Thermoplastic elastomer composition of encapsulation PETG (poly(ethylene terephthalate) glycol) and preparation method thereof

A technology of thermoplastic elastomer and composition, which is applied in the field of thermoplastic elastomer composition and its preparation of encapsulated PETG. Strong relay, strong grip and comfortable hand feel

Inactive Publication Date: 2012-06-27
SHANGHAI KUMHO SUNNY PLASTICS
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Traditional SAN, PS and other brush handles, because the material itself is not resistant to low temperature and chemicals, especially in winter, it is prone to brittleness and fracture, which may potentially cause harm to the human body
At present, copolyester materials are commonly used in high-end toothbrush handles. This material has excellent chemical resistance, excellent low-temperature flexibility and excellent transparency. However, general thermoplastic elastomers are not firmly bonded to these two resins. Unable to meet the requirements of use and become a difficult problem in this industry

Method used

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  • Thermoplastic elastomer composition of encapsulation PETG (poly(ethylene terephthalate) glycol) and preparation method thereof
  • Thermoplastic elastomer composition of encapsulation PETG (poly(ethylene terephthalate) glycol) and preparation method thereof

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Embodiment 1~4

[0029] Among embodiments 1 to 4, SEBS is produced by Kraton Polymer Company, and its trade name is KRATON G1651; the plasticizer is the naphthenic oil produced by Karamay, Xinjiang, and its trade name is KN4010; TPU is the trade name of S85A10 produced by BASF; The compatibilizer is the ethylene-n-butyl acrylate-carbonyl copolymer produced by DuPont, the trade name is HP4051; Antioxidant is hindered phenolic antioxidant, specifically is the AO 1010 of Ciba Company; Inorganic mineral is the 800 order calcium carbonate that Anhui Hengda Calcium Carbonate Company produces, also can be superfine talcum powder, barium sulfate and its mixed.

[0030] Its preparation method is as follows:

[0031] (1) take raw materials by each component shown in Table 1 and the weight percentage content thereof;

[0032] (2) Mix SEBS and plasticizer in the above raw materials for 20 to 30 minutes in a high mixer;

[0033] (3) Add other raw materials and mix evenly, take out;

[0034] (4) Then p...

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Abstract

The invention relates to a thermoplastic elastomer composition of encapsulation PETG (poly(ethylene terephthalate) glycol) and a preparation method of the thermoplastic elastomer composition. The composition is prepared from the following raw materials in weight percentage: 15-35% of SEBS (styrene-ethylene-butadiene-styrene), 18-40% of a plasticizer, 30-45% of TPU (thermoplastic polyurethane), 5-10% of a compatilizer, 0.2-0.4% of an antioxidant, and 5-20% of an inorganic mineral. The preparation method comprises weighing raw materials proportionally by weight; mixing SEBS and the plasticizer in a high mixing machine for 20-30min, adding other raw materials, mixing, and taking out; and placing into a double screw extruder for extrusion granulation, wherein the rotation speed of the main machine of the screw is 200-350rpm, and the processing temperature is in the range of 180-220 DEG C. The thermoplastic elastomer composition of the invention has the following advantages: the polarity of SEBS is changed, resulting in chemical reaction of surfaces of the elastomer and the copolymer polyester and high bonding strength of secondary injection molding, and after stripping, a layer of the elastomer completely adheres on the surface of the PETG backing material, resulting in comfort handfeel and strong gripping strength; and the composition is a non-toxic and innocuous environment-friendly material for human and environment, and fully meets the requirements of high-end toothbrushes for PETG encapsulation.

Description

technical field [0001] The invention relates to a thermoplastic elastomer material and a preparation method, in particular to a thermoplastic elastomer composition encapsulated with PETG and a preparation method thereof. Background technique [0002] Copolyester PETG has good processability, transparency, and chemical resistance, and is widely used in high-end personal care handles (such as toothbrushes, razors). [0003] As we all know, toothbrush handles are generally formed by coating a layer of elastomer with a thermoplastic resin by a secondary injection molding process. Traditional SAN, PS and other brush handles, because the material itself is not resistant to low temperature and chemicals, especially in winter, it is prone to brittleness and fracture, which may potentially cause harm to the human body. At present, copolyester materials are commonly used in high-end toothbrush handles. This material has excellent chemical resistance, excellent low-temperature flexibi...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L75/04C08L53/02C08K13/02C08K5/01C08K3/34C08K3/26C08K3/30B29C47/92B29C48/92
CPCB29C48/04B29C48/40B29C48/92B29C2948/9259B29C2948/92704B29C2948/92885B29C2948/92895
Inventor 廖志荣张平罗明华辛敏琦
Owner SHANGHAI KUMHO SUNNY PLASTICS
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