17 results about "P-dichlorobenzene" patented technology

The invention belongs to the field of high polymer material synthesis, and provides a method for preparing polyphenylene sulfide from high-purity p-dichlorobenzene, which adopts the whole process design of pre-construction of a composite sulfur source intermediate, regulation and control of an end group controllable oligomerization polyphenylene sulfide intermediate, segmented polymerization of the high-purity p-dichlorobenzene and precise dehydration-washing-drying. The ultra-low impurity level of 0.05-0.25 wt% of burning residues of the polyphenylene sulfide product, the sodium ion content of 10-200 mg / kg and the chloride ion content of 10-500 mg / kg is achieved, and meanwhile the high-performance stability of the melting point of 270-300 DEG C, the gel fraction of 92-99 wt% and the water content of 0.01-0.20 wt% is kept. The problems of deep removal of inorganic ions and ash content, balance of gel fraction and processability and control of residual solvents in the traditional polyphenylene sulfide preparation process are solved, and the method has wide application value in the fields of high-performance engineering plastics, special fibers, electronic packaging materials and the like.

The invention belongs to the technical field of high polymer material synthesis, and particularly discloses super-tough polyphenylene sulfide resin and a preparation method and application thereof.The method comprises the following steps that sodium sulfide and a sodium hydroxide solution are heated and mixed in the nitrogen atmosphere; raising the temperature again, performing decompression dehydration, and adding N-methyl pyrrolidone; adding p-dichlorobenzene and a catalyst for reaction; cooling, and carrying out solid-liquid separation on the polymer mixed slurry to obtain a solid material; and drying the solid material in vacuum. According to the super-tough polyphenylene sulfide resin as well as the preparation method and the application thereof, the super-tough polyphenylene sulfide resin with high molecular weight and low molecular weight distribution can be directly prepared at a synthesis end, and a low-temperature-freezing-resistant super-tough polyphenylene sulfide resin composite material can be obtained through the super-tough polyphenylene sulfide resin; and therefore, the application in multiple fields such as cooling systems of new energy automobiles and water peripheries of household appliances is realized.

This invention belongs to the field of catalyst technology, specifically relating to a supported iron-ruthenium catalyst and its application in the synthesis of m-dichlorobenzene and / or para-dichlorobenzene. The iron-ruthenium catalyst comprises a support and iron and ruthenium supported on the support. The support comprises quaternary ammonium salt-modified diatomaceous earth. Based on the total weight of the catalyst, the mass percentage of iron is 5-15%, and the mass percentage of ruthenium is 3-9%. The abundant active sites on the surface of the quaternary ammonium salt-modified diatomaceous earth support can significantly improve the catalytic activity and selectivity for m-dichlorobenzene and / or para-dichlorobenzene, without the formation of trichlorobenzene. The catalyst lifetime is 5-8 times longer than that of iron catalysts. The product can be separated and purified by stripping, distillation, and crystallization. The process is simple and can obtain high-purity m-dichlorobenzene and para-dichlorobenzene products.

This invention relates to a bacterium that degrades chlorobenzene pollutants and its applications. The bacterium is a *Pseudomonas putida* strain, named *Pseudomonas putida* BS-1, deposited at the China Center for Type Culture Collection (CCTCC) with accession number CCTCC M 2024441 on March 11, 2024. Compared with existing technologies, the strain provided by this invention can completely degrade a complex pollutant mixture of dichlorobenzene, chlorobenzene, and benzene within 48 hours. It can survive for a long time and maintain its degradation activity under actual pollution conditions of complex pollution and low temperatures. Furthermore, the functional genes related to the degradation of chlorobenzene pollutants are located on a plasmid, which helps the indigenous bacterium acquire the relevant functions for degrading chlorobenzene pollutants. This strain can be applied to in-situ bioremediation of groundwater with complex chlorobenzene pollution in chemical industrial parks, effectively overcoming the technical shortcomings of traditional reduction dechlorination remediation technologies, which often result in incomplete reduction of products, and achieving green, sustainable, and thorough purification without secondary pollutants.

The invention discloses a preparation method of an anaerobic microbial agent for stably degrading 1, 4-dichlorobenzene. The method comprises the following steps: collecting 1, 4-dichlorobenzene polluted site soil and in-situ underground water, constructing a sealed anaerobic microcosm in an anaerobic glove box according to 30 g of soil and 170 mL of underground water, and culturing in a dark place; 1, 4-dichlorobenzene is used as a directional selection substrate, and an electron donor (preferably methanol) capable of anaerobic hydrogen production is added according to 10 times of electron equivalent relative to the 1, 4-dichlorobenzene. In the first round, 5.15-10.3 mg / L is added, if complete degradation or residue is smaller than or equal to 3% of the initial round, the next round is supplemented, the amount of the added liquid is increased by 5.15-10.3 mg / L in each round, the amount of the added liquid is smaller than or equal to 58.5 mg / L in a single round, and circulation is larger than or equal to 10 rounds; and 10 mL of the enriched bacterial liquid can be transferred to 190 mL of a mineral culture medium for passage amplification. The obtained microbial inoculum can tolerate 1, 4-dichlorobenzene with relatively high concentration, is stable in degradation, and can be used for anaerobic bioremediation of polluted soil and underground water.

This invention belongs to the field of resin preparation technology, specifically relating to a polyphenylene sulfide resin and its preparation method. The preparation method includes the following steps: a composite stabilizer, anhydrous sodium sulfide, and a polar solvent are first mixed; the resulting first mixture undergoes a dehydration reaction to obtain a dehydrated reaction solution; the dehydrated reaction solution is then mixed with p-dichlorobenzene; the resulting second mixture undergoes prepolymerization and postpolymerization sequentially to obtain the polyphenylene sulfide resin; the composite stabilizer includes carbodiimide having the structure of formula I, lithium chloride, and sodium hydroxide; R 1 -(N=C=N) n -R 2 Equation I; n is an integer from 1 to 20; R 1 and R 2 The polymer is independently selected from substituted or unsubstituted alkyl, cycloalkyl, aryl, or aralkyl groups. The composite stabilizer in this invention effectively inhibits excessive hydrolysis by polar solvents, improves reaction efficiency, and controls the polymer molecular structure, thereby obtaining high molecular weight, high yield, and high whiteness PPS resin.

The invention belongs to the technical field of resin gears, and particularly provides a low-friction compound gear as well as a preparation method and application thereof.The low-friction compound gear is prepared by mixing the following raw materials in parts by mass: 50-60 parts of polylaurolactam, 15-20 parts of polyformaldehyde, 2-3 parts of a compatilizer, 2-3 parts of heat conduction fibers, 0.3-0.4 part of a coupling agent, 0.1-0.2 part of a crystal forming agent and 0.01-0.02 part of an antioxidant; the heat-conducting fibers are obtained by etching polyether-ether-ketone fibers and coating and curing the polyether-ether-ketone fibers; the crystal forming agent is obtained by condensation polymerization of p-dichlorobenzene, sodium sulfide and biphenyl derivatives. According to the compound gear prepared by matching the crystal forming agent with the heat-conducting fiber, the crystallinity of the gear product can reach 67.9%, the heat conductivity is greater than or equal to 3.34 W. (m.K)-1, and the mechanical property is excellent.

The invention discloses a preparation method of antioxidant polyphenylene sulfide resin, and aims to solve the problems of metal catalytic oxidation, easy loss of antioxidant due to uneven dispersion and poor high-temperature stability in the prior art. The preparation method comprises the following steps: pre-polymerizing p-dichlorobenzene, sodium sulfide, N-methyl pyrrolidone and a catalyst to obtain oligomer slurry; after cooling, adding a composite antioxidant system for dispersion, and then adding a dispersing aid containing a siloxane chain segment; raising the temperature to 230-250 DEG C for final polymerization, and washing and drying to obtain a product. The composite antioxidant system can block multi-path oxidation, and the dispersing aid can reduce the loss of the antioxidant. The oxidation induction temperature of the product is 490-470 DEG C, the tensile strength retention rate is greater than or equal to 92% after the product is aged for 1200 hours at 230 DEG C, the loss rate of the antioxidant is less than or equal to 5%, and the process is suitable for industrialization and is suitable for harsh scenes such as high-temperature filtration and automotive electronics.

The invention discloses low-end-group chlorine polyphenylene sulfide and a preparation method thereof.The preparation method comprises the following steps that N-methyl pyrrolidone, a sodium hydrosulfide aqueous solution, a hydroxide aqueous solution and a catalyst are mixed, and a mixture is obtained; removing free water in the mixture, adding N-methyl pyrrolidone and p-dichlorobenzene into the mixture under a nitrogen protection atmosphere, heating to 180-240 DEG C, carrying out an early polymerization reaction, heating to 240-270 DEG C, adding a third monomer, and carrying out a later polymerization reaction; and after the reaction is finished, cooling, filtering, washing and drying to obtain the low-end-group chlorine polyphenylene sulfide. Through an innovative synthesis process, the prepared PPS resin with low end group chlorine is uniform in particle shape, the product yield is in an industry leading level, and the problems that in a traditional process, the content of end group chlorine of a product is high, and the product gradually dissociates in the processing process are effectively solved; by means of excellent performance, the packaging film can be widely applied to high-end fields such as electronic component packaging and the like.

The invention belongs to the field of high polymer material synthesis, and particularly provides a preparation method of an antioxidant PPS melt-blown material.In the polymerization process, a naphthalene ring structure monomer is introduced to be subjected to condensation polymerization with p-dichlorobenzene and sodium hydrosulfide in a polar solvent, a PPS copolymer containing a naphthalene ring structure is formed, the oxidation resistance of the PPS copolymer can be improved through introduction of a naphthalene ring, and the antioxidant performance of the PPS melt-blown material is improved; the strength and the toughness of the material can also be enhanced; when the composite material is applied to preparation of the melt-blown material, the subsequent modification treatment of coating, dipping or adding an antioxidant on the surface of the melt-blown material can be reduced, the process is simplified, the production efficiency is improved, and the production cost of the melt-blown material is reduced.

The invention belongs to the field of chemical material treatment, and particularly relates to a solvent recovery method in a polyphenylene sulfide resin production process. According to the method, low polymers are cut firstly, then N-methyl pyrrolidone and p-dichlorobenzene in washing liquid are extracted and recovered, high-energy-consumption operation of direct water steaming is avoided, an extraction agent in a raffinate phase is recovered in a pervaporation mode, selective permeability of a membrane is utilized, and compared with steam stripping, the separation efficiency is high, the energy consumption is low, and the cost is low. The extraction agent is recovered in an azeotropic coupling steam stripping manner, so that on one hand, the energy consumption is reduced, and on the other hand, the problem of acidizing corrosion of a reboiler caused by heating rectification by using the reboiler is solved; the method comprises the following steps: carrying out reduced pressure supergravity rectification on residual components, recycling unreacted p-dichlorobenzene monomers, and then carrying out refining purification and other treatment operations on NMP, so that efficient recovery of the solvent NMP is realized, and the method has the characteristics of controllable process, high separation efficiency, low energy consumption, small pollution, high solvent purity and high yield.

The present application belongs to the technical field of new plant variety breeding, and particularly relates to a breeding method of a bletilla triplod and application thereof. The breeding method of the bletilla triplod comprises the following steps: screening a bletilla diploid; artificially inducing and identifying a bletilla tetraploid; culturing the identified bletilla tetraploid to flowering; and hybridizing the bletilla tetraploid and the bletilla diploid to obtain a bletilla triplod fruit; wherein a mutagen used for the induction is a mixed aqueous solution of 10 ppm p-dichlorobenzene and 5 ppm alpha-bromonaphthalene. The present application first creates a new bletilla triplod variety, and establishes a complete set of bletilla triplod advantage utilization and breeding method. The present application first obtains a new bletilla triplod germplasm, and lays a scientific foundation for bletilla triplod breeding.

The application belongs to the technical field of resin gears, and specifically provides a low-friction composite gear, a preparation method and application thereof, which is prepared by mixing raw materials including the following components by mass: poly(lauryl lactam) 50-60 parts, polyformaldehyde 15-20 parts, a compatilizer 2-3 parts, a heat-conducting fiber 2-3 parts, a coupling agent 0.3-0.4 parts, a crystallization agent 0.1-0.2 parts, and an antioxidant 0.01-0.02 parts; the heat-conducting fiber is obtained by etching and glue-curing poly(ether ether ketone) fiber; and the crystallization agent is obtained by polycondensation reaction of p-dichlorobenzene, sodium sulfide and a biphenyl derivative. The composite gear prepared by using the crystallization agent and the heat-conducting fiber has a gear product crystallinity of 67.9%, a thermal conductivity of 3.34 W·(m·K) ‑1 , and excellent mechanical properties.

This invention belongs to the field of analytical chemistry and sensing materials, and provides a detection and analysis material for online detection of 1,4-dichlorobenzene and its preparation method. This invention employs a synergistic composite design of a porous cross-linked polyionic liquid matrix and a functionalized carbon nanotube intermediate. Using sodium chloride as a sacrificial template, an interconnected pore structure is constructed. Through polydopamine coating and in-situ free radical polymerization, a polymer shell containing 4-vinylpyridine and glycidyl methacrylate structural units is covalently fixed to the surface of multi-walled carbon nanotubes, achieving integrated construction of enrichment recognition and signal transduction pathways. It also possesses low viscosity, coatable processability, and excellent immersion stability, effectively solving the technical contradictions of balancing high porosity and membrane continuity, uniform carbon nanotube dispersion and coatable processing windows, and functional enrichment sites and pore structure stability. This invention has broad application value in the fields of ambient air quality monitoring and online detection of volatile organic compounds.

The invention belongs to the field of analytical chemistry and sensing detection materials, and provides a detection and analysis material for online detection of 1, 4-dichlorobenzene and a preparation method thereof.According to the detection and analysis material, a porous cross-linked polyion liquid matrix and a functionalized carbon nanotube intermediate are synergistically compounded, sodium chloride is used as a sacrificial template to construct an intercommunicated pore structure, and the porous cross-linked polyion liquid matrix and the functionalized carbon nanotube intermediate are combined to form a porous structure; a polymer shell layer containing 4-vinylpyridine and glycidyl methacrylate structural units is covalently fixed on the surface of the multi-walled carbon nanotube through polydopamine coating and in-situ free radical polymerization, so that enrichment recognition and signal transduction path integrated construction is realized, and the multi-walled carbon nanotube has low-viscosity coating processability and excellent immersion cleaning resistance stability; the technical contradiction that high porosity and membrane continuity, uniform dispersion of the carbon nanotubes and a processing window capable of being coated, and functional enrichment sites and pore structure stability are difficult to consider at the same time is effectively solved, and the method has wide application value in the fields of environmental air quality monitoring and volatile organic compound online detection.

The invention discloses a preparation method of polyphenylene sulfide resin, which comprises the following steps: taking a sulfur-containing compound and p-dichlorobenzene as raw materials, carrying out condensation polymerization in a polar organic solvent in an alkaline environment, after the reaction is finished, cooling and separating to obtain the polyphenylene sulfide resin, and when the temperature is reduced to a preset temperature of 243-248 DEG C in the cooling process, carrying out condensation polymerization in the polar organic solvent to obtain the polyphenylene sulfide resin. Adding polyphenylene sulfide particles with a particle size of 700-900 [mu] m or a slurry prepared from the polyphenylene sulfide particles into the system, and carrying out heat preservation; the adding mass of the polyphenylene sulfide particles with the particle size of 700-900 microns is 1-5% of the total mass of the polyphenylene sulfide calculated by the total sulfur of the system; according to the invention, the amount of PPS ultrafine powder generated by polymerization reaction can be reduced, the particle size of the ultrafine powder PPS is increased, so that the ultrafine powder PPS becomes a PPS main product, the post-treatment vibration separation efficiency is further improved, the yield of the PPS main product is improved, the ash content and oligomer content can be kept relatively low, and the particle size distribution can be optimized to a certain extent.

The present application relates to the technical field of plant chromosome preparation, and specifically discloses a method for increasing the number of mitotic metaphase chromosomes of sugarcane or sugarcane relative genus root tips, comprising: soaking sugarcane or sugarcane relative genus stem double bud segments in an indole-3-acetic acid solution with a concentration of 60-120 mg / L, and culturing in sand or peat substrate; root tip pretreatment: culturing for 2-3 days, selecting healthy and tender root tips, and placing the root tips in saturated p-dichlorobenzene aqueous solution for low-temperature treatment at 8-12 DEG C for 3-5 h; using Carnoy's fixative for fixation; enzymolysis of the root tip growth point; smearing the root tip on a glass slide for preparation; and staining treatment. The method for preparing the present application can achieve the fastest time of only 4 days from root tip culture to chromosome observation, has a short cycle, high efficiency, is convenient and fast for sampling, has a large number of metaphase division phases in the chromosomes, clear morphology, a clean glass slide background, and is convenient for chromosome counting observation and karyotype analysis, and has important significance for the development of sugarcane cytogenetics research.