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Method for modifying aspen fibers by using silicon-boron sol

A technology of poplar fiber and wood fiber, which is applied in the field of silicon-borosol modified poplar fiber, can solve the problems of poor dimensional stability, flammability, and easy decay, achieves improved dimensional stability and flame retardant performance, and solves the problems of dimensional stability and flame retardancy. The effect of poor stability

Inactive Publication Date: 2014-01-29
NANJING FORESTRY UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] The present invention proposes a method for modifying poplar wood fiber with silicon-boron sol, and uses the modified poplar wood fiber as raw material to suppress the fiberboard. question

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0013] 1. Preparation of poplar wood fiber: After peeling and slicing the raw material poplar wood, it is preheated and cooked, sent to a heat grinder for processing into fibers, and then dried to a moisture content of 2 to 3%.

[0014] 2. Preparation of silicon-boron sol: ethyl orthosilicate (TEOS), absolute ethanol (EtOH), water (H 2 O), boric acid is added in the Erlenmeyer flask according to the mol ratio of 1: 10: 10: 0.46, with 0.1mol.L -1 Hydrochloric acid is used as a catalyst, and the pH value is adjusted to 5. At room temperature, vigorously stir for 1 hour to obtain a transparent sol, which is used for the treatment of wood fibers;

[0015] 3. Poplar fiber modification: poplar fiber was extracted with acetone and tap water for 24 hours in a Soxhlet extractor, and dried at 80°C until constant weight. Then put the treated poplar fiber into the self-made treatment tank to vacuumize and keep a vacuum of 0.097MPa. After 25 minutes, add silicon-boron sol (per 100g poplar...

Embodiment 2

[0019] 1. Preparation of poplar wood fiber: After peeling and slicing the raw material poplar wood, it is preheated and cooked, sent to a heat grinder for processing into fibers, and then dried to a moisture content of 2 to 3%.

[0020] 2. Preparation of silicon-boron sol: ethyl orthosilicate (TEOS), absolute ethanol (EtOH), water (H 2 O), boric acid is added in the Erlenmeyer flask according to the mol ratio of 1: 10: 30: 0.39, with 0.1mol.L -1 Hydrochloric acid is used as a catalyst, and the pH value is adjusted to 6. At room temperature, vigorously stirred for 1 hour to obtain a transparent sol, which is used for the treatment of wood fibers;

[0021] 3. Poplar fiber modification: Poplar fiber was extracted with acetone and tap water for 26 hours in a Soxhlet extractor, and dried at 80°C to constant weight. Then put the treated poplar fiber into the self-made treatment tank to vacuumize and keep a vacuum of 0.097MPa. After 30 minutes, add silicon-boron sol (per 100g poplar...

Embodiment 3

[0025] 1. Preparation of poplar wood fiber: After peeling and slicing the raw material poplar wood, it is preheated and cooked, sent to a heat grinder for processing into fibers, and then dried to a moisture content of 2 to 3%.

[0026] 2. Preparation of silicon-boron sol: ethyl orthosilicate (TEOS), absolute ethanol (EtOH), water (H 2 O), boric acid is added in the Erlenmeyer flask according to the mol ratio of 1:10:15:0.33, with 0.1mol.L -1 Hydrochloric acid is used as a catalyst, and the pH value is adjusted to 6. At room temperature, vigorously stirred for 1 hour to obtain a transparent sol, which is used for the treatment of wood fibers;

[0027] 3. Poplar fiber modification: Poplar fiber was extracted with acetone and tap water for 20 hours in a Soxhlet extractor, and dried at 80°C to constant weight. Then put the treated poplar fiber into the self-made treatment tank to vacuumize and keep a vacuum of 0.097MPa. After 20 minutes, add silicon-boron sol (per 100g poplar fi...

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Abstract

The invention relates to a method for modifying aspen fibers by using silicon-boron sol, which comprises the technical steps of: preparing aspen fibers; preparing silicon-boron sol; modifying the aspen fibers; and pressing a fiber board with middle density. The method has the advantages of using the aspen fibers as research objects, using ethyl orthosilicate as a starting material, using boric acid as an additive, using hydrochloric acid as a catalyst and preparing the sol by using a unique proportioning relationship. The structure of the material is changed in a cell / nano level, thereby solving the problems of poor dimension stability, easy corrosion, flammability and the like. The fiber board with middle density has the following properties: 0.56 to 0.79MPa of internal bonding strength, 25 to 26MPa of bending strength, 14.8% to 14.36% of expansion rate of water absorbing thickness and 31% to 34% of oxygen index. The expansion rate of water absorbing thickness of the fiber board which is not pressed by using the fibers treated by using the sol in the same condition is 35.9%, and the oxygen index is 20%. The dimension stability and the flammability are obviously enhanced.

Description

technical field [0001] The invention relates to a method for modifying poplar fiber with silicon-boron sol, and belongs to the technical field of poplar fiber / nanometer composite material. Background technique [0002] Plant fiber is a kind of hydrophilic material, and the wood composite material made of plant fiber without waterproof treatment has great hygroscopicity and water absorption, and the dimensional stability of the product is poor. After the board absorbs water, it will deform, reduce its strength, increase heat transfer and electrical conductivity, and it is easy to decay, which affects the use range and service life of the material. In addition, wood is a flammable material, and wood composites made of it also have this fatal flaw, thus limiting the scope of use of wood composites. So far, many researchers in the wood industry have done a lot of research work on the modification of wood composite materials, in order to improve the dimensional stability, corros...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): B27K3/52
Inventor 徐莉曹文静姜维娜杨星周晓燕
Owner NANJING FORESTRY UNIV