Polypropylene/calcium carbonate nanocomposite and preparation method thereof
A technology of nanocomposite and polypropylene homopolymer, applied in the field of polypropylene/calcium carbonate nanocomposite and polypropylene composite
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Embodiment 1
[0028] The polypropylene homopolymer is PP1003 (Beijing Yanshan Petrochemical Co., Ltd.), and the weight-average molecular weight of the polypropylene homopolymer is 400,000; the nano-calcium carbonate is provided by Beijing Xinlu Boao Nanotechnology Co., Ltd.
[0029] Surface treatment of nano-calcium carbonate: dry 200g of nano-calcium carbonate in an oven, remove moisture, and pulverize in a high-speed pulverizer for 4 minutes. Then pass the nano-calcium carbonate powder through a 500-mesh sieve and vibrate for about 10 minutes to obtain the nano-calcium carbonate powder with a particle size of 20-200 nm.
[0030] The 100g nano-calcium carbonate powder and 3g calcium stearate were mixed for 4 minutes, then the mixed nano-calcium carbonate and calcium stearate were placed in the blender, and the temperature was 100-130°C at a temperature of 100-130°C. Stir for 10-15 minutes under high-speed stirring at 2500-3000 rpm, and then cool down to room temperature to obtain nano-calc...
Embodiment 2
[0033] The nano-calcium carbonate of polypropylene homopolymer and surface modification is the same as embodiment 1.
[0034] In terms of weight percentage, uniformly mix 99% polypropylene homopolymer and 1% surface-modified nano-calcium carbonate to obtain a mixture, and then melt the mixture with a twin-screw extruder at a temperature of 190-220°C blending to obtain a composite of polypropylene and surface-modified nano-calcium carbonate; the mechanical properties of gained polypropylene and surface-modified nano-calcium carbonate composite are shown in figure 1 , 2 , 3 shown.
Embodiment 3
[0036] The nano-calcium carbonate of polypropylene homopolymer and surface modification is the same as embodiment 1.
[0037] In percent by weight, uniformly mix 98% polypropylene homopolymer and 2% surface-modified nano-calcium carbonate to obtain a mixture, and then melt the mixture with a twin-screw extruder at a temperature of 190-220°C blending to obtain a composite of polypropylene and surface-modified nano-calcium carbonate; see the mechanical properties of the composite of polypropylene and surface-modified nano-calcium carbonate figure 1 , 2 , 3 shown.
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