc)2) and manganese dibutyl dithiocarbamate (Mn(ddtc)2) into amixed solvent; stirring uniformly, heating to 120 to 140 DEG C under the inert gas protection or vacuum conditions, and performing heat preservation for 5 to 15 minutes to obtain the ternary zinc sulfide manganese nanowire. The raw materials adopted by the process are common simple raw materials, the cost is low, the process controllability is high, the quality of products is high, and batched production and industrialization of the ternary zinc sulfide manganese nanowire are benefited.
Owner:HEFEI UNIV OF TECH

Formula of environment protection type flame-retardant rubber pipe

The invention relates to a formula of an environment-friendly flame retardant hose, which comprises the following compositions and weight portions: 100 portions of ethylene propylene diene rubber, 20 portions to 40 portions of fast extruded carbon black, 40 portions to 60 portions of calcined clay, 120 portions to 160 portions of aluminium hydroxide, 5 portions to 10 portions of zinc borate, 10 portions to 20 portions of antimony trioxide, 0.5 portion to 0.8 portion of thiuram tetrasulfide, 1.5 portions to 2.0 portions of zinc dibutyl dithiocarbamate, 0.5 portion to 0.8 portion of tetramethylthiuram disulfide, 3 portions to 5 portions of zinc oxide, 1 portion to 3 portions of stearic acid, 1 portion to 3 portions of polyethylene glycol, 1.5 portions to 2.0 portions of morpholine disulfide, 0.3 portion to 0.6 portion of sulfur and 20 portions to 40 portions of paraffin oil. Compared with the traditional product, the invention has the tensile strength of physical and mechanical property of 14MPa, which is higher than the traditional formula by 1.5 times. The invention can obtain FV-0 grade of vertical burn of national standard of flame resistance, namely the requirements of nonflammable material, can achieve the same flame resistant effect with the traditional method and meet the requirements of environment protection and safety of the hose of the modern automobile.
Owner:TIANJIN PENGYI GRP CO LTD

Environment-friendly low-smoke flame-retardant rubber composition and preparation method thereof

The invention discloses an environment-friendly low-smoke flame-retardant rubber composition and a preparation method thereof, and the rubber composition comprises the following raw materials: 30-50 parts of natural rubber, 40-50 parts of butadiene styrene rubber, 1-6 parts of a flame retardant, 2-7 parts of a vulcanizing agent, 1-9 parts of an accelerant, 1-5 parts of an anti-aging agent, 2-7 parts of a stabilizer and 4-6 parts of a flexibilizer. The flame retardant is prepared by mixing magnesium hydroxide, tributyl phosphate and tricresyl phosphate according to a ratio of (1-7): (2-6): (1-5), and the vulcanizing agent is prepared by mixing sulfur powder, dicumyl peroxide and dicumyl peroxide according to a ratio of (4-8): (1-5): (6-12). The accelerant is prepared by mixing tetramethyl thiuram disulfide, tetramethyl thiuram monosulfide and zinc dibutyldithiocarbamate according to the ratio of (2-6): (1-8): (1-6), carbon black ash added in a traditional rubber composition is removed, and then the flexibilizer is used for reinforcement, so smoke generated in the combustion process of rubber can be greatly reduced, and the service life of the rubber composition is prolonged. Meanwhile, the flame retardant is added, so that the flame retardant property of the rubber composition can be greatly improved.
Owner:南京固瑞橡胶有限公司

Novel environmental-friendly glue

The invention discloses a novel environmental-friendly glue, relates to the technical field of fine chemical engineering, and particularly relates to a preparation method of the novel environmental-friendly glue. The glue is characterized by being prepared from following raw materials according to the following ratio: 33-50 g of vinyl acetate emulsion, 42-50 g of a vinylacetate copolymer resin, 5-8 g of propyltrimethoxysilane, 2-7 g of dioctyl pyrophosphate, 8-13 g of acrylic acid, 18-36 g of paraffin, 9-15 g of 2-methylaziridine, 7-17 g of furfuralcohol, 4-18 g of polyethylene glycol, 3-6 g of calcium carbonate, 8-10 g of zinc dimethyldithiocarbamate, 0.5-2.8 g of zinc dibutyldithiocarbamate, 2-5 g of octadecanol and 0.1-6 g of unsaturated resin paint. The glue is nontoxic and odorless, and has good viscosity, flexibility and light resistance. The glue can be manufactured simply. The production cost and the raw material cost can be reduced effectively.
Owner:SHENZHEN TAIQIANG CHEM

A kind of preparation method of ternary zinc manganese sulfide nanowire

The invention relates to a preparation method of a ternary zinc sulfide manganese nanowire. The doping amount of manganese is 26 to 84 percent, the nanowire is uniform in size, the diameter is 6.9+ / -1.2 nm and the manganese is doped uniformly; the structural general formula of the ternary zinc sulfide manganese is ZnxMn1-xS, and the numerical range of the subscript x is 0.26 to 0.84; and the ternary zinc sulfide manganese nanowire serves as a magnetic material and is applied to magnetic devices, or serves as a light-emitting material and is applied to photoelectric devices. The preparation method particularly comprises the following steps: adding a silver sulfide (Ag2S) nanoparticle catalyst, zinc dibutyl dithiocarbamate (Zn(ddtc)2) and manganese dibutyl dithiocarbamate (Mn(ddtc)2) into amixed solvent; stirring uniformly, heating to 120 to 140 DEG C under the inert gas protection or vacuum conditions, and performing heat preservation for 5 to 15 minutes to obtain the ternary zinc sulfide manganese nanowire. The raw materials adopted by the process are common simple raw materials, the cost is low, the process controllability is high, the quality of products is high, and batched production and industrialization of the ternary zinc sulfide manganese nanowire are benefited.
Owner:HEFEI UNIV OF TECH
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