Amphoteric reaction-type surfactant and preparation method thereof
A surfactant, amphoteric reaction technology, used in the preparation of carboxylic acid amides, chemical instruments and methods, preparation of organic compounds, etc., can solve the problems of poor freeze-thaw stability of latex, reduced film water resistance, slow film formation rate, etc. , to achieve the effect of excellent emulsifying performance, reducing material loss and not easy to homopolymerize
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[0023] Example 1
[0024] (1) Preparation of intermediate: Take 10.2g (0.10mol) of N,N-dimethyl-1,3-propanediamine, dissolve it in 50mL of benzene, and transfer to a dropping funnel. Take the molar ratio of n(N,N-dimethyl-1,3-propanediamine): n(maleic anhydride) of 1:1 maleic anhydride, dissolve it in 100mL of benzene, and transfer to In a 250mL three-necked flask, equipped with a stirrer, thermometer, dropping funnel, heated in a water bath, the dropping temperature is 30℃, and the dropping time is 1h. After the dripping is completed, the temperature is raised to 50℃, and the reaction is continued for 2h. , Stand still, filter after cooling, wash the filter cake several times with ethyl acetate, and wash the product several times with ethyl acetate. After filtering, dry under vacuum overnight at 40°C. The yield is calculated and the yield can reach 87.2%. Take an appropriate amount of product and determine the neutralization value to determine the amount of alkali required for ...
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[0030] Example 2
[0031] (1) Preparation of intermediate: Take maleic anhydride and N,N-dimethyl-1,3-propanediamine and dissolve them in toluene at a molar ratio of 1.1:1, where N,N-dimethyl-1 , 3-Propane diamine is fed by dripping, the dripping temperature is about 25℃, and the dripping time is 0.5h. After the dripping is completed, the temperature is raised to 45℃, and the reaction is continued for 2h. After the reaction is over, let it stand still After cooling and filtering, the filter cake is obtained. The filter cake is washed with ethyl acetate, filtered and dried to obtain the product white powder, the intermediate N-(3-dimethylaminopropyl)maleamic acid.
[0032] (2) Preparation of amphoteric reactive surfactant: take water to dissolve the intermediate N-(3-dimethylaminopropyl) maleamic acid, the mass ratio of water to intermediate is 1.2:1, in the dissolved solution Add dropwise sodium hydroxide or potassium hydroxide solution with a mass concentration of 15% to adjust t...
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[0034] Example 3
[0035] (1) Preparation of intermediate: Take maleic anhydride and N,N-dimethyl-1,3-propanediamine and dissolve them in xylene at a molar ratio of 1.2:1, where N,N-dimethyl- 1,3-propanediamine is fed by dripping, the dripping temperature is about 35℃, and the dripping time is 1.5h. After the dripping is completed, the temperature is raised to 55℃ and the reaction is continued for 2 to 3h. After the reaction is over, After standing, cooling and filtering, the filter cake is obtained. The filter cake is washed with ethyl acetate, filtered and dried to obtain a white powder, the intermediate N-(3-dimethylaminopropyl)maleamic acid;
[0036] (2) Preparation of amphoteric reactive surfactant: take water to dissolve intermediate N-(3-dimethylaminopropyl)maleamic acid, the mass ratio of water to intermediate is 1.5:1, in the dissolved solution Add dropwise sodium hydroxide or potassium hydroxide solution with a mass concentration of 30% to adjust the pH to 9; then add 1-...
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