Method for coating plastic molded article
A coating method and plastic molding technology, which is applied to the surface coating liquid device, coating, thin material treatment, etc., can solve the problems of insufficient drying and curing, and achieve excellent recoating adhesion, Excellent durability effect
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[0083] Hereinafter, although an Example is given and this invention is demonstrated in more detail, this invention is not limited to these Examples. In addition, "parts" and "%" mean "parts by weight" and "% by weight" unless otherwise specified.
[0084] Water-based polyolefin resin (A):
[0085] The aqueous dispersion of maleic anhydride-modified chlorinated polyolefin has a maleic acid addition amount of 2.2% by weight, a chlorine content of 14%, and a weight average molecular weight of about 60,000.
[0086] Water-based acrylic resin (B):
[0087] Acrylic resin emulsion, molecular weight 300000, acid value 10mgKOH / g, hydroxyl value 9mgKOH / g, calculated Tg50℃, calculated SP8.8.
[0088] Waterborne polyurethane resin (C):
[0089] "UCOAT UX-5210", a polycarbonate-based polyurethane resin, manufactured by Sanyo Chemical Industry Co., Ltd., a trade name, and a solid content of 32%.
[0090] Hydroxyl-containing water-based acrylic resin (D-1)
[0091] Add 145 parts o...
preparation example 1
[0103] Add 38 parts of melamine resin (E) 38 parts (about 30 parts by solid content weight), the acrylic resin emulsion (D) of solid content 25.2% in polyester resin (D-2) 30 parts while stirring. -1) 119 parts (approximately 30 parts by solid content weight) and 25 parts (10 parts by solid content weight) of water-based polyurethane resin (C) of 40% solid content. Then, 20 parts of "Alumi Paste GX180A" (manufactured by Asahi Kasei Co., Ltd., trade name, aluminum flake paste) was added as an aluminum pigment component while stirring and mixed and dispersed, and dimethylethanolamine and deionized water were further added to adjust the pH to 8. 0. Viscosity up to 40 seconds at 20° C. in the measurement using Ford Cup No. 4 to obtain a water-based base coat paint (II-1).
preparation example 2
[0105] In addition to changing the compounding amount of the melamine resin (E) in Preparation Example 1 into 25 parts (20 parts in terms of solid content weight), and changing the compounding capacity of water-based polyurethane resin (C) into 50 parts (in terms of solid content weight) 20 parts), other than the same method as in Preparation Example 1, to obtain a water-based base coat paint (II-2).
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