Application of two naphthoquinone compounds in preparing antitumor medicaments
A technology of anti-tumor drugs and pharmaceutical preparations, applied in the field of medicine, can solve the problem that there is not much research on the chemical components of wild walnut.
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Embodiment 1
[0057] 20 kg of dried root bark of wild walnut (Juglans cathayensis Dode) was crushed, extracted by percolation with 95% ethanol, and the extract was concentrated under reduced pressure to obtain 2.5 kg of extract. The extract was evenly dispersed in 40L of water, and extracted with petroleum ether and ethyl acetate in turn. Obtain 400g of ethyl acetate part, mix it with 500g of silica gel, add to the top of the installed silica gel column, elute with petroleum ether: ethyl acetate system gradient, TLC tracking, combine and contain the same components, reduce pressure After concentration and drying, 1.0 g of 2-methoxyjuglone and 0.3 g of 3-methoxyjuglone were obtained from the polar segment of petroleum ether / ethyl acetate 5:1.
[0058] 2-methoxy juglone (2-methoxy juglone) is a brownish-red needle-like crystal, soluble in ethyl acetate, acetone, chloroform, DMSO, etc., and the color of ethanol sulfate is bright yellow spots. EI-MS gives molecular ion peak as 204( figure 1 )...
Embodiment 2
[0061] Active ingredient (by one of two kinds of compounds that embodiment 1 makes 10g
[0062] or composition)
[0063] Lactose 100g
[0064] Cornstarch 25g
[0066] Made into 1000 pieces
[0067] Preparation method: uniformly moisten the active ingredient, lactose and starch mixture with water to make a soft material, granulate the wetted mixture, pass through a 20-mesh sieve, dry at 80°C, add magnesium stearate, sieve again, and then The mixture is compressed into tablets, each weighing 140mg, containing 10mg of the active ingredient.
Embodiment 3
[0069] Get 2.5g of the active ingredient (one of the two compounds obtained in Example 1 or the composition), add 200ml of propylene glycol and ethanol, stir to dissolve, add water for injection and dilute to 10000ml, filter through a 0.22 μm microporous membrane, pour Sealed, 20ml / bottle, sterilized by circulating steam for 30 minutes, inspected, packaged, and obtained injection.
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