Oil-resistant raw material for preparing fluorinated silicone rubber-modified silicone rubber

The technology of fluorosilicone rubber and modified silicon is applied in the field of preparing raw materials of methyl vinyl trifluoropropyl silicone rubber modified oil-resistant silicone rubber, and can solve the problems of complicated process, difficult to popularize and use, high price of fluorosilicone rubber, etc. Achieve the effect of improving high temperature oil resistance, beneficial to oil resistance and improving oil resistance

Inactive Publication Date: 2011-07-20
SHANDONG MEICHEN ECOLOGY & ENVIRONMENT CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, due to the poor resistance of silicone rubber itself to non-polar oils, this greatly limits the scope of application of silicone rubber, and with the improvement of people's awareness of environmental protection, higher and higher requirements have been put forward for automobile emissions and fuel penetration. Requirements, traditional silicone rubber has been difficult to meet these requirements
Some manufacturers use fluorosilicone rubber instead of silicone rubber for some oil-resistant occasions, but due to the high price of fluorosilicone rubber, it is difficult to promote the use
In some occasions, such as automotive turbocharger hoses, some manufacturers use a composite structure of silicone tubes lined with fluorosilicone rubber. However, due to the difficulty in bonding fluorosilicone rubber and silicone rubber, this composite structure hose requires complex processes. can achieve

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0008] The dosage is in parts by mass:

[0009] serial number

components

Dosage / serving

1

Methyl vinyl silicone rubber

50

2

Methyl vinyl trifluoropropyl silicone rubber

50

3

Fumed silica

40

4

Highly Active Magnesium Oxide

3

5

AN-3

2.5

6

Dimethyldimethoxysilane

4

7

diatomaceous earth

75

8

Titanium dioxide

75

9

2,5-Dimethyl-2,5-di-tert-butyl peroxide

0.9

[0010] Oil resistance:

[0011] Resistance to ASTM 3# oil (150℃*70h) volume change rate 9.3%

[0012] Resistance to fuel C (23℃*70h) volume change rate 3.8%

[0013] Adhesive strength:

[0014] Bonding strength with silicone rubber 1.94KN / m

[0015] Adhesion strength with fluorosilicone 1.75KN / m

Embodiment 2

[0017] The dosage is in parts by mass:

[0018] serial number

components

Dosage / serving

1

Methyl vinyl silicone rubber

60

2

Methyl vinyl trifluoropropyl silicone rubber

40

3

Fumed silica

30

4

Highly Active Magnesium Oxide

3

5

AN-3

1.5

6

Dimethyldimethoxysilane

3

7

diatomaceous earth

70

8

Titanium dioxide

75

9

2,5-Dimethyl-2,5-di-tert-butyl peroxide

0.7

[0019] Oil resistance:

[0020] Resistance to ASTM 3# oil (150℃*70h) volume change rate 12.3%

[0021] Resistance to fuel C (23℃*70h) volume change rate 4.6%

[0022] Adhesive strength:

[0023] Bonding strength with silicone rubber 2.77KN / m

[0024] Bond strength with fluorosilicone 1.60KN / m

Embodiment 3

[0026] The dosage is in parts by mass:

[0027] serial number

components

Dosage / serving

1

Methyl vinyl silicone rubber

70

2

Methyl vinyl trifluoropropyl silicone rubber

30

3

Fumed silica

35

4

Highly Active Magnesium Oxide

2.5

5

AN-3

1.3

6

Dimethyldimethoxysilane

2.5

[0028] 7

diatomaceous earth

60

8

Titanium dioxide

80

9

2,5-Dimethyl-2,5-di-tert-butyl peroxide

1.0

[0029] Oil resistance:

[0030] Resistance to ASTM 3# oil (150℃*70h) volume change rate 13.2%

[0031] Resistance to fuel C (23℃*70h) volume change rate 5.8%

[0032] Adhesive strength:

[0033] Bonding strength with silicone rubber 2.89KN / m

[0034] Adhesion strength with fluorosilicone 1.53KN / m

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PUM

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Abstract

The invention discloses an oil-resistant raw material for preparing fluorinated silicone rubber-modified silicone rubber. The raw material is characterized by comprising the following components in parts by mass: 50-90 parts of methyl vinyl silicone rubber, 10-50 parts of methyl vinyl trifluoro-propyl silicone rubber, 30-40 parts of fumed silica, 1-3 parts of high-activity magnesia, 0.5-2.5 parts of AN (Acrylic Nitrile)-3, 2-5 parts of dimethyldimethoxysilane, 50-90 parts of kieselguhr, 40-80 parts of titanium pigment and 0.5-1.2 parts of 2,5-dimethyl-2,5-ditert-butyl hexane peroxide. By adopting the raw material, the oil resistance of the silicone rubber is effectively improved, the volume change of ASTM resistant 3# oil (150 DEG C*70h) is not greater than 15 percent, and a formula can be applied to oil resistant occasions by partially substituting the fluorinated silicone rubber.

Description

technical field [0001] The invention belongs to the technical field of rubber, and in particular relates to a raw material for preparing methyl vinyl trifluoropropyl silicone rubber (fluorosilicone rubber) modified oil-resistant silicone rubber. Background technique [0002] Due to its special molecular structure, silicone rubber has excellent high and low temperature resistance, ozone resistance, chemical corrosion resistance and electrical properties. Therefore, silicone rubber has been widely used in various aspects of the national economy, especially in the automotive industry. Wide range of applications. However, due to the poor resistance of silicone rubber itself to non-polar oils, this greatly limits the scope of application of silicone rubber, and with the improvement of people's awareness of environmental protection, higher and higher requirements have been put forward for automobile emissions and fuel penetration. Requirements, traditional silicone rubber has bee...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L83/07C08L83/08C08K13/02C08K3/36C08K3/22C08K5/5419C08K5/14B32B25/20
Inventor 张磊
Owner SHANDONG MEICHEN ECOLOGY & ENVIRONMENT CO LTD
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