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Polyurethane orange-peel coating

A polyurethane orange and coating technology, which is applied in polyurea/polyurethane coatings, coatings, etc., can solve the problems of affecting the appearance of orange-grain coatings, reducing the solid content of construction, and reducing the effect of orange-grain. Good construction performance and improved orange grain effect

Active Publication Date: 2011-08-03
CNOOC CHANGZHOU PAINT & COATINGS IND RES INST +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the addition of thixotropic additives such as organic bentonite or fumed silica significantly increases the viscosity of the coating. Therefore, a large amount of solvent needs to be added to meet the requirements of construction and manufacturing. As a result, the construction solid content of the coating is reduced. When the film is formed, the shrinkage rate of the paint film is large after the solvent evaporates, and the effect of the orange pattern is reduced. In addition, organic bentonite and fumed silica have a certain degree of matting, which reduces the gloss of the paint film and affects the appearance of the orange pattern paint.

Method used

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  • Polyurethane orange-peel coating

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0016] Embodiment 1 prepares polyurethane orange pattern paint (white)

[0017] ①Preparation of a composition for adjusting the fluidity of the paint (abbreviated as A1)

[0018] In a clean container, add 23.5 g of solvent (toluene: butyl acetate = 1: 1), stir and disperse with a high-speed disperser, slowly add orange grain additive (ZY-62 from Changzhou Zhiyou Mengqi Paint Co., Ltd. Self-forming orange grain additive) 1.5g, stir for 10 minutes, then add 75g of hydroxy acrylic resin (RCR3000-X-60 resin produced by CNOOC Changzhou Coating and Chemical Industry Institute) containing symmetrical diurea groups, stir for 20 minutes, store for later use ;

[0019] ②Preparation of component B

[0020] Component B is composed of the following components, and the amount of each component is as follows by weight percentage: 30-50% of base resin, 5-25% of pigment, 10-20% of filler, 20-30% of the composition for adjusting the fluidity of the paint %, the balance is solvent, and the sp...

Embodiment 2

[0029] Embodiment 2 prepares polyurethane orange pattern paint (white)

[0030] ①Preparation of a composition for adjusting the fluidity of the paint (abbreviated as B1)

[0031] In a clean container, add 18 g of solvent (toluene: butyl acetate = 1: 1), stir and disperse with a high-speed disperser, slowly add orange grain additive (L-4630 orange grain aid from Shanghai Deyude Trading Co., Ltd. agent) 2.0g, stirred for 10 minutes, then added 80g of saturated polyester resin (product RCR2001-X-60 resin produced by CNOOC Changzhou Paint Chemical Industry Institute) containing symmetrical diurea groups, stirred for 20min, preserved, and set aside;

[0032] ②Preparation of component B

[0033] The specific formula of component B is shown in Table 2, and the preparation steps are the same as in Example 1.

[0034] Table 2

[0035]

[0036] ③ Prepare group A

[0037] Using Bayer's product N-75 (HDI biuret)

[0038] ④Preparation of polyurethane orange coating

[0039] Accord...

Embodiment 3

[0040] Embodiment 3 prepares polyurethane orange pattern paint (yellow)

[0041] ①Preparation of a composition for adjusting the fluidity of the paint (abbreviated as A2)

[0042]In a clean container, add 23.5 g of solvent (toluene: butyl acetate = 1: 1), stir and disperse with a high-speed disperser, slowly add orange grain additive (ZY-62 from Changzhou Zhiyou Mengqi Paint Co., Ltd. Self-forming orange grain auxiliary agent) 1.5g, stirred for 10 minutes, then added 75g of hydroxyacrylate resin (product 81198 resin produced by Newpace Co., Ltd.) containing symmetrical diuretyl groups, stirred for 20min, preserved, and set aside;

[0043] ②Preparation of component B

[0044] The specific formula of component B is shown in Table 3, and the preparation steps are the same as in Example 1.

[0045] table 3

[0046]

[0047] ③ Prepare group A

[0048] Using Bayer's product N-3390 (HDT trimer)

[0049] ④Preparation of polyurethane orange coating

[0050] According to the we...

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PUM

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Abstract

The invention relates to a polyurethane orange-peel coating, which comprises a component A and a component B, wherein the component A is a diisocyanate prepolymer; the component B consists of the following components in percentage: 30-50 percent of base resin, 5-25 percent of pigment, 10-20 percent of filler, 20-30 percent of composition for adjusting the flowing property of the coating and the balance of solvent; the polyurethane orange-peel coating is prepared by uniformly mixing the component A with the component B in the weight ratio of 1:(3-6); the base resin is one or two of saturated polyester resin with the non-volatile matter content of more than or equal to 65 percent (weight) or hydroxyl acrylic resin; the composition for adjusting the flowing property of the coating consists of hydroxyl acrylic resin or saturated polyester resin which has the non-volatile matter content of more than or equal to 60 percent (weight) and contains symmetrical diurea groups, an orange-peel aid and a solvent; and the using amount of the orange-peel aid is 1-3 percent of the weight of the hydroxyl acrylic resin or the saturated polyester resin which contains symmetrical diurea groups. The coating disclosed by the invention has a good orange-peel effect, high glossiness, water resistance, oil resistance, cutting fluid resistance and high stain resistance.

Description

technical field [0001] The invention relates to a polyurethane orange-grain paint, which is especially suitable for high-performance topcoat on the surface of steel structures such as machine tools, plastic beds, instruments and meters, medical equipment, motors, electric tools, or aluminum alloys. Background technique [0002] Orange pattern paint can form a unique orange-shaped effect, elegant and generous, strong decoration, excellent weather resistance, tough coating film, good impact resistance, abrasion resistance, chemical resistance and water resistance, and it is resistant to rough The surface of the substrate has a certain covering effect, and is widely used as a high-performance topcoat on the surface of steel structures such as machine tools, plastic beds, instruments, medical equipment, motors, and electric tools, or aluminum alloys. Due to the strong concave-convex appearance and prominent patterns of the orange pattern coating, it is generally required that th...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09D175/04C09D175/06C09D5/28C09D7/12
Inventor 陈斌周铭张玉兴丁邦勇张东阳李焕
Owner CNOOC CHANGZHOU PAINT & COATINGS IND RES INST
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