High-intensity molecular sieve and preparation method thereof

A molecular sieve, high-strength technology, applied in the direction of A-type crystalline aluminosilicate zeolite, octahedral crystalline aluminosilicate zeolite, crystalline aluminosilicate zeolite, etc., can solve the problem of high molecular sieve wear rate

Inactive Publication Date: 2012-06-20
YANTAI UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Although the mechanical strength of the molecular sieve prepared by the latter two methods has been improved to a certain extent, the wear rate of the molecular sieve is relatively high.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0024] Strip high strength 4A molecular sieve (Ф3×10mm)

[0025] Weigh 85g of industrial 4A molecular sieve raw powder and 15g of montmorillonite, mix them evenly, mix 10g of 25% sodium silicate and 30ml of 2% polyethylene glycol aqueous solution and add them, knead them evenly and extrude them into strips, then heat them at 150℃ After drying for 5 hours, the dried strip molecular sieve was calcined at 550°C for 5 hours and then cooled to obtain strip high strength 4A molecular sieve finished product A.

Embodiment 2

[0027] Spherical high strength 4A molecular sieve (3~5mm)

[0028] Weigh 80g of industrial 4A molecular sieve raw powder, 20g of bentonite and 7.5g of CaSO4 and mix evenly, use 50g of 1.5% polyethylene glycol aqueous solution to roll into a ball, then dry at 120°C for 10 hours, and dry the dried spherical molecular sieve at 600 After calcination at ℃ for 5 hours and cooling, the finished product B of spherical high-strength 4A molecular sieve was obtained.

Embodiment 3

[0030] Spherical high strength 5A molecular sieve (3~5mm)

[0031] Weigh 70g of industrial 5A molecular sieve raw powder and 30g of diatomaceous earth, mix well, use 60g of sodium metaaluminate containing 30% and 2.5% polyvinyl alcohol aqueous solution to form rolling balls, and then dry at 100°C for 40 hours. The spherical molecular sieve was calcined at 650°C for 10 hours and then cooled to obtain the finished product C of spherical high-strength 5A molecular sieve.

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PUM

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Abstract

The invention relates to a high-intensity molecular sieve and a preparation method thereof. The method comprises the following steps: uniformly mixing molecular sieve material and a binder so as to obtain molecular sieve quality A; adding structure intensifier into the molecular sieve quality A so as to obtain molecular sieve quality B, and then obtaining the high-intensity molecular sieve through forming, drying, roasting and cooling the molecular sieve quality B in sequence. The molecular sieve prepared by using the method provided by the invention not only has excellent mechanical strengthand also is low in abrasion ratio.

Description

technical field [0001] The invention relates to a high-strength molecular sieve and a preparation method thereof, belonging to the technical field of petrochemical industry. Background technique [0002] Molecular sieves are a class of adsorbents and catalysts with a wide range of uses. They are often used in gas separation, dehydration, desulfurization, and acid-catalyzed reaction processes in chemical production processes. Molecular sieves often need to be regenerated during use. For example, molecular sieves used in the pressure swing adsorption process need to be alternately raised and lowered; Charcoal regeneration, etc. All these processes cause more or less damage to the structure of molecular sieves, and the development of high-strength molecular sieves is conducive to prolonging the service life of molecular sieve adsorbents / catalysts, which has important practical significance. [0003] Patent CN1044980C discloses a method for preparing high-strength molecular si...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C01B39/14C01B39/22
Inventor 房德仁张慧敏
Owner YANTAI UNIV
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