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High-CTI (comparative tracking index) halogen-free flame retardant resin composition for copper-clad laminate

A technology of flame-retardant resin and copper-clad substrate, which is applied in the field of high CTI value halogen-free flame-retardant resin composition, can solve the problem that ATH is added less and the flame retardancy cannot meet the requirements, and the heat resistance of FR4 board is not good. Heat resistance decline and other problems, to achieve the effect of high heat resistance of the system, high CTI value, and improved processing performance

Active Publication Date: 2012-07-18
无锡宏仁电子材料科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] In recent years, some high CTI boards are mainly CEM-3 materials, but since the implementation of lead-free in the electrical and electronic related industries, the high temperature environment requirements for product applications have also been increasing accordingly, and new requirements have been placed on the heat resistance of materials. Therefore, CEM-3 materials are unable to meet the above requirements, and some existing FR4 plates with high CTI also have the problem of poor heat resistance. This kind of plates generally use ATH (aluminum hydroxide) to provide CTI, but Adding more ATH will cause a decrease in heat resistance, and adding less ATH will not meet the requirements for flame retardancy

Method used

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  • High-CTI (comparative tracking index) halogen-free flame retardant resin composition for copper-clad laminate
  • High-CTI (comparative tracking index) halogen-free flame retardant resin composition for copper-clad laminate

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0040] A high CTI value halogen-free flame-retardant resin composition, containing the following components in parts by weight: 39 parts of DOPO modified epoxy resin, 21 parts of bisphenol A epoxy resin, 2 parts of dicyandiamide, undecyl 0.3 parts of imidazole, 10 parts of aluminum hydroxide, 28 parts of boehmite.

Embodiment 2

[0042] A high CTI value halogen-free flame-retardant resin composition, containing the following components in parts by weight: 39 parts of DOPO modified epoxy resin, 21 parts of bisphenol A novolac epoxy resin, 2 parts of dicyandiamide, undecane 0.2 parts of imidazole, 19 parts of aluminum hydroxide, and 19 parts of boehmite.

Embodiment 3

[0044] A high CTI value halogen-free flame-retardant resin composition, containing the following components in parts by weight: 31.5 parts of DOPO modified epoxy resin, 17 parts of bisphenol A novolac epoxy resin, 1.5 parts of dicyandiamide, undecane 0.5 parts of imidazole, 20 parts of aluminum hydroxide, and 30 parts of boehmite.

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PUM

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Abstract

The invention discloses a high-CTI (comparative tracking index) halogen-free flame retardant resin composition for a copper-clad laminate. The composition comprises the following components in parts by weight: 30-70 parts of polyepoxy resin, 1-5 part of curing agent, 0.01-1 parts of curing promoter, and 20-60 parts of filler. The resin composition disclosed by the invention remains high heat resistance while being endued with a high CTI value. The resin composition disclosed by the invention not only contains phosphorus epoxy resin, but also is added with some tough epoxy resins, so that the processing characteristics are greatly improved. The copper-clad laminate fabricated with the resin composition disclosed by the invention has the characteristics of high heat resistance, high CTI value, no halogen, good processing characteristics and the like.

Description

Technical field [0001] The invention involves a high CTI value -free flame -free resin composition for copper -covering the substrate. Background technique [0002] With the rapid development of science and technology and the formation of large -scale industrial integration, it has caused incomparable damage to the human living environment, thereby making environmental protection very urgent.In recent years, electronic technology has developed rapidly, and the impact of electronic products on the environment has become increasingly serious, especially electronic waste products. At present, most of the electronic products are halogen flame retardant. After the burning of halogen, not only the amount of smoke is large, the smell is unpleasant, and the smell is unpleasant, and the smell is unpleasant.It will produce very corrosive halide hydrogen gases.According to the literature report, in recent years, the flame retardant -containing flame retardant will produce two evil substance...

Claims

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Application Information

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IPC IPC(8): C08L63/00C08L63/02C08K3/22C08K3/36C08G59/50
Inventor 李宏途霍小伟施忠仁肖浩
Owner 无锡宏仁电子材料科技有限公司
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