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Positive electrode as well as preparation method and application thereof

A positive electrode and positive electrode technology, applied in the field of electrochemistry, can solve the problem of limited degree of power density improvement, and achieve the effects of small energy consumption, large surface area, large energy density and power density

Active Publication Date: 2012-05-23
OCEANS KING LIGHTING SCI&TECH CO LTD +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

In order to increase the power density of lithium-ion batteries, methods of nanometerization and increased conductivity are often used, but the extent to which the power density can be increased is limited.

Method used

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  • Positive electrode as well as preparation method and application thereof
  • Positive electrode as well as preparation method and application thereof
  • Positive electrode as well as preparation method and application thereof

Examples

Experimental program
Comparison scheme
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preparation example Construction

[0027] The embodiment of the present invention also provides the above positive electrode preparation method, the process flow of the method is shown in image 3 shown, see also figure 1 , including the following steps:

[0028] S1. Obtain graphene derivative material, conductive agent, binder and positive electrode substrate 1, wherein, the molecular structural formula of described graphene derivative material is as follows:

[0029]

[0030] S2. Mixing the graphene derivative material, the conductive agent and the binder to prepare a positive electrode coating liquid;

[0031] S3. Coating the positive electrode coating solution on the surface of the positive electrode substrate 1 and drying to obtain the positive electrode.

[0032] It can be seen from the above S1 to S3 that the preparation of the positive electrode only needs to coat the positive electrode coating liquid prepared by mixing the graphene derivative material, the conductive agent and the binder on the po...

Embodiment 1

[0054] The positive electrode structure is as figure 1 As shown, the positive electrode includes a positive electrode substrate 1 and a positive electrode coating 2 bonded on the surface of the positive electrode substrate. Wherein, positive electrode coating 2 comprises graphene derivative material, conductive agent and binder; graphene derivative material molecular structural formula is as follows,

[0055]

[0056] The positive electrode preparation method is as follows, see also image 3 :

[0057] (1) Obtain graphene derivative material, acetylene black, polyvinylidene fluoride, aluminum positive electrode substrate 1, wherein the molecular structure of the graphene derivative material is as above;

[0058] (2) mixing the graphene derivative material, the conductive agent and the binder in a mass ratio of 0.84:0.08:0.08 to prepare a positive electrode coating solution;

[0059] (3) Spray the positive electrode coating liquid onto the surface of the positive electrod...

Embodiment 2

[0068] The structure of the positive electrode is the same as in Example 1, and the performance of the positive electrode is similar to that of the positive electrode in Example 1.

[0069] The positive electrode preparation method is as follows, see also image 3 :

[0070] (1) Obtain graphene derivative material, acetylene black, polyvinylidene fluoride, aluminum positive electrode substrate 1, wherein, the molecular structure of the graphene derivative material is as in the above-mentioned embodiment 1;

[0071] (2) mixing the graphene derivative material, the conductive agent and the binder in a mass ratio of 0.94:0.04:0.02 to prepare a positive electrode coating solution;

[0072] (3) Spray the positive electrode coating liquid onto the surface of the positive electrode substrate 1, dry, roll, and cut into pieces to obtain the positive electrode.

[0073] It has been measured that the positive electrode sheet has a larger energy supply capacitance and electric double la...

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Abstract

The invention discloses a positive electrode, which comprises a positive electrode substrate and a positive electrode coating combined on the surface of the positive electrode substrate, wherein the positive electrode coating comprises a graphene derivant material, conductive agent and binding agent, and the graphene derivant material has the following molecular structural formula. The preparation method of the positive electrode comprises the following steps: obtaining the graphene derivant material, the conductive agent, the binding agent and the positive electrode substrate; mixing the graphene derivant material, the conductive agent and the binding agent to obtain positive electrode coating liquid; coating the positive electrode coating liquid onto the surface of the positive electrode substrate; and drying to obtain the positive electrode. According to the positive electrode disclosed by the invention, faradic pseudocapacitance and double layer capacitance can be provided, and larger energy density and power density can be provided. The preparation method of the positive electrode has the advantages of simple working procedure and low requirement on the equipment and is suitable for industrial production, production efficiency is improved, and production cost is lowered.

Description

technical field [0001] The invention belongs to the technical field of electrochemistry, and in particular relates to a positive electrode and its preparation method and application. Background technique [0002] Since Andre K. Geim (Andre K. Geim) of the University of Manchester in the United Kingdom prepared graphene materials in 2004. Due to its unique structure and optoelectronic properties, it has attracted extensive attention. Single-layer graphite is considered an ideal material due to its large specific surface area, excellent electrical and thermal conductivity and low thermal expansion coefficient. In particular, its high conductivity, large specific surface properties and its two-dimensional nanoscale structural properties of monomolecular layers can be widely used in electrode materials. Therefore, graphene materials are used as electrode materials for supercapacitors and lithium-ion batteries. [0003] In 1990, Japan's SONY company successfully launched a com...

Claims

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Application Information

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IPC IPC(8): H01B1/24H01B13/00H01G9/058H01M4/13H01M4/62H01M4/139H01G11/32H01G11/86
CPCY02E60/122Y02E60/10
Inventor 周明杰潘军刘大喜王要兵
Owner OCEANS KING LIGHTING SCI&TECH CO LTD