Mn-Zn ferrite with broad temperature, broadband, high curie point and low loss and preparation method thereof

A manganese-zinc ferrite, high Curie point technology, applied in the direction of inorganic material magnetism, can solve the problems of low magnetic permeability at ultra-low temperature, insufficient coil inductance, easy to stop vibration, etc., and achieve high temperature saturation magnetic flux density Bs increase, Guaranteed permeability, power consumption and temperature, the effect of increasing the saturation magnetic flux density Bs

Inactive Publication Date: 2010-01-06
NANJING FINEMAG TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Nickel-zinc material has the characteristics of high frequency and high Curie point, but the ultra-low temperature magnetic permeability is low, so that the coil inductance is insufficient and difficult to start, and the power consumption of the material is large, and the heat of the lamp is too high; although the manganese-zinc material has high magnetic density and low power consumption Advantages, but the Curie point and frequency are difficult to increase, high temperature is easy to stop vibration, and the size of the lamp is large
[0013] Chinese patent application (CN101183582A) discloses a NiMnZn power ferrite material with high saturation flux density and low loss. It obtains saturation flux density Bs 1194A/ m, greater than 460mT at 100°C, high frequency power consumption 500kHz50mT less than 150kw/m at 100°C

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0052] Selection of raw materials:

[0053] Commercially pure Fe 2 o 3 , ZnO, MnO, and CaCO above chemical purity 3 , SiO 2 , V 2 o 5 , Nb 2 o 5 、 Ta 2 o 5 , ZrO 2 、K 2 CO 3 , SnO 2 、TiO 2 、Co 2 o 3 Wait;

[0054] The component design of the wide temperature and wide frequency high Curie point low loss manganese zinc ferrite material of the present invention:

[0055] The main component content of ferrite material is calculated as oxide: Fe 2 o 3 It is 54.2mol%, ZnO is 4.5mol%, and the rest is MnO; the first addition is assisted by oxide calculation including: SiO 2 It is 100ppm (0.01wt%); CaO is 700ppm (0.07wt%); the second auxiliary component added includes: V 2 o 5 300ppm (0.03wt%), Nb 2 o 5 It is 200ppm (0.02wt%); the content of the third auxiliary component added is calculated as oxide: TiO 2 1000ppm (0.1wt%); SnO 2 500ppm (0.05wt%); Co 2 o 3 It is 500ppm (0.05wt%).

[0056] The preparation method of the wide temperature wide frequency high Cur...

Embodiment 2

[0075] Selection of raw materials:

[0076] Commercially pure Fe 2 o 3 , ZnO, MnO, and CaCO above chemical purity 3 , SiO 2 , V 2 o 5 , Nb 2 o 5 、 Ta 2 o 5 , ZrO 2 、K 2 CO 3 , SnO 2 、TiO 2 、Co 2 o 3 Wait;

[0077] Component design of ferrite material:

[0078] The main component content is calculated as oxides: Fe 2 o 3 is 55mol%, ZnO is 4.2mol%, and the rest is MnO; the first addition is assisted by oxide calculation including: SiO 2 It is 50ppm (0.005wt%); CaO is 500ppm (0.05wt%); the second auxiliary component added includes: Ta 2 o 5 150ppm (0.015wt%), Nb 2 o 5 200ppm (0.02wt%), ZrO 2 300ppm (0.03wt%), K 2 O is 1000ppm (0.1wt%); the content of the third auxiliary component added is calculated as oxide: TiO 2 800ppm (0.08wt%); SnO 2 400ppm (0.04wt%); Co 2 o 3 It is 1000ppm (0.1wt%).

[0079] The preparation method of the manganese-zinc ferrite material with wide temperature, wide frequency, high Curie point and low loss in this example has the ...

Embodiment 3

[0081] Selection of raw materials:

[0082] Commercially pure Fe 2 o 3 , ZnO, MnO, and CaCO above chemical purity 3 , SiO 2 , V 2 o 5 , Nb 2 o 5 、 Ta 2 o 5 , ZrO 2 、K 2 CO 3 , SnO 2 、TiO 2 、Co 2 o 3 Wait;

[0083] Component design of ferrite material:

[0084] The main component content is calculated as oxides: Fe 2 o 3 It is 55.7mol%, ZnO is 4mol%, and the rest is MnO; the first addition is assisted by oxide calculation including: SiO 2 It is 200ppm (0.02wt%); CaO is 500ppm (0.05wt%); the second auxiliary component added includes: Ni 2 o 3 1000ppm (0.1wt%), Nb 2 o 5 It is 200ppm (0.02wt%); the content of the third auxiliary component added is calculated as oxide: TiO 2 1500ppm (0.15wt%); SnO 2 750ppm (0.075wt%); Co 2 o 3 It is 4000ppm (0.4wt%).

[0085] The preparation method of the manganese-zinc ferrite material with wide temperature, wide frequency, high Curie point and low loss in this example has the same process steps and process conditions a...

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PUM

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Abstract

The invention discloses a Mn-Zn ferrite with broad temperature, broadband, high curie point and low loss and a preparation method thereof, the composition calculated by content of oxides is as follows: 52-57mol% of Fe2O3, 3-7mol% of ZnO and the balance of MnO; a first auxiliary component comprises 0.01wt%-0.1wt% of CaO and 0.005wt%-0.02wt% of SiO2; a second auxiliary component comprises one or more of V2O5, Nb2O5, Ta2O5, ZrO2, K2O and NiO, and the content is 0-0.2wt% by calculation, and a third auxiliary component comprises 0.04-0.075wt% of SnO2, 0.08-0.15wt% of TiO2 and 0.05-0.5wt% of Co2O3, wherein, the content of TiO2 is twice as much as that of SnO2. Pre-burning under the protection of nitrogen, sintering, the control of cooling atmosphere and the densification process are carried out, thereby leading the Mn-Zn ferrite with broad temperature, broadband and high curie point to not only meet the market demands of magnetic cores of electromagnetic couplers for electrodeless lamps, but also open up a vast world for new applications of a variety of high frequency power ferrite magnetic cores in communication and strong electric fields.

Description

technical field [0001] The invention relates to a manganese-zinc ferrite material with wide temperature and wide frequency, high Curie point and low loss and a preparation method thereof, belonging to the technical field of ferrite magnetic materials. Background technique [0002] In recent years, the world's major ferrite companies have competed to improve the technical performance of manganese-zinc ferrite materials to adapt to the increasingly expanding application fields. Under the demanding requirements of IT industry, power electronics, lighting electronics and other users, a new and complete The concept has gradually dominated the research and development direction of ferrite soft magnetic materials. This means that the material is required to have a higher saturation magnetic flux density Bs, better DC superposition characteristics, and a lower specific loss coefficient tgδ / μ i (including power consumption Pc under high magnetic flux density) and total harmonic dist...

Claims

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Application Information

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IPC IPC(8): H01F1/34C04B35/26C04B35/622C04B35/64
Inventor 石炎刘九皋王修炜顾骏
Owner NANJING FINEMAG TECH
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