Method for producing potassium chloride by using direct flotation process of third solid sylvinite

A technology of potassium chloride and potassium salt ore, which is applied in the direction of alkali metal chloride, etc., can solve problems such as limited space for expansion, and achieve the effects of saving investment and operating costs, high product purity, and high yield

Inactive Publication Date: 2011-08-17
QINGHAI INST OF SALT LAKES OF CHINESE ACAD OF SCI +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] Although the state strongly supports my country's potash fertilizer production and doubled the new output, due to the lack of domestic potash resources, the total annual output of potash fertilizer in China is about 2.5 million tons, and the expansion space is very limited, which cannot meet the domestic market of 10 million. Tons of huge demand, currently about 80% of domestic agricultural potash depends on imports, agriculture is an important foundation for my country's national economic and social development, and the potash problem has become a bottleneck for the sustainable development of my country's agriculture

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0021] Embodiment 1 A kind of method that utilizes tertiary solid potash ore positive flotation method to produce potassium chloride comprises the steps:

[0022] (1) After the raw material ore is crushed to a particle size of less than 10mm by the PE100-60 crusher produced by Wuhan Prospecting Machinery Factory, take 1080g of raw material ore and add 360g of water to decompose in the decomposition tank produced by Inner Mongolia Gold Machinery Factory. The decomposition reaction time For 25 minutes, the total potassium yield was greater than 81%, and 1440 g of slurry was obtained.

[0023] (2) The slurry is sent to the flotation process, and flotation agents and inhibitors are added respectively in the slurry, wherein the weight-to-volume ratio of raw material ore and flotation agents is 1000:0.6, and the volume ratio of flotation agents and inhibitors is 5:1; after mixing evenly, carry out flotation according to the closed-circuit process of first-stage roughing, first-stage...

Embodiment 2

[0028] Embodiment 2 A kind of method that utilizes the tertiary solid sylvitite positive flotation method to produce potassium chloride comprises the steps:

[0029] (1) After the raw ore is crushed to a particle size of less than 10mm by a crusher, 1188g of the raw ore is taken, and 360g of water is added to decompose in the decomposition tank. The decomposition reaction time is 25 minutes, and the total potassium yield is greater than 81%, obtaining 1548g of slurry .

[0030] (2) The slurry is sent to the flotation process, and flotation agents and inhibitors are added respectively in the slurry, wherein the weight-to-volume ratio of the raw material ore and the flotation agents is 1000:0.8, and the volume ratio of the flotation agents and the inhibitors is After mixing evenly, flotation is carried out according to the closed-circuit process of primary roughing, primary sweeping, and secondary beneficiation, with a total of 5 minutes of flotation, and 136g of flotation conce...

Embodiment 3

[0035] Embodiment 3 A kind of method utilizing the tertiary period solid potash ore positive flotation method to produce potassium chloride comprises the following steps:

[0036] (1) After the raw material ore is crushed to a particle size less than 10mm by a crusher, 1152g of the raw material ore is taken, and 360g of water is added to decompose in a decomposition tank. The decomposition reaction time is 25 minutes, and the total potassium yield is greater than 81%, obtaining 1512g of slurry .

[0037] (2) The slurry is sent to the flotation process, and flotation agents and inhibitors are added respectively in the slurry, wherein the weight-to-volume ratio of raw material ore and flotation agents is 1000:0.7, and the volume ratio of flotation agents and inhibitors is 5.5:1; after mixing evenly, carry out flotation according to the closed-circuit process of first-stage roughing, first-stage sweeping, and second-stage beneficiation, for a total of 5 minutes of flotation, and ...

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Abstract

The invention relates to a method for producing potassium chloride by using the direct flotation process of third solid sylvinite. The method comprises the following steps: third solid sylvinite materials are crushed into particles with the diameter smaller than 10 millimeters, water is added into the crushed materials for decomposition to obtain slurry, and the weight ratio of the materials to water is 3:1 to 3.3:1; a flotation agent and a restraining agent are respectively added into the slurry, after the mixture is mixed evenly, a closed process including one-stage rough flotation, one-stage of scavenging flotation and two-stage fine flotation is carried out to perform flotation, and coarse potassium chloride, fine potassium chloride, tailing potassium chloride and decomposition motherliquid are respectively obtained after filtration; the decomposition mother liquid is evaporated and cooled for two times to fully change into magnesium chloride products; after coarse potassium chloride is washed, filtered and dried, a potassium chloride product the purity of which is more than 90% is obtained. The method can realize the decomposition process under the condition of large granularity, and effectively saves investment and running cost of grinding devices and raises the productivity of potassium chloride.

Description

technical field [0001] The invention relates to a method for producing potassium chloride, in particular to a method for producing potassium chloride by positive flotation of tertiary solid potassium salt ore. Background technique [0002] Potassium resources in the world are extremely rich, with a total of 250 billion tons of resources. Most of them are underground solid potassium salts, and a small part is potassium-containing brine. They are mainly distributed in North America, Europe, South America, the Middle East, Thailand, Laos and other countries in Asia. However, my country's potassium salt resources are scarce, especially the lack of large soluble solid potassium salt deposits. There are 40 proven soluble potassium salt deposits, including 6 large ones, distributed in Qinghai, Xinjiang, Tibet, Yunnan, Shandong, Gansu and other provinces. Among them, potassium-rich salt lakes are concentrated in the Qaidam Basin. The grade of these potassium-rich salt lakes is relat...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C01D3/08
Inventor 张志宏马海州朱明松曾波程怀德李丽娟
Owner QINGHAI INST OF SALT LAKES OF CHINESE ACAD OF SCI
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