Method for producing silicon-calcium-magnesium fertilizer by using ironmaking blast furnace water-quenching slag as raw materials

A technology of iron-making blast furnace and water-quenched slag, which is applied in the field of silicon-calcium-magnesium fertilizer production, which can solve the problems of plant damage, high heavy metal content in silicon fertilizer, and aggravated soil environmental risks, and achieve the effect of avoiding damage and high effective nutrient content

Active Publication Date: 2012-03-28
广州工业投资控股集团有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the above method has the disadvantages of complex production process, high processing temperature and low effective silicon content.
[0006] At present, the main problems in the research and development of silicon fertilizers: some silicon fertilizers are too expensive to be popularized and applied; some silicon fertilizers have low effective silicon content, and the effect of increasing production is not significant; some silicon fertilizers have high heavy metal content, and long-term application will increase the environmental risk of the soil
Due to cost considerations, some enterprises do not have a granulation process in the process of making silicon fertilizer. During the application of powdered silicon fertilizer, the dust phenomenon is serious, and the dust sticks to the plant body, and its alkaline substances cause damage to the plant.
Some traditional granular silicon fertilizers use water glass as a binder. The silicon fertilizer particles formed by it are hard and difficult to disperse and dissolve after being applied to the soil for a long time. It is difficult for plants to absorb the effective silicon, which greatly reduces the fertilizer efficiency of silicon fertilizers.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0026] A method for producing silicon-calcium-magnesium fertilizer using water-quenched slag of ironmaking blast furnace as raw material, comprising the following steps:

[0027] 1) drying the water-quenched slag produced in the blast furnace ironmaking process to a water content of 15wt%;

[0028] 2) Add quicklime accounting for 5wt% of the water slag to the dried water slag, and then send it into a ball mill for ball milling until the particle size is 80-100 mesh;

[0029] 3) Add binder (clay) accounting for 5wt% of the powder and water accounting for 10wt% of the powder to the powder after ball milling, and granulate on a fertilizer granulator until the particle size is 2-4mm;

[0030] 4) The granulated fertilizer can be dried and packaged.

[0031] After testing, the finished fertilizer is granular, with a pH of 11.4 and a nutrient content of SiO 2 35%, CaO 30%, MgO 15%.

Embodiment 2

[0033] 1) drying the water-quenched slag produced in the blast furnace ironmaking process to a water content of 25wt%;

[0034] 2) Add quicklime accounting for 10wt% of the water slag to the dried water slag, and then send it into a ball mill for ball milling until the particle size is 80-100 mesh;

[0035] 3) Add binder (clay) accounting for 10wt% of the powder and water accounting for 15wt% of the powder to the powder after ball milling, and granulate on a fertilizer granulator until the particle size is 2-4mm;

[0036] 4) The granulated fertilizer can be dried and packaged.

[0037] After testing, the finished fertilizer is granular, with a pH of 12.5 and a nutrient content of SiO 2 32%, CaO 35%, MgO 12%.

Embodiment 3

[0039] 1) drying the water-quenched slag produced in the blast furnace ironmaking process to a water content of 18wt%;

[0040] 2) Add quicklime accounting for 8wt% of the water slag to the dried water slag, and then send it into a ball mill for ball milling until the particle size is 80-100 mesh;

[0041] 3) Add binder (kaolin) accounting for 8wt% of the powder and water accounting for 12wt% of the powder to the powder after ball milling, and granulate on a fertilizer granulator until the particle size is 2-4mm;

[0042] 4) The granulated fertilizer can be dried and packaged.

[0043] After testing, the finished fertilizer is granular, with a pH of 12.1 and a nutrient content of SiO 2 33%, CaO 32%, MgO 13%.

[0044] The process of adding 5%-10% quicklime in the ball milling process of the present invention utilizes the high temperature state generated in the ball milling process to make the quicklime (calcium oxide) react with the silicon dioxide in the water slag to form c...

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Abstract

The invention discloses a method for producing a silicon-calcium-magnesium fertilizer by using ironmaking blast furnace water-quenching slag as raw materials. The method comprises the following steps of: (1) drying the water-quenching slag generated in a blast furnace ironmaking process; (2) adding 5-10wt% of quicklime in the dried water-quenching slag and delivering into a ball milling machine for ball milling; (3) adding 5-10wt% of binders and 10-15wt% of water into powder obtained after the ball milling, and granulating on a fertilizer granulating machine; and (4) drying the granulated fertilizer. The silicon-calcium-magnesium fertilizer prepared in the invention is granular and is different from a powdery silicon fertilizer produced in the past, so that the silicon-calcium-magnesium fertilizer is more convenient to apply in the fields for framers, and damages to crops because the fertilizer is attached to crop blades in a use process are also avoided. In addition, after the quicklime is added, the produced silicon-calcium-magnesium fertilizer has higher available nutrient content and has the effective silicon content capable of reaching more than 30%.

Description

technical field [0001] The invention relates to a method for producing silicon-calcium-magnesium fertilizer by using water-quenched slag of ironmaking blast furnace as raw material. Background technique [0002] Water-quenched slag is also called blast furnace slag. It is the waste slag formed by water-quenching and quenching blast furnace slag in the process of iron-making by iron and steel enterprises. Its main components are: SiO 2 , 34.9%, CaO 36.8%, A1 2 o 3 11.3%, MgO, 13.2%. [0003] The use of water-quenched slag as a fertilizer has a long history in Germany. At present, the main process of using blast furnace slag to produce silicon fertilizer in Germany is: crushing the blast furnace slag to a certain particle size and applying it directly, or crushing the blast furnace slag and mixing it with phosphate components for direct application. Japan adopts the air quenching method to rapidly cool the slag, and the primary utilization rate of heat recovery can reach ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C05D11/00
Inventor 李绍康郑煜基乐国彪陈能场杨传柱曹颂华
Owner 广州工业投资控股集团有限公司
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