Method for recycling hydrogen sulfide
A recovery method, hydrogen sulfide technology, applied in the field of polyphenylene sulfide production process improvement, can solve the problems of secondary pollution, environmental protection and other disadvantages
Inactive Publication Date: 2012-05-30
DALIAN CHUANGDA TECH TRADE MARKET
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Problems solved by technology
In the process of producing polyphenylene sulfide monomer (PPS) by polycondensation process using alkali metal sulfide and p-dichlorobenzene as raw materials, waste gas rich in hydrogen sulfide and toxic media will be generated, which is harmful to environmental protection
However, the prior art adopts the physical absorption method, and there is secondary pollution
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The present invention relates to a method for recycling hydrogen sulfide, which adopts sodium sulfide polyhydrate and p-dichlorobenzene as raw material, and utilizes processes of dehydrating sodium sulfide and performing polycondensation to produce polyphenylene sulfide monomer. The method is characterized by allowing reaction of hydrogen sulfide-rich waste gas and sodium hydroxide in an alkali solution absorption tank, performing deep dehydrogenation on sodium hydrogen sulfide, and returning the dehydrogenated product as raw material for production of polyphenylene sulfide to carry out polycondensation reaction with p-dichlorobenzene. The method treats virulent hydrogen sulfide waste gas to achieve a good environmentally friendly effect, and converts the waste gas into recycled production raw material to form a beneficial closed cycle.
Description
technical field [0001] The invention relates to the improvement of the production process of polyphenylene sulfide, in particular to the recovery method of hydrogen sulfide. Background technique In the process of producing polyphenylene sulfide monomer (PPS) by polycondensation process using alkali metal sulfide and p-dichlorobenzene as raw materials, waste gas rich in hydrogen sulfide and toxic media will be generated, which is harmful to environmental protection. However, the prior art adopts the physical absorption method, which causes secondary pollution. Contents of the invention In view of the above disadvantages of the prior art, the purpose of the invention is to study a hydrogen sulfide recovery method so as to overcome the above disadvantages of the prior art. The object of the present invention is achieved by the following methods. Hydrogen sulfide recovery method, using polyhydrated sodium sulfide and p-dichlorobenzene as raw materials to produce polyph...
Claims
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IPC IPC(8): C08G75/02C08G75/0213C08G75/0254
Inventor 海勇
Owner DALIAN CHUANGDA TECH TRADE MARKET