Film for semiconductor device, and semiconductor device
A technology for semiconductors and thin films, which is applied in the field of thin films for semiconductor devices, and can solve the problems of decreased fluidity of the adhesive layer, semiconductor wafer retention, and decreased peelability.
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Embodiment 1
[0133]
[0134] In a reaction vessel with a condenser tube, a nitrogen introduction tube, a thermometer and a stirring device, 80 parts of 2-ethylhexyl acrylate (2EHA), 20 parts of 2-hydroxyethyl acrylate (HEA), 0.2 parts of peroxide were added Benzoyl and 60 parts of toluene were polymerized at 61° C. for 6 hours in a nitrogen stream to obtain an acrylic polymer A having a weight average molecular weight of 800,000. The molar ratio of 2EHA and HEA was 100 moles to 20 moles. The measurement of the weight average molecular weight is as described above. In addition, the weight average molecular weight is a value calculated by measuring by GPC (gel permeation chromatography) and performing polystyrene conversion.
[0135] 10 parts of 2-methacryloyloxyethyl isocyanate (hereinafter referred to as "MOI") (80 mol % relative to HEA) was added to the acrylic polymer A, and the addition was carried out at 50° C. for 48 hours in an air stream. A reaction treatment was carried out to ...
Embodiment 2
[0152]
[0153] As the dicing film of this example, the same dicing film as described in Example 1 was used.
[0154]
[0155] Relative to 100 parts of acrylic acid ester polymer (manufactured by Negami Kogyo Co., Ltd., trade name "Palakron W-197CM" mainly composed of ethyl acrylate-methyl methacrylate, Tg: 18°C, weight average molecular weight: 400,000 ), 1 part of an isocyanate-based crosslinking agent (manufactured by Nippon Polyurethane Co., Ltd., trade name "KORO ONE HX"), o-cresol novolak epoxy resin (manufactured by Nippon Kayaku Co., Ltd., trade name "EOCN-1027") ”) 400 parts, 400 parts of phenolic resin (manufactured by Mitsui Chemicals Co., Ltd., trade name “Miteks XLC-LL”) and spherical silica as inorganic filler (manufactured by アドマテックス Co., Ltd., trade name “SO-25R”, 100 parts of average particle diameters 0.5 micrometers) were melt|dissolved in methyl ethyl ketone, and it prepared by adjusting the density|concentration to 20.0 weight%.
[0156]
[0157] Th...
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