High toughness and high rigidity polypropylene nano-composite material, and preparation method thereof

A nano-composite material, polypropylene technology, applied in the treatment of dyed high molecular organic compounds, fibrous fillers, dyed low molecular organic compounds and other directions, can solve problems such as damage to material properties

Inactive Publication Date: 2012-03-14
SHIYAN FEINAKE TECH
View PDF4 Cites 7 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the lower molecular weight compatibilizers required to prepare polypropyle

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • High toughness and high rigidity polypropylene nano-composite material, and preparation method thereof
  • High toughness and high rigidity polypropylene nano-composite material, and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0026] Preparation of co-intercalation organic layered silicate: First, 100 parts of sodium-based montmorillonite are stirred in 1000 parts of water at high speed for 2 hours, and then 30 parts of cetyltrimethylammonium bromide are added Continue to stir in the suspension for 2 hours. After the ion exchange reaction is completed, let stand for 24 hours to fully precipitate the suspension, and remove the supernatant to obtain a sludge mixture. Then 40 parts of bisphenol A epoxy resin ARALDITE GY240 (manufactured by CIBA-GEIGY, molecular weight 340-380 , Epoxy value 0.52-0.56) was added to the sludge mixture and fully stirred for 2 hours. Finally, it is dehydrated and dried and the product is crushed to a particle size of 200-400 mesh to obtain co-intercalation organic montmorillonite

[0027] Raw material components: component (A) is 100 parts of homopolymer polypropylene, produced by Daqing Petrochemical Company, the brand is T30S; component (B) is 0.05 parts of dicumyl peroxide...

Embodiment 2

[0041] Except that the amount of component D is increased to 15 parts, the other components and conditions are the same as in Example 1.

Embodiment 3

[0043] Except that the amount of component D is increased to 15 parts and the amount of component E is increased to 5 parts, the other components and conditions are the same as in Example 1.

[0044] The mechanical properties of the materials obtained in Examples 2 and 3 are shown in Table 2.

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

PUM

No PUM Login to view more

Abstract

The present invention relates to a high toughness and high rigidity polypropylene nano-composite material prepared by a reactive extrusion and blending method. According to the present invention, with a coupling effect of polypropylene and elastomer macromolecular radical in a reaction by a multi-functional monomer, a interface interaction between the polypropylene and the elastomer macromolecular radical is enhanced so as to improve compatibility and toughness; meanwhile, the multi-functional monomer is inserted into the middle of a layered silicate to generate an in situ grafting intercalation reaction, such that the dispersion separation of the multi-functional monomer in the polypropylene is prompted, the layers of the silicate affect the interface reaction, and provide a stabilizing effect and a refining effect for the elastomer dispersion phase. With the present invention, the co-intercalated organic layered silicate is adopted, and provides a significant rigidity increasing effect and a significant toughness increasing effect; the polypropylene nano-composite material of the present invention has high toughness and rigidity.

Description

Technical field [0001] The invention relates to a polypropylene nano composite material with high toughness and high rigidity and a preparation method thereof. Background technique [0002] Polypropylene is the fastest-growing type of general-purpose plastics. At present, my country’s annual consumption is close to 10 million tons. It has the advantages of light weight, low price, good mechanical properties, good thermal stability, and solvent resistance. Used in industrial fields such as automobiles, home appliances, and packaging, in many cases polypropylene blends and composite materials are used to replace more expensive engineering plastics. But compared with engineering plastics such as nylon and polyester, polypropylene has insufficient rigidity. The flexural modulus of homopolypropylene of high degree (>95%) is about 1400 MPa, while the flexural modulus of nylon 6 and nylon 66 are above 2500 MPa. At the same time, homopolypropylene shows considerable brittleness when ...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

Application Information

Patent Timeline
no application Login to view more
IPC IPC(8): C08L51/00C08L51/06C08K9/04C08K3/34C09C1/28C09C3/08C09C3/10
Inventor 刘晓辉范家起吴勇熊萌梁勇张俊美
Owner SHIYAN FEINAKE TECH
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Try Eureka
PatSnap group products

Browse by: Latest US Patents, China's latest patents, Technical Efficacy Thesaurus, Application Domain, Technology Topic.

© 2024 PatSnap. All rights reserved.Legal|Privacy policy|Modern Slavery Act Transparency Statement|Sitemap