Method for preparing k-carrageenan with high gel strength from eucheuma

A technology of kylin cabbage and carrageenan is applied in the field of extracting high gel strength kappa-carrageenan, which can solve the problems of environmental pollution, high concentration of alkali treatment, increased water consumption for cleaning, etc. The effect of reducing the amount of alkali

Active Publication Date: 2011-09-14
上海国矗生物科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] The purpose of the present invention is to overcome the deficiencies in the prior art, to provide a method for preparing high gel strength κ-carrageenan from Eucheuma, which solves the problem ...

Method used

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Examples

Experimental program
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Effect test

Embodiment 1

[0021] Embodiment one: a kind of method for preparing high gel strength kappa-carrageenan from Eucheuma, comprises the following process steps:

[0022] (1) Ultrasonic ethanol pretreatment: add 150ml of ethanol aqueous solution to 10g of red alga Eucheuma, treat it under ultrasonic conditions for 30 minutes, wash and swell to soften the red alga Eucheuma, the ultrasonic frequency is 70KHz, and the treatment temperature is 30°C; Drain the algae residue obtained after ultrasonic treatment, and reclaim the aqueous ethanol solution; the volume percent concentration of the aqueous ethanol solution is 20%;

[0023] (2) Potassium hydroxide alkali modification: Add 150ml of alkali modifier to the algae residue obtained in step (1), heat to 80°C for 1 hour to remove C in carrageenan 6 The sulfate ester group on the position forms 3,6-inner ether-galactose; the alkali modifier is a potassium hydroxide solution with a mass concentration of 3%;

[0024] (3) Glue cooking: Wash the algae r...

Embodiment 2

[0032] Embodiment two: a kind of method for preparing high gel strength κ-carrageenan from Eucheuma, comprises the following process steps:

[0033] (1) Ethanol ultrasonic pretreatment: Add 10L ethanol aqueous solution to 1000g of red alga Eucheuma, treat it under ultrasonic conditions for 50 minutes, wash and swell to soften the red alga Eucheuma, the ultrasonic frequency is 80KHz, and the treatment temperature is 50°C; Drain the algae residue obtained after ultrasonic treatment, and reclaim the aqueous ethanol solution; the volume percent concentration of the aqueous ethanol solution is 30%;

[0034] (2) Potassium hydroxide alkali modification: Add 10L of alkali modifier to the algae residue obtained in step (1), heat to 75°C for 2 hours to remove C in carrageenan 6 The sulfate ester group on the position forms 3,6-inner ether-galactose; the alkali modifier is a potassium hydroxide solution with a mass concentration of 4%;

[0035](3) Glue cooking: wash the algae residue wi...

Embodiment 3

[0038] Embodiment three: a kind of method for preparing high gel strength κ-carrageenan from Eucheuma, comprises the following process steps:

[0039] (1) Ultrasonic ethanol pretreatment: Add 2000ml of ethanol aqueous solution to 200g of Eucheuma red algae, treat under ultrasonic conditions for 30 minutes, wash and swell to soften the algae of Eucheuma red algae, the ultrasonic frequency is 90KHz, and the treatment temperature is 40°C; Drain the algae residue obtained after ultrasonic treatment, and reclaim the ethanol aqueous solution; the volume percent concentration of the ethanol aqueous solution is 50%;

[0040] (2) Potassium hydroxide alkali modification: add 1000ml alkali modifier to the algae residue obtained in step (1), heat to 60°C for 2 hours to remove C in carrageenan 6 The sulfate ester group on the position forms 3,6-inner ether-galactose; the alkali modifier is a potassium hydroxide solution with a mass concentration of 2%;

[0041] (3) Glue cooking: wash the ...

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Abstract

The invention relates to a method for preparing k-carrageenan with high gel strength from eucheuma. The method comprises the following steps of: (1) adding aqueous solution of ethanol into red algae eucheuma, treating under the ultrasonic condition, and draining water from the algae residue; (2) adding alkali modifier into the algae residue, and heating to remove sulfate groups on the C6 site in carrageenan so as to form 3,6-inner ether-galactose; (3) boiling gel: cleaning the algae residue by using tap water, draining water, adding deionized water, boiling the gel, and filtering to obtain carrageenan gel solution; (4) adding macroporous weak alkaline styrene series anion exchange resin into the carrageenan gel solution, decolorizing, and filtering to obtain liquid for later use; and (5) adding a flocculation accelerator into the liquid obtained by filtering, filtering to obtain white gel, performing vacuum drying, and crushing the product obtained by vacuum drying to obtain the k-carrageenan. By the method, the loss of gel is low, the consumption of alkali is greatly reduced, and the water treatment cost and the environmental pollution are reduced.

Description

technical field [0001] The invention relates to a method for extracting κ-carrageenan with high gel strength from red alga Eucheuma, belonging to the field of marine resource processing and utilization. Background technique [0002] Carrageenan (Carrageenan, also known as carrageenan, carrageenan) is extracted from various red algae such as Chondrus, Eucheuma, Gigartina and Hypena A water-soluble colloid, which is one of the world's three major alginate industrial products (agar, carrageenan, and alginate). Carrageenan is a complex mixture of several polysaccharides. It is a linear polysaccharide formed by alternating links with 1,3-β-D-galactopyranose and 1,4-α-D-galactopyranose as the basic skeleton. According to the different positions of the half-ester sulfate group on galactose, it can be divided into seven types. At present, the main types of industrial production and use are κ-(Kappa), ι-(Iota) and λ-(Lamda) There are three types. κ-type carrageenan can form a hard...

Claims

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Application Information

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IPC IPC(8): C08B37/00
Inventor 王洪新田洪芸马朝阳娄在祥
Owner 上海国矗生物科技有限公司
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