Method for preparing ethanol by using raw material containing cellulose

A technology for cellulose and raw materials, applied in the field of ethanol preparation, can solve the problems of reducing the proportion of cellulose and reducing the yield of ethanol, and achieve the effects of increasing the yield, shortening the enzymatic hydrolysis time, and improving the production efficiency

Active Publication Date: 2009-09-09
COFCO GROUP
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  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The presumed reason may be that due to the large amount of cellulose-containing raw materials put into the steam explosion device in each batch, and the difference in the accumulation mode of each batch of raw materials or the instability of steam explosion conditions, it is impossible to ensure that all the cellulose-containing raw materials The cellulose raw material fully absorbs the water vapor within a few minutes after being steamed, so there will still be most of the cellulose-containing raw materials that cannot be completely exploded by the water vapor inside because they cannot fully absorb the water vapor. As a result, the lignin sheath embedding cellulose and hemicellulose in the cellulose-containing raw material cannot be fully destroyed, reducing the proportion of cellulose in the cellulose-containing raw material that can be contacted with enzymes, thereby reducing the yield of ethanol

Method used

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  • Method for preparing ethanol by using raw material containing cellulose
  • Method for preparing ethanol by using raw material containing cellulose
  • Method for preparing ethanol by using raw material containing cellulose

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0064] This example illustrates the process of the present invention for producing ethanol from cellulose-containing feedstocks.

[0065] (1) Continuous steam explosion

[0066] test as figure 1For the corn stalk raw material shown, the water content of the corn stalk measured by the above-mentioned method is 20% by weight, the raw material is cut into small sections of 1.5 cm × 0.2 cm × 0.5 cm, and the corn stalk section with a water content of 20% by weight is It is fed continuously from the feeder, and water drenched before being transported to the heat preservation pressure device, and the water drench makes the water content of the corn stalks 40% by weight. Then 2000 grams of corn stalks with a water content of 40% by weight are continuously transported to the above-mentioned heat preservation pressure device, the pressure of the heat preservation pressure device is 1.6 MPa, and the temperature is 195 ° C. Continuous transmission, the linear speed of transmission enabl...

Embodiment 2

[0077] This example illustrates the process of the present invention for producing ethanol from cellulose-containing feedstocks.

[0078] Ethanol was prepared according to the method of Example 1, except that the corn stalks with a water content of 20% by weight were water drenched to make the water content of the corn stalks 75% by weight. Then according to the conditions and methods of Example 1, 4800 grams of corn stalks with a water content of 75% by weight are continuously delivered to the heat preservation pressure device for continuous steam explosion, and the steam explosion waste is collected and washed to obtain a total of 6000 grams of solid steam explosion waste ( The water content is 80% by weight).

[0079] According to the method of HPLC analysis of the steam explosion product of sulfuric acid hydrolysis described in Example 1, record 6000 grams of steam explosion product containing 520 grams of cellulose and 144.4 grams of hemicellulose.

[0080] According to ...

Embodiment 3

[0082] This example illustrates the process of the present invention for producing ethanol from cellulose-containing feedstocks.

[0083] Ethanol was prepared according to the method of Example 1, the difference was that 1500 grams of corn stalks with a water content of 20% by weight were continuously fed from the feeder without water showering and directly transported to the heat preservation pressure device for continuous steaming Explosion, the condition of steam explosion is the same as embodiment 1, and obtains 2400 grams of solid steam explosion waste (water content is 50% by weight) altogether after collecting steam explosion waste and washing.

[0084] According to the method of HPLC analysis of the steam explosion product of sulfuric acid hydrolysis described in Example 1, record 2400 grams of steam explosion product containing 515.2 grams of cellulose and 142.2 grams of hemicellulose.

[0085] According to the method of Example 1, the above-mentioned steam explosion ...

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PUM

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Abstract

The invention discloses a method for preparing ethanol by using a raw material containing cellulose, which comprises the steps of subjecting the raw material containing cellulose to steam explosion, mixing an obtained product of the steam explosion with an enzyme for enzymolysis, and obtaining an enzymatic product through fermentation, wherein a method for the steam explosion of the raw material containing cellulose comprises the steps of continuously delivering the raw material containing cellulose to a heat-preservation pressure unit, keeping the raw material containing cellulose in the heat-preservation pressure unit for 3 to 10 minutes and then releasing part of the raw material containing cellulose in the heat-preservation pressure unit to normal pressure every other 5 to 12 seconds; and a method for mixing the product of the steam explosion and the enzyme comprises the step of mixing part of the product of steam explosion with the enzyme first to obtain a mixture and then continuously adding the rest production of the steam explosion into the mixture for mixing, wherein the rest product of the steam explosion is added at a speed that keeps the concentration of the product of the steam explosion in the reaction system no more than 150g / L and the weight of the part, mixed with the enzyme first, of the product of the steam explosion accounts for 10 to 30 percent of the total weight of the product of the steam explosion. The method can improve the ethanol yield greatly.

Description

technical field [0001] The present invention relates to a method for producing ethanol, and more particularly, to a method for producing ethanol from cellulose-containing raw materials. Background technique [0002] In the prior art, ethanol can be produced from raw materials containing cellulose, which are generally roots, stems and leaves of plants, including straw. The straw refers to the remaining roots, stems and leaves of crops (generally herbaceous plants) after harvesting seeds or fruits, mainly stems and leaves, such as corn straw, sorghum straw, rice straw, wheat straw and other cereal plants, including bean Straw oil plant straw and cotton straw. Cellulose, hemicellulose and lignin in the straw are closely combined through covalent bonds and / or non-covalent bonds, and the three account for about 70-90% by weight of the total weight of the dry matter of the straw. The respective contents of cellulose, hemicellulose and lignin in straw will vary with different sou...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C12P7/06C12R1/84C12R1/865
CPCY02E50/17Y02E50/10
Inventor 刘甲申岳国君袁敬伟王国忠林海龙于天杨
Owner COFCO GROUP
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